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Near-Field Excitation Dynamics in Molecules: Nonuniform Light-Matter Interaction Theory Beyond a Dipole Approximation

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Part of the Nano-Optics and Nanophotonics book series (NON)

Abstract

We have presented near-field excitation dynamics in molecules beyond diffraction limit of the incident visible laser field. A generalized theoretical description of a light-matter interaction taking account of nonuniformity of the light due to its intensity gradient has been developed on the basis of the multipolar Hamiltonian. The computations are demonstrated in high-harmonic generation spectra of a linear chain molecule of dicyanodiacetylene, NC6N and also in optical forces induced by a near-field for a 1 nm-sized metal particle mimicked by a jellium model and for C60.

Keywords

Surface Enhance Raman Scattering Dipole Approximation Electron Dynamic Resonance Excitation Nonuniform Electric Field 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgements

This research was supported by a Grant-in-Aid (No. 21350018) and by the Next-Generation Supercomputer Project from the Ministry of Education, Culture, Sports, Science and Technology of Japan. The computation was partly performed at the Research Center for Computational Science, Okazaki, Japan.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2013

Authors and Affiliations

  1. 1.Department of Theoretical and Computational Molecular ScienceInstitute for Molecular ScienceOkazaki, AichiJapan

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