Skip to main content

Some Halophosphates Phosphors

  • Chapter
  • First Online:
Phosphate Phosphors for Solid-State Lighting

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 174))

Abstract

The Halophosphate phosphor is defined as a phosphor with the apatite mineral structure. Almost all commonly found tubes on the global lighting market employ an internal coating of calcium halophosphate materials (generally known simply as ‘Halophosphate’ tubes). This revolutionary material was invented in 1942 by a group led by A. H. McKeag of Osram-GEC in London, and succeeded in almost doubling lamp efficiency. This breakthrough was responsible for propelling the fluorescent business into the vast market. However, by modern standards, halophosphate materials are relatively inefficient and deliver inferior lighting quality compared to newer technologies of fluorescent phosphors. Although fluorescent tubes have low initial purchase cost, this was rapidly offset by the increased electrical power consumption required to generate a given amount of light. Owing to their lesser energy efficiency, halophosphate tubes are being phased out and shortly replaced by other more efficient fluorescent phosphor materials. These phosphors are blends of two different materials which radiate broadly in the blue and orange parts of the spectrum, respectively. By changing the ratio of the two components a full range of warm to cool white hues can be achieved.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Y. Jie, C. Guo, Z. Ren, J. Bai, Opt. Laser Technol. 43, 762 (2011)

    Article  Google Scholar 

  2. M. Hirano, S. Shionoya, J. Phys. Soc. Jpn. 28, 926 (1970)

    Article  CAS  Google Scholar 

  3. D.K. Sardar, W.A. Sibley, R. Alcala, J. Lumin. 27, 2738 (1982)

    Article  Google Scholar 

  4. D. Noetzold, G. Herzog, I. Henke, Anorg. Allg. Chem. 613, 127 (1992)

    Google Scholar 

  5. M. Sato, T. Tanaka, M. Ohota, J. Electrochem. Soc. 141, 1851 (1994)

    Article  CAS  Google Scholar 

  6. R.W. Warren, Phys. Rev. B 6, 4679 (1972)

    Article  CAS  Google Scholar 

  7. S.J. Dhoble, S.V. Moharil, T.K. Gundu Rao, J. Lumin. 126, 383 (2007)

    Article  CAS  Google Scholar 

  8. S.J. Dhoble, V.B. Pawade, K.N. Shinde, Eur. Phys. J. Appl. Phys. 52, 11104 (2010)

    Article  Google Scholar 

  9. K.N. Shinde, I.M. Nagpure, A.B. Fulke, S.J. Dhoble, Luminescence 26, 363 (2011)

    Article  CAS  Google Scholar 

  10. I.M. Nagpure, K.N. Shinde, S.J. Dhoble, A. Kumar, J. Alloys Compd. 481, 632 (2009)

    Article  CAS  Google Scholar 

  11. M. Kottaisamy, R. Jagannathan, P. Jeyagopal, R.P. Rao, R.L. Narayanan, J. Phys. D: Appl. Phys. 27, 2210 (1994)

    Article  CAS  Google Scholar 

  12. International Centre of Diffraction Data/Powder Diffraction File 2, 17–609, 071–1316 and 015–0876

    Google Scholar 

  13. A.N. Akhavan-Niaki, Ann. Chim. (France) 6, 51 (1961)

    Google Scholar 

  14. K. Sudarsanan, R.A. Young, Acta Cryst. B 30, 1381 (1974)

    Article  Google Scholar 

  15. R.D. Shannon, Acta Cryst. A 32, 751 (1976)

    Article  Google Scholar 

  16. D. NoÈtzold, H. Wulff, Phys. Stat. Sol. (b) 207, 271 (1998)

    Article  Google Scholar 

  17. S.R. Jam, K.C. Adiga, V.R.P. Vemeker, Combust. Flame 40, 71 (1981)

    Article  Google Scholar 

  18. H. Choi, Ch.H. Kim, Ch.H. Pyun, S.J. Kim, J. Lumin. 82, 25 (1999)

    Google Scholar 

  19. J. Kuang, Y. Liu, J. Zhang, J. Solid State Chem. 179, 266 (2006)

    Article  CAS  Google Scholar 

  20. M. Yu, J. Lin, Z. Wang, J. Fu, S. Wang, H.J. Zhang, Y.C. Han, Chem. Mater. 14, 2224 (2002)

    Article  CAS  Google Scholar 

  21. L. Sun, C. Qian, C. Liao, X. Wang, C. Yan, Solid State Commun. 119, 393 (2001)

    Article  CAS  Google Scholar 

  22. D. Jia, W.M. Yen, J. Lumin. 101, 115 (2003)

    Article  CAS  Google Scholar 

  23. Q. Su, J. Lin, B. Li, J. Alloys Compd. 225, 120 (1995)

    Article  CAS  Google Scholar 

  24. G. Blasse, Lumin. Inorg. Solids 475, 215 (1978)

    Google Scholar 

  25. A. Stevels, L.N. Schrama-de Pauw, Electrochem. Soc. 123, 691 (1976)

    Article  CAS  Google Scholar 

  26. K.N. Shinde, I.M. Nagpure, S.J. Dhoble, Synth. React. Inorg. Metal-Org. Nano-Metal Chem. 41, 107 (2011)

    CAS  Google Scholar 

  27. Y. Dong, G. Zhou, X. Jun, G. Zhao, F. Su, L. Su, G. Zhang, D. Zhang, H.J. Li, Mater. Res. Bull. 41, 1959–1963 (2006)

    Google Scholar 

  28. K. Toda, J. Alloys Compd. 408, 665 (2006)

    Article  Google Scholar 

  29. V.P. Dotsenko, I.V. Berezovskaya, N.P. Efryushina, A.S. Voloshinovskii, P. Dorenbos, C.W.E. van Eijk, J. Lumin. 93, 137 (2001)

    Article  CAS  Google Scholar 

  30. C.-K. Chang, T.-M. Chen, Appl. Phys. Lett. 91, 081902 (2007)

    Article  Google Scholar 

  31. R. Yu, J. Wang, J. Zhang, H. Yuan, Q.J. Su, Solid State Chem. 181, 658 (2008)

    Article  CAS  Google Scholar 

  32. X. Zhang, H. He, Z. Li, T. Yu, Z. Zou, J. Lumin. 128, 1876 (2008)

    Article  CAS  Google Scholar 

  33. G. Blasse, A.J. Bril, Electrochem. Soc. 115, 10967 (1968)

    Google Scholar 

  34. K.S. Sohn, B. Cho, H.D. Park, Y.G. Choi, K.H. Kim, J. Eur. Ceram. Soc. 20, 1043 (2000)

    Article  CAS  Google Scholar 

  35. V.B. Bhatkar, S.K. Omanwar, S.V. Moharil, Phys. Stat. Sol. A 191(1), 272 (2002)

    Article  CAS  Google Scholar 

  36. M. Kottaisamy, R.M. Mohan, D. Jeyakumar, J. Mater. Chem. 7(2), 345 (1997)

    Google Scholar 

  37. K. Toda, Phys. Stat. Sol. A191(1), 272 (2002)

    Google Scholar 

  38. E.V. Sokolova, Y.K. Kabalov, G. Ferraris, J. Schneider, A.P. Khomyakov, Concepts. Can. Mineral 37, 83 (1999)

    CAS  Google Scholar 

  39. D.T. Palumbo, J.J. Brown Jr, J. Electrochem. Soc. 117(9), 1184 (1970)

    Article  CAS  Google Scholar 

  40. D.T. Palumbo, J.J. Brown Jr, J. Electrochem. Soc. 118, 1159 (1971)

    Google Scholar 

  41. T. Koskentato, M. Leskel, L. Niinisto, Mater. Ref. Bull. 20, 265 (1985)

    Article  Google Scholar 

  42. A. Morell, N. Khiati, J. Electrochem. Soc. 140, 2019 (1993)

    Article  CAS  Google Scholar 

  43. C. Barthou, J. Benoit, P. Benalloul, A. Morell, J. Electrochem. Soc. 141, 524 (1994)

    Google Scholar 

  44. S.J. Dhoble, K.N. Shinde, Adv. Mat. Lett. 2(5), 349–353 (2011)

    CAS  Google Scholar 

  45. F.C. Hawthorne, Can. Miner. 20, 263 (1982)

    CAS  Google Scholar 

  46. B.D. Cullity, Elements of X-Ray Diffraction (Addision-Wesley, London, 1978)

    Google Scholar 

  47. U. Rambabu, S. Buddhudu, Opt. Mater. 17, 401 (2001)

    Article  CAS  Google Scholar 

  48. L. Yu, H. Song, S. Lu, Z. Liu, L. Yang, X. Kong, J. Phys. Chem. 108, 16697 (2004)

    Article  CAS  Google Scholar 

  49. J. Dexpert-Ghys, R. Mauricot, M.D. Faucher, J. Lumin. 69, 203 (1996)

    Article  CAS  Google Scholar 

  50. S.J. Dhoble, J. Phys. D: Appl. Phys. 33, 158 (2000)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Kartik N Shinde .

Rights and permissions

Reprints and permissions

Copyright information

© 2012 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Shinde, K.N., Dhoble, S.J., Swart, H.C., Park, K. (2012). Some Halophosphates Phosphors. In: Phosphate Phosphors for Solid-State Lighting. Springer Series in Materials Science, vol 174. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-34312-4_6

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-34312-4_6

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-34311-7

  • Online ISBN: 978-3-642-34312-4

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

Publish with us

Policies and ethics