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Specific Intermolecular Interactions of Cyclic Aromatic Compounds with Nitrogen Atom in Their Functional Groups

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Abstract

The thermodynamic properties of processes of vaporization of cyclic compounds with saturated and unsaturated cycles and nitrogen atoms in the functional group, established at a standard temperature, are known for a limited number of compounds (Table 3.1). Nevertheless it allows us to find the role of the specific interactions Н2С → СН2, Н2С → H–СН, НС → СН and НС → Н–С, formed by relevant groups СН2, СН of the carbon-hydrogen cycles in the energy of the formed specific interaction D≡N → C≡ by the cyanide group –C≡N and the hydrogen bond of the amino group.

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Baev, A.K. (2014). Specific Intermolecular Interactions of Cyclic Aromatic Compounds with Nitrogen Atom in Their Functional Groups. In: Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-37472-2_3

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