Abstract
Thousands of tourists from all over the world flock to two island sites at opposite ends of the earth from one another for no other reason than to gaze in awe and wonder at the color phenomenon each one is famous for. Hawaii’s Green Sand Beach on the southernmost point of the Big Island boasts an entire beach covered with tiny olivine crystals that sparkle like emeralds in the tropical sun. Olivine is a common constituent of lava flows, but only in this one place has it been found of gem quality—the crystals in this case seem to have floated on a former lava lake. Around the globe in the North Atlantic, a unique body of water known as the Blue Lagoon on Iceland’s Reykjanes peninsula plays host to about 400,000 visitors a year who come to take a dip in this unique body of water—also an indirect product of an ancient lava flow flooded by the transforming effluent from a nearby geothermal power plant. What is it about some materials that give rise to these and so many other wonderful colors? Why are other substances colorless, and can we modify them to produce color? The answers to these questions are not simple, and they involve awareness of several important insights regarding the nature of matter, particularly atoms and molecules.
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References
Elschner C (1907) On the occurrence of silicate gems and other rare minerals in the Hawaiian Islands. Chem-Ztg 30:1119
Petursdottir SK, Bjornsdottir SH, Hreggvidsson GO, Hjorleifsdottir S, Kristjansson JK (2009) Analysis of the unique geothermal microbial ecosystem of the Blue Lagoon. FEMS Microbiol Ecol 70(3):425–432
Dalton J (1803) On the absorption of gases by water and other liquids. In Alembic Club Reprint No. 2 (1893) Foundations of the atomic theory. William F. Clay, Edinburgh, p. 25
See for example Lee Buescher’s website: http://atomictimeline.net/index.php and Barcodes http://www.barcodesinc.com/articles/timeline-on-atomic-structure.htm. Accessed 11 Dec 2011
Mendeleev D (1869) On the relationship of the properties of the elements to their atomic weights. Zeitschrift für Chemie 12:405–406
Thomson JJ (1897) Cathode rays. Phil Mag 44:293–316
Goldstein E (1898) Über eine noch nicht untersuchte Strahlungsform an der Kathode inducirter Entladungen. Annalen der Physik 300:38–48
Rutherford E (1911) The scattering of the α and β rays and the structure of the atom. Proc Manch Lit Phil Soc, IV 55:18–20
Planck M (1922) 1920 Nobel prize address. In: Moulton FR, Schifferes JJ (eds) Autobiography of science 1950. Doubleday, New York
Einstein A (1905) Über einen die Erzeugung und Verwandlung des Lichtes betreffenden heuristischen Gesichtspunkt. Annalen der Physik 17:132–148
Moseley HGJ (1913) The high frequency spectra of the elements. Phil Mag 26:1024
Soddy F (1913) Intra-atomic charge. Nature 92:399–400
Chadwick J (1932) The existence of a neutron. Proc Roy Soc A 136:692–708
Bohr N (1913) On the constitution of atoms and molecules. Phil Mag 26:1–25
Balmer JJ (1885) Notiz über die Spektrallinien des Wasserstoffs. Ann Phys 25:80–87
Langmuir I (1919) The structure of atoms and the octet theory of valence. Proc Natl Acad Sci U S A 5:252–259
Russell C (1996) Edward Frankland: chemistry, controversy and conspiracy in victorian England. Cambridge University Press, Cambridge, p 108
Frankland E (1852) On a new series of organic bodies containing metals. Phil Trans 142:417–444; p 440
Kossel W (1916) 1. Über Molekülbildung als Frage des Atombaus. Ann Phys 49(IV):229–362; p 241
Lewis GN (1916) The atom and the molecule. J Am Chem Soc 38:762–786; pp. 777–778 (reprinted with permission, American Chemical Society © 1916)
Langmuir I (1919) The arrangement of electrons in atoms and molecules. J Am Chem Soc 41:868–934; p. 933 (reprinted with permission, American Chemical Society © 1919)
Pauling L (1931a) Quantum mechanics and the chemical bond. Phys Rev 37:1185–1186 (this introductory paper is not part of the series, but leads into it)
Pauling L (1931) The nature of the chemical bond. Application of results obtained from the quantum mechanics and from a theory of paramagnetic susceptibility to the structure of molecules. J Am Chem Soc 53:1367–1400
Pauling L (1931) The nature of the chemical bond. II. The one-electron bond and the three-electron bond. J Am Chem Soc 53:3225–3237
Pauling L (1932) The nature of the chemical bond. III. The transition from one extreme bond type to another. J Am Chem Soc 54:988–1003
Pauling L (1932) The nature of the chemical bond. IV. The energy of single bonds and the relative electronegativity of atoms. J Am Chem Soc 54:3570–3582
Pauling L, Wheland GW (1933) The nature of the chemical bond. V. The quantum-mechanical calculation of the resonance energy of benzene and naphthalene and the hydrocarbon free radicals. J Chem Phys 1:362–374
Pauling L, Sherman J (1933) The nature of the chemical bond. VI. The calculation from thermochemical data of the energy of resonance of molecules among several electronic structures. J Chem Phys 1:606–617
Pauling L, Sherman J (1933) The nature of the chemical bond. VII. The calculation of resonance energy in conjugated systems. J Chem Phys 1:679–686
Orna MV (1980) Chemistry and artists’ colors: part I. Light and color. J Chem Educ 57:256–258
Nassau K (1983) The physics and chemistry of color. The fifteen causes of color. Wiley-Interscience, New York
Witt ON (1876) Zur Kenntniss des Baues und der Bildung färbender Kohlenstoffverbindungen. Ber 9:522–527
Orna MV (1978) The chemical origins of color. J Chem Educ 55:478–484
Griffiths J (1976a) Colour and constitution of organic molecules. Academic Press, New York, pp 82, 140
Griffiths J (1976b) Colour and constitution of organic molecules. Academic Press, New York, pp 17–53
Werner A (1893) Beiträge zur Konstitution anorganischer Verbindungen. Z Anorg Chem 3:267–330
Van Vleck JH (1932) Theory of the variations of paramagnetic anisotropy among different salts of the iron group. Phys Rev 41:208–215
Koren ZC (1996) Historico-chemical analysis of plant dyestuffs used in textiles from ancient Israel. In: Orna MV (ed) Archaeological chemistry: organic, inorganic and biochemical analysis. American Chemical Society, Washingon, pp 269–310
Przibram K (1923) Verfärbung und Lumineszenz durch Becquerelstrahlen. Zeit Physik 20:196–208
Rabinowitch E (1942) Electron transfer spectra and their photochemical effects. Rev Modern Phys 14:127
Yu PY, Cardona M (2004) Fundamentals of semiconductors: physics and materials properties. Springer, New York
Turley J (2002) The essential guide to semiconductors. Prentice Hall, New York
Orna MV (1980) Chemistry and artists’ colors: Part II. Structural features of colored compounds. J Chem Educ 57:264–267
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Orna, M.V. (2013). The Chemical Causes of Color. In: The Chemical History of Color. SpringerBriefs in Molecular Science(). Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-32642-4_3
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