Skip to main content

Specific Intermolecular Interactions of Nitrogen and Oxygen Containing Cyclic Hydrocarbons

  • Chapter
  • First Online:
Book cover Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds
  • 477 Accesses

Abstract

The simplest oxazole molecules and its derivatives with two hetero atoms in the cycle exclude the possibility of understanding the specificity of the formed interactions with the use of ideas of sp3-hybridization [1–7]. The increased ability of the oxygen atom to shift of the electron density predetermines the increased positive charge of the carbon atom, at location С(2), located between these atoms. Therefore, the interaction of the oxygen atom with carbon atoms at locations С(2) and С(5) leads to the four interactions of one type, D–O → CH, in the structure of liquid oxazole with the network of specific interactions with increased stability

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Baev AK, Korolkov DV (2003) Phenomenon of dative bonds in elementorganic compounds with alkyl ligand. Abstract XVth FECHEM conference on organometallic chemistry. University of Zurich, p 350

    Google Scholar 

  2. Baev AK (2003) Novel Approaches to the structure of functional solvents and elementorganic compounds with abstract international conference on solution chemistry, Debrecen. p 79

    Google Scholar 

  3. Baev AK (2004) Insolvence of model sp3-hybridization of carbon atom and chemistry of non aqua solutions. IX international conference. The problem of solvation and complex formation in solutions, Plyos, pp 62–64

    Google Scholar 

  4. Baev AK (2004) Lack of co-ordination thermodynamic properties of elementorganic compounds with sp3-hybridization of carbon atom and its insolence. Russian scientific symposium on thermo chemistry and calorimetry, Niznie Novgorod, pp 40–41

    Google Scholar 

  5. Baev AK (2009) Phenomenological significance of nonidentical sp3-hybridization model and a nature of interaction in chemistry of liquid non-electrolites and chemical thermodynamics. Abstracts. In: X international conference on physical and coordination porphyrin’s chemistry and their analogous (ICPC-10), Ivanovo, p 86

    Google Scholar 

  6. Baev AK (2012) Specific intermolecular interactions of organic compounds. Springer, Hiedelberg/Dordrecht/London/New York, 434p

    Book  Google Scholar 

  7. Schustorovich EM (1978) Chemical bonds in coordination compounds. Knowledge, Moscow, p 434

    Google Scholar 

  8. Chickos JS, Acree WE (2002) Enthalpies of vaporization of organic and organometallic compounds, 1880–2002. J Phys Chem Rev 31(2):537

    CAS  Google Scholar 

  9. Baev AK (1969) Problems of chemical nature of phase transformation. In: General and applied chemistry, vol 1. Vysheischaia Educating, Minsk, pp 197–206

    Google Scholar 

  10. Baev AK (1969) Phase condition and complex formation ability of halogenide metals. In: General and applied chemistry, vol 1. Vysheischaia Educating, Minsk, pp 207–218

    Google Scholar 

  11. Baev AK (1987) Chemistry of gas-heterogenic systems of elementorganic compounds, Science and technology. Vysheischaia Educating, Minsk, 174p

    Google Scholar 

  12. Chickos JS, Acree WE (2003) Enthalpies of sublimation of organic and organometallic compounds, 1910–2001. J Phys Chem Rev 32(2):519

    CAS  Google Scholar 

  13. Armstrong DR, Perkins PG (1969) Calculation of the electronic structures and the gas-phase heats of formation of BH3, NH3, and BH3,CO. Inorganic physical theoretical. J Chem Soc 7(7):1044–1048

    Google Scholar 

  14. Kahn O (1969) Semi-empirical determination of electron transfer in complexes by a quantum chemical method. J Chim Phys 66:869

    CAS  Google Scholar 

  15. Gurianova EN, Goldshtain IG, Romm IP (1973) Donor-acceptor bonds. Chemistry, Moscow, p 397

    Google Scholar 

  16. Veillard A, Levy B, Danbll R, Gallais F (1967) Structural electroniqul of borazane BH3-NH3. Theor Chim Acta 8:312

    Article  CAS  Google Scholar 

  17. Moireau MG, Veillard A (1968) Quantum mechanical calculations on barriers to internal rotation. II. The borazane molecular BH3-NH3. Theor Chim Acta 11:344

    Article  CAS  Google Scholar 

  18. Veillard A, Daudel R (1970) Nature et proprieties des liaison de Coordination. Colloques internationaux du centre National de la Recherche Scientifigue, Paris, p 22

    Google Scholar 

  19. Kudchadk SA, Rao CNR (1970) Extended Huckel calculations on N-V addition compounds. Theory Chim Acta 18:258

    Article  Google Scholar 

  20. Ehrenson S (1968) Theory of electron effect at formation of complex of trimethylamine with trimethylborium. Theor Chim Acta 10:193

    Article  CAS  Google Scholar 

  21. Ehrenson S (1968) Effect environment at examination of a reactivity adding of trimethylamine to trimethylborium. Theory Chem Acta 10:209

    Article  CAS  Google Scholar 

  22. Boer FP, Newton MD (1966) Molecular orbital’s for boron hydrides parameterized from SEF – model calculations. J Am Chem Soc 88:2361–2366

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Baev, A.K. (2014). Specific Intermolecular Interactions of Nitrogen and Oxygen Containing Cyclic Hydrocarbons. In: Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-37472-2_7

Download citation

Publish with us

Policies and ethics