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Alkaline-Earth Metal Compounds pp 141–189Cite as

Alkaline-Earth Metal Complexes in Homogeneous Polymerization Catalysis

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Abbreviations

Ae:

Alkaline-earth

BD:

Butadiene

BDI:

β-Diketiminate

Bn:

Benzyl

Bu:

Butyl

CGP:

Chain growth polymerization

CL:

ε-Caprolactone

Cp:

Cyclopentadienyl

Cp*:

Pentamethylcyclopentadienyl

d,l-LA:

Racemic lactide

equiv:

Equivalent(s)

Et:

Ethyl

Flu:

Fluorenyl

GL:

Glycolide

h:

Hour(s)

Ind:

Indenyl

IP:

Isoprene

iPr:

iso-propyl

IR:

Infrared

iROP:

Immortal ring-opening polymerization

LA:

Lactide

l-LA:

l-Lactide

Ln:

Lanthanide

MALDI-ToF-MS:

Matrix-assisted laser desorption ionization time-of-flight mass spectrometry

MAO:

Methylaluminoxane

Me:

Methyl

meso-LA:

meso lactide

min:

Minute(s)

MMA:

Methyl methacrylate

M n :

Number-average molecular weight

M w :

Weight-average molecular weight

M w/M n :

Polydispersity index

NMR:

Nuclear magnetic resonance

Nu:

Nucleophile

PBD:

Poly(butadiene)

PCL:

Poly(ε-caprolactone)

PE:

Poly(ethylene)

PEO:

Poly(ethylene oxide)

Ph:

Phenyl

PIP:

Poly(isoprene)

PLA:

Poly(lactide)

PLLA:

Poly(l-lactide)

P m :

Probability of meso linkages of consecutive monomer units

PMMA:

Poly(methyl methacrylate)

Pr:

Propyl

P r :

Probability of racemic linkages of consecutive monomer units

PS:

Poly(styrene)

PTMC:

Poly(trimethylene carbonate)

ROP:

Ring-opening polymerization

rt:

Room temperature

s:

Second(s)

s :

Secondary

SEC:

Size exclusion chromatography

tBu:

tert-butyl

T g :

Glass transition temperature

THF:

Tetrahydrofuran

T m :

Melting temperature

TMC:

Trimethylene carbonate

TOF:

Turnover frequency

TON:

Turnover number

Tp:

Tris(pyrazolyl)borate

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Authors and Affiliations

  1. Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS–Université de Rennes 1, 263 avenue du Général Leclerc, 35042, Rennes Cedex, France

    Jean-François Carpentier & Yann Sarazin

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  1. Jean-François Carpentier
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  2. Yann Sarazin
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Correspondence to Jean-François Carpentier or Yann Sarazin .

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Editors and Affiliations

  1. , Anorganische Chemie (FAU), University of Erlangen, Egerlandstr. 1, Erlangen, 91058, Germany

    Sjoerd Harder

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Carpentier, JF., Sarazin, Y. (2013). Alkaline-Earth Metal Complexes in Homogeneous Polymerization Catalysis. In: Harder, S. (eds) Alkaline-Earth Metal Compounds. Topics in Organometallic Chemistry, vol 45. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-36270-5_5

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