Abstract
In this chapter, cyclodextrin-based chiral stationary phases (CSPs) developed for the enantiomeric separation using gas chromatography are reviewed. A correlation of the CD structure and the enantioselectivities of the resultant CSPs are discussed.
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Abbreviations
- GC:
-
Gas chromatography
- GC-MS:
-
Gas chromatography
- HPLC:
-
High-performance liquid chromatography
- SFC:
-
Supercritical fluid chromatography
- FID:
-
Flame ionization detection
- CSP:
-
Chiral stationary phase
- CD:
-
Cyclodextrin
- CMP:
-
Chiral mobile phase additives
- Chiraldex PH-A:
-
Permethylated S-hydroxypropyl-α-CD
- Chiraldex PH-B:
-
Permethylated S-hydroxypropyl-β-CD
- Chiraldex PH-G:
-
Permethylated S-hydroxypropyl-γ-CD
- Chiraldex DA-A:
-
2,6-O-Dipentylated 3-O-acetylated α-CD
- Chiraldex DA-B:
-
2,6-O-Dipentylated 3-O-acetylated β-CD
- Chiraldex DA-G:
-
2,6-O-Dipentylated 3-O-acetylated γ-CD
- Chiraldex TA-A:
-
2,6-O-Dipentylated 3-O-trifluoroacetylated α-CD
- Chiraldex TA-B:
-
2,6-O-Dipentylated 3-O-trifluoroacetylated β-CD
- Chiraldex TA-G:
-
2,6-O-Dipentylated 3-O-trifluoroacetylated γ-CD
- Chiraldex PN-G:
-
2,6-O-Dipentylated 3-O-propionyl-γ-CD
- Chiraldex BP-G:
-
2,6-O-Dipentylated 3-O-butyryl-γ-CD
- Chiraldex DM-B:
-
Di-O-dimethyl-β-CD
- Hydrodex B:
-
Permethylated β-CD + polysiloxane
- Chiraldex B:
-
Permethylated β-CD + poly(dimethylsi1oxane)
- Lipodex A:
-
2,3,6-Tri-O-pentyl-α-CD
- Lipodex B:
-
2,3,6-Tri-O-pentyl-3-O-acetyl-α-CD
- Lipodex C:
-
2,3,6-Tri-O-pentyl-β-CD
- Lipodex D:
-
2,3,6-Tri-O-pentyl-3-O-acetyl-β-CD
- Lipodex E:
-
2,3,6-Tri-O-pentyl-3-O-acetyl-γ-CD
- α-Dex 120:
-
Permethylated α-CD (20 %)-SPB 35
- β-Dex 110:
-
Permethylated β-CD (20 %)-SPB 35
- β-Dex 120:
-
Permethylated γ-CD (20 %)-SPB 35
- perMe-β-CD:
-
2,3,6-Permethyl-β-cyclodextrin
- perMe-γ-CD:
-
2,3,6-Permethyl-γ-cyclodextrin
- DMP-B:
-
2,6-Di-O-methyl-3-O-pentyl-β-cyclodextrin
- DMP-G:
-
2,6-Di-O-methyl-3-O-pentyl-γ-cyclodextrin
- CP-Chirasil-Dex CB:
-
Heptakis(2,3,6-tri-O-metil)-β-cyclodextrin
- OPP:
-
Organophosphorus pesticide
- PMHP-α-CD:
-
Permethyl-O-(S)-2-hydroxypropyl-α-cyclodextrin
- PMHP-β-CD:
-
Permethyl-O-(S)-2-hydroxypropyl-β-cyclodextrin
- PMHP-γ-CD:
-
Permethyl-O-(S)-2-hydroxypropyl-γ-cyclodextrin
- DBTBCD:
-
Heptakis(2,6-di-O-butyl- 3-O-trifluoroacetyl)-β-CD
- DNTBCD:
-
Heptakis(2,6-di-O-nonyl-3-O-trifluoroacetyl)-β-CD
- DDTBCD:
-
Heptakis(2,6-di-O-dodecyl-3-O-trifluoroacetyl)-β-CD
- DBBBCD:
-
Heptakis(2,6-di-O-butyl-3-O-butyryl)-β-CD
- DPABCD:
-
Heptakis(2,6-di-O-pentyl-3-O-acetyl)-β-CD
- 20Me/P6COOMe:
-
6I-O-Methoxy-carbonyl-6I-deoxy-2I–VII,3I–VII,6II–VIIeicosa-O-methylcyclodextrin
- 20Me/P6OCH2CO OMe:
-
6I-O-Methoxycarbonylmethyl-2I–VII,3I–VII,6II–VII-eicosa-O -methyl-cyclodextrin
- 20Me/P2OCH2COOMe:
-
2I-O-Methoxycarbonylmethyl-2II–VII, 3I–VII,6I–VII-eicosa-O-methyl-cyclodextrin
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Dai, Y., Hai, J., Tang, W., Ng, SC. (2013). Cyclodextrin-Based Chiral Stationary Phases for Gas Chromatography. In: Tang, W., Ng, SC., Sun, D. (eds) Modified Cyclodextrins for Chiral Separation. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-37648-1_2
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DOI: https://doi.org/10.1007/978-3-642-37648-1_2
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