Skip to main content

Novel Silicone Rubber/Layered Double Hydroxide Nanocomposite: Preparation and Characterization

  • Conference paper
Advanced Nanomaterials and Nanotechnology

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 143))

  • 3036 Accesses

Abstract

Silicone rubber (SR)/stearate ion modified Mg–Al–LDH (St-LDH) with 1, 3, 5, 8 % loading are obtained by the solution intercalation and characterized. Transmission electron microscope (TEM) of 3 wt % filler loaded SR nanocomposite confirms the exfoliation of St-LDH layers (thickness:1–2 nm, size:75–100 nm). Tensile strength, elongation at break and Young's modulus of the corresponding nanocomposite are found to be maximum improved compared to neat SR by 97, 43 and 55 % respectively. SEM micrographs of the fractured surfaces show the uniform failure of the matrix without involving any crack initiation in neat SR, whereas roughly fractured surface with large number of microvoids are observed in the corresponding of SR nanocomposite. The improvement in the solvent-resistance properties of the SR/St-LDH nanocomposites is attributed to the excellent barrier properties of St-LDH layers and the exfoliated structure of St-LDH. The developed SR/St-LDH nanocomposites are expected to be a novel material with unique combination of mechanical and solvent resistance property.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. W. Chen, B. Qu, Structural characteristics and thermal properties of PE-g-MA/MgAl-LDH exfoliation nanocomposites synthesized by solution intercalation. Chem. Mater. 15, 3208 (2003)

    Article  CAS  Google Scholar 

  2. H. Acharya, S.K. Srivastava, A.K. Bhowmick, Synthesis of partially exfoliated EPDM/LDH nanocomposites by solution intercalation: Structural characterization and properties. Compos. Sci. Technol. 67, 2807 (2007)

    Article  CAS  Google Scholar 

  3. M. Pramanik, S.K. Srivastava, B.K. Samantaray, A.K. Bhowmick, Synthesis and characterization of organosoluble, thermoplastic elastomer/clay nanocomposites. J. Polym. Sci. Part B: Polym. Phys. 40, 2065 (2002)

    Article  CAS  Google Scholar 

  4. T. Kuila, H. Acharya, S.K. Srivastava, A.K. Bhowmick, Ethylene vinyl acetate/mg-al ldh nanocomposites by solution blending. Polym. Compos. 30, 497 (2008)

    Article  Google Scholar 

  5. B. Pradhan, S.K. Srivastava, R. Ananthakrishnan, A. Saxena, Preparation and characterization of exfoliated layered double hydroxide/silicone rubber nanocomposites. J. Appl. Polym. Sci. 119, 343 (2011)

    Article  CAS  Google Scholar 

  6. K. Chibwe, W. Jones, Intercalation of organic and inorganic anions into layered double hydroxides. J. Chem. Soc. Chem. Commun. 14, 926 (1989)

    Article  Google Scholar 

  7. S.D. Burnside, E.P. Giannelis, Synthesis and properties of new poly (Dimethylsi1oxane) nanocomposites. Chem. Mater. 7, 1597 (1995)

    Article  CAS  Google Scholar 

  8. L. Dewimille, B. Bresson, L. Bokobza, Synthesis, structure and morphology of poly(dimethylsiloxane) networks filled with in situ generated silica particles. Polymer 46, 4135 (2005)

    Article  CAS  Google Scholar 

  9. B. Pradhan, S.K. Srivastava, A.K. Bhowmick, A. Saxena, Effect of bilayered stearate ion-modified Mg–Al layered double hydroxide on the thermal and mechanical properties of silicone rubber nanocomposites. Polym. Int. 61, 458 (2012)

    Article  CAS  Google Scholar 

  10. S. Carlino, The intercalation of carboxylic acids into layered double hydroxides: a critical evaluation and review of the different methods. Solid State Ionics 98, 73 (1997)

    Article  CAS  Google Scholar 

  11. E. Mahboobeh, W.M.Z.W. Yunus, Z. Hussein, M. Ahmad, N.A. Ibrahim, Flexibility improvement of poly(lactic acid) by stearate-modified layered double hydroxide. J. Appl. Polym. Sci. 118, 1077 (2010)

    CAS  Google Scholar 

  12. R. Patel, K.S. Patel, Flow injection determination of anionic surfactants with cationic dyes in water bodies of central India. Analyst 123, 1691 (1998)

    Article  CAS  Google Scholar 

  13. Z. S. Mo, and H. F. Zhang, Science Press: PRC; 2003. p. 232

    Google Scholar 

  14. P.J. Flory, J.H. Rehner, Statistical mechanics of cross-linked polymer networks I I. swelling. J. Chem. Phys. 11, 521 (1943)

    Article  CAS  Google Scholar 

  15. L. Qu, G. Huang, Q. Wang, Z. Xie, Effect of diphenylsiloxane unit content on aggregation structure of poly(dimethylsiloxane-co-diphenylsiloxane). J. Polym. Sci. Part B: Polym. Phys. 46, 72 (2008)

    Article  CAS  Google Scholar 

  16. F. Bueche, Molecular basis for the Mullins effect. J. Appl. Polym. Sci. 4, 107 (1960)

    Article  CAS  Google Scholar 

  17. F. Bueche, Mullins effect and rubber-filler interaction. J. Appl. Polym. Sci. 5, 271 (1961)

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors are grateful to Council of Scientific and Industrial Research (CSIR) and Defence Research and Development Organisation (DRDO), New Delhi, India, for financial support.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Suneel Kumar Srivastava .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Pradhan, B., Srivastava, S.K. (2013). Novel Silicone Rubber/Layered Double Hydroxide Nanocomposite: Preparation and Characterization. In: Giri, P.K., Goswami, D.K., Perumal, A. (eds) Advanced Nanomaterials and Nanotechnology. Springer Proceedings in Physics, vol 143. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-34216-5_36

Download citation

Publish with us

Policies and ethics