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Glass Electrodes

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Ion-Selective Electrodes

Part of the book series: Lecture Notes in Chemistry ((LNC,volume 81))

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Abstract

This chapter is devoted to glass electrodes for the pH and metal ion measurements, as well as to RedOx-sensitive glass electrodes.

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Notes

  1. 1.

    Here, the symbol R− stands for ionogenic group in glass: ≡Si–O− or =Al–O− or =B–O− or whatever else, dependent on the glass composition.

  2. 2.

    It is important to mention that microscopic non-equality of ion exchange and the respective deviation from the electroneutrality within the space-charge region at the membrane/solution interface always takes place. Furthermore, the boundary potential originates from this minute non-equality, see Sect. 2.2. However, this microscopic non-equality does not affect the macroscopic compositions of the respective phases and even those of the surface layers outside the space-charge region.

References

  1. M. Cremer, Z. Biol., 1906, 47, 562.

    Google Scholar 

  2. F. Haber, Z. Klemensiewicz, Z. Phys. Chem., 1909, 67, 385.

    Google Scholar 

  3. B.P. Nicolsky, Acta Physicochim. URSS, 1937, 7, 597.

    Google Scholar 

  4. M. Dole, The glass electrode. Methods, applications, and theory. Wiley, N.Y., 1941.

    Google Scholar 

  5. G. Eisenman (ed), Glass electrodes for hydrogen and other cations. Principles and practice. Dekker, N.Y., 1967.

    Google Scholar 

  6. A.A. Belyustin, J. Solid State Electrochem., 2011, 15, 47.

    Google Scholar 

  7. A.A. Kiprianov, N.G. Karpukhina, V.A. Molodozhen, Herald St. Petersburg Univ., 1998, ser. 4, 53 (Russ).

    Google Scholar 

  8. N.G. Karpukhina, A.A. Kiprianov, Fiz. Khim. Stekla, 2001, 27, 101 (Russ.).

    Google Scholar 

  9. G. Eisenman, Biophys. J., 1962, 2, 259.

    Google Scholar 

  10. G. Eisenman, Adv. Anal. Chem. Instrum., 1965, 4, 213.

    Google Scholar 

  11. O.K. Stefanova, M.M. Shultz, E.A. Materova, B.P. Nikolsky, Herald Leningrad Univ., 1963, ser. 4, 93 (Russ).

    Google Scholar 

  12. M.M. Shultz, Dokl. Acad. Nauk USSR, 1970, 194, 377 (Russ.).

    Google Scholar 

  13. M.M. Shultz, O.K. Stefanova, Herald Leningrad Univ., 1972, ser. 4, 22 (Russ).

    Google Scholar 

  14. M.M. Shultz, O.K. Stefanova, Herald Leningrad Univ., 1972, ser. 4, 80 (Russ).

    Google Scholar 

  15. M.M. Shultz, O.K. Stefanova, Herald Leningrad Univ., 1976, ser. 4, 88 (Russ).

    Google Scholar 

  16. W.E. Morf, The principles of Ion-Selective Electrodes and of Membrane Transport, Akademiai Kiado, Budapest, 1981.

    Google Scholar 

  17. A.A. Belyustin, M.M. Shultz, in Academician B.P. Nikolsky, Life, Works, School, A.A. Belyustin, F.A. Belinskaya (Eds), St.Petersburg. Univ. Publ. House, St.Petersburg, 2000, p. 196 (Russ.).

    Google Scholar 

  18. B.P. Nikolsky, M.M. Shultz, A.A. Belyustin, Herald Leningrad Univ., 1963, Ser. 4, 86 (Russ.).

    Google Scholar 

  19. F.G.K. Baucke, Anal. Chem., 1994, 66, 4519.

    Google Scholar 

  20. F.G.K. Baucke, Fres. J. Anal. Chem., 1994, 349, 582.

    Google Scholar 

  21. F.G.K. Baucke, J. Electroanal. Chem., 1994, 367, 131.

    Google Scholar 

  22. F.G.K. Baucke, Ber. Bunsenges. Phys. Chem., 1996, 100, 1466.

    Google Scholar 

  23. F.G.K. Baucke, J. Phys. Chem. B, 1998, 102, 4835.

    Google Scholar 

  24. F.G.K. Baucke, J. Solid State Electrochem. 2011, 15, 23.

    Google Scholar 

  25. A.A. Belyustin, Russ. Chem. Rev., 1980, 49, 920.

    Google Scholar 

  26. A.A. Belyustin, I.V. Valova, Fiz. Khim. Stekla, 1980, 6, 449 (Russ.).

    Google Scholar 

  27. A.A. Belyustin, I.V. Valova, Fiz. Khim. Stekla, 1980, 6, 456 (Russ.).

    Google Scholar 

  28. I.S. Ivanovskaya, A.A. Belyustin, I.D. Pozdnyakova, Sens. Actuators B, 1995, 24–25, 304.

    Google Scholar 

  29. A.A. Belyustin, I.S. Ivanovskaya, Kh.L. Bichiya, Sens. Actuators B, 1998, 48, 485.

    Google Scholar 

  30. A.A. Belyustin, Electroanalysis, 1999, 11, 799.

    Google Scholar 

  31. B.P. Nikolsky, M.M. Shultz, A.M. Pisarevskii, US Patent 3773642, 1973.

    Google Scholar 

  32. B.P. Nikolsky, M.M. Shultz, A.M. Pisarevskii, FRG Patent 2134101, 1973.

    Google Scholar 

  33. M.M. Shultz, A.M. Pisarevskii, I.P. Polozova, Oxidation Potential. Theory and Practice, Khimia Publ. House, Leningrad, 1984 (Russ.).

    Google Scholar 

  34. A.A. Belyustin, A.M. Pisarevskii, G.P. Lepnev, A.S. Sergeev, M.M. Schultz, Sens. Actuators B, 1992, 10, 61.

    Google Scholar 

  35. A.M. Pisarevskii, I.P. Polozova, O.I. Starushko, L.A. Khorseeva, Ion-exchange Ionometry, 1982, 3, 184 (Russ.).

    Google Scholar 

  36. A.M. Pisarevskii, I.P. Polozova, F. Hockridge, Russ. J. Appl. Chem., 2005, 78, 102.

    Google Scholar 

  37. W.S. Hughes, J. Chem. Soc., London, 1928, 491.

    Google Scholar 

  38. D.A. McInnes, M. Dole, Ind Eng Chem Anal, 1929, Ed 1, 57.

    Google Scholar 

  39. D.A. McInnes, M. Dole, J. Amer. Chem. Soc., 1930, 52, 29.

    Google Scholar 

  40. S.I. Sokolov, A.G. Passinskii, Z. Phys. Chem. A, 1932, 160, 366.

    Google Scholar 

  41. G.P. Avseevich, Ucheniye Zapiski Leningr. Univ., 1949, 108, 3 (Russ.).

    Google Scholar 

  42. G.P. Avseevich, Ucheniye Zapiski Leningr. Univ.. 1951, 150, 50 (Russ.).

    Google Scholar 

  43. H.H. Cary, W.P. Baxter, US Patent No 2462843 (1949).

    Google Scholar 

  44. G.A. Perley, US Patent No 2444845, (1948).

    Google Scholar 

  45. G.A. Perley, Anal. Chem., 1949, 21, 395.

    Google Scholar 

  46. K. Horovitz, Z. Physik., 1923, 15, 369.

    Google Scholar 

  47. H. Schiller, Ann. Phys., 1924, 74, 105.

    Google Scholar 

  48. M.M. Schultz, T.M. Ovchinnikova, Vestnik Leningr. Univ., 1954, Ser. Math. Fiz. Khim., 2, 129 (Russ.).

    Google Scholar 

  49. M.M. Schultz, L.G. Aio, Vestnik Leningr. Univ., 1955, Ser. Math. Fiz. Khim., 8, 153 (Russ.).

    Google Scholar 

  50. B.P. Nikolskii, M.M. Schultz, N.V. Peshekhonova, Zh. Fiz. Khim., 1958, 32, 19 (Russ.).

    Google Scholar 

  51. B.P. Nikolskii, M.M. Schultz, N.V. Peshekhonova, Zh. Fiz. Khim., 1958, 32, 262 (Russ.).

    Google Scholar 

  52. G. Eisenman, D.O. Rudin, J.U. Casby, Science, 1957, 126, 831.

    Google Scholar 

  53. G. Eisenman, Particular properties of cation-selective glass electrodes containing Al2O3, Ref. 5, pp 268–283.

    Google Scholar 

  54. M.M. Schultz, V.A. Dolidze, E.P. Sarukhanova, V.A. Bagaturova, USSR Patent No 206023, 1967.

    Google Scholar 

  55. J.E. Leonard, Beckman reprint R-6148, 1959.

    Google Scholar 

  56. G. Mattock, Analyst, 1962, 87, 930.

    Google Scholar 

  57. A.A. Belyustin, I.V. Valova, V.A. Dolidze, G.I. Orlova, E.P. Sarukhanova, Ts.M. Siradze, M.M. Schultz, Anal. Instrum.-making industry, 1975, 3, 112 (Russ.).

    Google Scholar 

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Authors and Affiliations

  1. Ion-Selective Electrode Laboratory, St. Petersburg State University, 26 Universitetski Pr., Stary Peterhof, 198504, St. Petersburg, Russia

    Konstantin N. Mikhelson

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Mikhelson, K.N. (2013). Glass Electrodes. In: Ion-Selective Electrodes. Lecture Notes in Chemistry, vol 81. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-36886-8_5

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