Abstract
The present chapter explored the advancement of research in carbon nanomaterials (graphene and carbon nanotubes), in the areas of synthesis, properties and applications including electronics, field emission, biological and energy applications. The reported properties and applications of these carbon nanomaterials have opened up new opportunities for the future devices and materials. The knowledge presented here should lead to a better understanding of the key factors that can influence the future research directions.
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References
Kroto HW, Heath JR, O’ Brien SC, Curl SC, Smalley RE (1985) C60: buckministerfullerene. Nature 318:162–163
Ajayan PM (1999) Nanotubes from carbon. Chem Rev 99:1787–1800
Huang X, Yin Z, Wu S, Qil X, He Q, Zhang Q, Yan Q, Boey F, Zhang H (2011) Graphene-based materials: synthesis, characterization, properties, and applications. Small 7:1876–1902
Choi W, Lahiri I, Seelaboyna R, Kang Y (2010) Synthesis of Graphene and its applications: a review. Crit Rev Solid State Mat Sci 35:52–71
Choi W, Lee J-W (2011) Graphene: synthesis and applications. CRC Press, Boca Raton, Publication Date: October 11 (2011). ISBN 10: 1439861870, 13: 978-1439861875
Foldvari M, Bagonluri M (2008) Carbon nanotubes as functional excipients for nanomedicines: I. Pharmaceutical properties. Nanomed Nanotech Biol Med 4(173)
Dresselhaus MS, Dresselhaus G, Saito R (1995) Physics of carbon nanotubes. Carbon 33:883–891
Avouris P, Chen Z, Perebeinos V (2007) Carbon-based electronics. Nat Nanotechnol 2(10):605
Ando T (2009) The electronic properties of graphene and carbon nanotubes. NPG Asia Mater 1(1):17–21
Anantram MP, Leonard F (2006) Physics of carbon nanotube electronic devices. Rep Prog Phys 69:507–561
Yao Z, Kane CL, Dekker C (2000) High-field electrical transport in single-wall carbon nanotubes. Phys Rev Lett 84:2941–2944
Kong J, Yenilmez E, Tombler TW, Kim W, Dai H, Laughlin RB, Liu L, Jayanthi CS, Wu SY (2001) Quantum interference and ballistic transmission in nanotube electron waveguides. Phys Rev Lett 87:106801
Awano Y, Sato S, Nihei M, Sakai T, Ohno Y, Mizutani T (2010) Carbon nanotubes for VLSI: interconnect and transistor applications. Proc IEEE 98(12)
Kreupl F, Graham AP, Duesberg GS, Steinhögl W, Liebau M, Unger E, Hönlein W (2002) Carbon nanotubes in interconnect applications. Microelectron Eng 64:399–408
Kreupl F, Graham AP, Liebau M, Duesberg GS, Seidel R, Unger E (2004) Carbon nanotubes for interconnect applications. In: Electron devices meeting, IEDM technical digest. IEEE International, pp 683–686
Awano Y, Sato S, Kondo D, Ohfuti M, Kawabata A, Nihei M, Yokoyama N (2006) Carbon nanotube via interconnect technologies: size-classified catalyst nanoparticles and low-resistance ohmic contact formation. Phys Stat Sol (a) 203:3611–3616
Horibe M, Nihei M, Kondo D, Kawabata A, Awano Y (2005) Carbon nanotube growth technologies using tantalum barrier layer for future ULSIs with Cu/low-k interconnect processes. Jpn J Appl Phys 44:5309
Tans S, Verschueren A, Dekker C (1998) Room-temperature transistor based on a single carbon nanotubes. Nature (London) 393(49)
Martel R, Schmidt T, Shea HR, Hertel T, Avouris P (1998) Single- and multi-wall carbon nanotube field-effect transistors. Appl Phys Lett 73:2447
McEuen PL, Fuhrer MS, Park H (2002) Single-walled carbon nanotube electronics. IEEE Trans Nanotechnol 1:78–85
Javey A, Kim H, Brink M, Wang Q, Ural A, Guo J, Mcintyre P, Mceuen P, Lundstrom M, Dai H (2002) High-κ dielectrics for advanced carbon nanotube transistors and logic gates. Nat Mater 1:241
Robertson DH, Brenner DW, Mintmire JW (1992) Energetics of nanoscale graphitic tubules. Phys Rev B 45:12592
Treacy MM, Ebbesen TW, Gibson JM (1996) Exceptionally high Young’s modulus observed for individual carbon nanotubes. Nature 38:678–680
Krishnan A, Dujardin E, Ebbesen TW, Yianilos PN, Treacy MMJ (1998) Young’s modulus of single-walled nanotubes. Phys Rev B 58:14013
Yu MF, Lourie O, Dyer MJ, Moloni K, Kelly TF, Ruoff RS (2000) Strength and breaking mechanism of multi-walled carbon nanotubes under tensile load. Science 287:637
Salvetat JP, Briggs GAD, Bonard JM, Bacsa RR, Kulik AJ, Stockli T, Burnham NA, Forro L (1999) Elastic and shear moduli of single-walled carbon nanotube ropes. Phys Rev Lett 82:944
Yu MF, Files BF, Arepalli S, Ruoff RS (2000) Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties. Phys Rev Lett 84:5552
Shokrieh MM, Rafiee R (2010) A review of the mechanical properties of isolated carbon nanotubes and carbon nanotube composites. Mech Comp Mater 46:2
Lu Q, Bhattacharya B (2005) The role of atomistic simulations in probing the small-scale aspects of fracture – a case study on a single-walled carbon nanotubes. Eng Fract Mech 72:2037–2071
Rafii-Tabar H (2004) Computational modelling of thermo-mechanical and transport properties of carbon nanotubes. Phys Rep 390:235–452
Bathe KJ (1997) Finite element procedures. Prentice-Hall, New Delhi, pp 1–14
Qian D, Dickey E, Andrews R, Rantell T (2000) Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites. Appl Phys Lett 76:2868–2870
Xu X, Thwe MM, Christopher S, Liao K (2002) Mechanical properties and interfacial characteristics of carbon-nanotube-reinforced epoxy thin films. Appl Phys Lett 81:2833
Shanmugharaj AM, Bae JH, Lee KY, Noh WH, Lee SH, Ryu SH (2007) Physical and chemical characteristics of multiwalled carbon nanotubes functionalized with aminosilane and its influence on the properties of natural rubber composites. Comp Sci Technol 67:1813
Xiao KQ, Zhang LC (2004) The stress transfer efficiency of a single-walled carbon nanotube in epoxy matrix. J Mater Sci 39:4481
Choi Y-K, Gotoh Y, Sugimoto K, Song S-M, Yanagisawa T, Endo M (2005) Processing and characterization of epoxy nanocomposites reinforced by cup-stacked carbon nanotubes. Polymer 46(11489)
Liu YJ, Chen XL (2003) Continuum models of carbon nanotube-based composites by the BEM. Electron J Bound Element 1:316–335
Biercuk MJ, Llaguno MC, Radosavljevic M, Hyun JK, Johnson AT, Fischer JE (2002) Carbon nanotube composites for thermal management. Appl Phys Lett 80:2767–2769
Huang H, Liu CH, Wu Y, Fan S (2005) Aligned carbon nanotube composite films for thermal management. Adv Mater 17:1652–1656
Kim P, Shi L, Majumdar A, Mc Euen PL (2001) Thermal transport measurement of individual multiwalled nanotubes. Phys Rev Lett 87:215502
Pop E, Mann D, Wang Q, Goodson K, Dai H (2006) Thermal conductance of an individual single-wall carbon nanotube above room temperature. Nano Lett 6:96–100
Berber S, Kwon Y-K, Tomanek D (2000) Unusually high thermal conductivity of carbon nanotubes. Phys Rev Lett 84:4613–4616
Che J, Cagin T, Goddard WA (2000) III thermal conductivity of carbon nanotubes. Nanotechnology 11:65–69
Donadio D, Galli G (2007) Thermal conductivity of isolated and interacting carbon nanotubes: comparing results from molecular dynamics and the Boltzmann transport equation. Phys Rev Lett 99:255502
Hone J, Ellwood I, Muno M, Mizel A, Cohen ML, Zettl A, Rinzler AG, Smalley RE (1998) Thermoelectric power of single-walled carbon nanotubes. Phys Rev Lett 80:1042–1045
Bradley K, Jhi S-H, Collins PG, Hone J, Cohen ML, Louie SG, Zettl A (2000) Is the intrinsic thermoelectric power of carbon nanotubes positive ? Phys Rev Lett 85:4361–4364
Li W, Lu L, Lin ZD, Pan ZW, Xie SS (1999) Linear specific heat of carbon nanotubes. Phys Rev B 59:R9015
Yu CH, Shi L, Yao Z, Li DY, Majumdar A (2005) Thermal conductance and thermopower of an single-wall carbon nanotubes. Nano Lett 5:1842–1846
Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6:183–191
Freitag M (2011) Graphene: trilayers unraveled. Nat Phys 7:596–597
Hass J, de Heer WA, Conrad EH (2008) The growth and morphology of epitaxial multilayer graphene. J Phys Cond Matter 20:323202
Lee C, Wei X, Kysar JW, Hone J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321:385–388
Ramanathan T, Abdala AA, Stankovich S, Dikin DA, Herrera-Alonso M, Piner RD, Adamson DH, Schniepp HC, Chen X, Ruoff RS, Nguyen ST, Aksay IA, Prud’Homme RK, Brinson LC (2008) Functionalized graphene sheets for polymer nanocomposites. Nat Nanotechnol 3:327–331
Rafiee MA, Rafiee J, Wang Z, Song H, Yu ZZ, Koratkar N (2009) Enhanced mechanical properties of nanocomposites at low graphene content. ACS Nano 3:3884–3890
Liu F, Ming P, Li J (2007) Ab initio calculation of ideal strength and phonon instability of graphene under tension. Phys Rev B 76:064120
Pereira VM, Castro Neto AH, Peres NMR (2009) Tight-binding approach to uniaxial strain in graphene. Phys Rev B 80:045401
Xu Z (2009) Graphene nanoribbons under tension. J Compd Theor Nanosci 6(625)
Lu Q, Huang R (2010) Effect of edge structure on elastic modulus and fracture of graphene nanoribbons under uniaxial tension. arXiv:1007. 3298
Zhao H, Min K, Aluru NR (2009) Size and chirality dependent elastic properties of graphene nanoribbons under uniaxial tension. Nano Lett 9:3012–3015
Min K, Aluru NR (2011) Mechanical properties of graphene under shear deformation. Appl Phys Lett 98:013113
Pei QX, Zhang YW, Shenoy VB (2010) A molecular dynamics study of the mechanical properties of hydrogen functionalized graphene. Carbon 48:898–904
Zheng QB, Geng Y, Wang SJ, Li ZG, Kim JK (2010) Effects of functional groups on the mechanical and wrinkling properties of graphene sheets. Carbon 48:4315–4322
Bunch JS, van der Zande AM, Verbridge SS, Frank IW, Tanenbaum DM, Parpia JM, Craighead HG (2007) Electromechanical resonators from graphene sheets. Science 315:490–493
Chen C, Rosenblatt S, Bolotin KI, Kalb W, Kim P, Kymissis I, Stormer HL, Heinz TF, Hone J (2009) Performance of monolayer graphene nanomechanical resonators with electrical readout. Nat Nanotech 4:861
Mizuta H, Ramirez MAG, Tsuchiya Y, Nagami T, Sawai S, Oda S, Okamoto M (2009) Multi-scale simulation of hybrid silicon nano-electromechanical (NEM) information systems. J Autom Mobile Robot Intell Syst 3:58
Dutta S, Pati SK (2010) Novel properties of graphene nanoribbons: a review. J Mater Chem 20:8207–8223
Han MY, Ozyilmaz B, Zhang Y (2007) Energy band gap engineering of graphene nanoribbons. Phys Rev Lett 98:206805
Erdogan E, Popov I, Rocha CG, Cuniberti G, Roche S, Seifert G (2011) Engineering carbon chains from mechanically stretched graphene-based materials. Phys Rev B 83:041401 (R)
Topsakal M, Ciraci S (2010) Elastic and plastic deformation of graphene, silicene, and boron nitride honeycomb nanoribbons under uniaxial tension: a first-principles density-functional theory study. Phys Rev B 81:024107
Castro Neto AH, Guinea F, Peres NMR, Novoselov KS, Geim AK (2009) The electronic properties of graphene. Rev Modern Phys 81:109
Berger C, Song Z, Li T, Li X, Ogbazghi AY, Feng R, Dai Z, Marchenkov AN, Conrad EH, First PN, de Heer WA (2004) Ultrathin epitaxial graphite: 2D electron gas properties and a route toward graphene-based nanoelectronics. J Phys Chem 108:19912–19916
Katsnelson MI (2007) Graphene: carbon in two dimensions. Mat Today 10:20–27
Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA (2004) Electric field effect in atomically thin carbon films. Science 306:666–669
Novoselov KS, Geim AK, Morozov SV, Jiang D, Katsnelson MI, Grigorieva IV, Dubonos SV, Firsov AA (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438:197
Novoselov KS, Jiang Z, Zhang Y, Morozov SV, Stormer HL, Zeitler U, Maan JC, Boebinger GS, Kim P, Geim AK (2007) Room-temperature quantum Hall effect in graphene. Science 315:1379
Novoselov KS, McCann E, Morozov SV, Fal’ko VI, Katsnelson MI, Zeitler U, Jiang D, Schedin F, Geim AK (2006) Unconventional quantum Hall effect and Berry’s phase of 2π in bilayer graphene. Nat Phys 2:177
McCann E (2006) Asymmetry gap in the electronic band structure of bilayer graphene. Phys Rev B 74:161403
Zhou SY, Gweon G-H, Fedorov AV, First PN, de Heer WA, Lee D-H, Guinea F, Castro Neto AH, Lanzara A (2007) Substrate-induced bandgap opening in epitaxial graphene. Nat Mater 6:770
Hass J, Varchon F, Millan-Otoya JE, Sprinkle M, Sharma N, de Heer WA, Berger C, First PN, Magaud L, Conrad EH (2008) Why multilayer graphene on 4H-SiC(0001) behaves like a single sheet of graphene. Phys Rev Lett 100:125504
Elias DC, Nair RR, Mohiuddin TMG, Morozov SV, Blake P, Halsall MP, Ferrari AC, Boukhvalov DW, Katsnelson MI, Geim AK, Novoselov KS (2009) Control of graphene’s properties by reversible hydrogenation: evidence for graphene. Science 323:610
Zhou SY, Siegel DA, Fedorov AV, Lanzara A (2008) Metal to insulator transition in epitaxial graphene induced by molecular doping. Phys Rev Lett 101:086402
Peres NMR (2009) The electronic properties of graphene and its bilayer. Vacuum 83:1248
Morozov SV, Novoselov KS, Schedin F, Jiang D, Firsov AA, Geim AK (2005) Two-dimensional electron and hole gases at the surface of graphite. Phys Rev B 72:201401
McCann E, Fal’ko VI (2006) Landau-level degeneracy and quantum hall effect in a graphite bilayer. Phys Rev Lett 96:086805
Mak KF, Shan J, Heinz TF (2010) Electronic structure of few-layer graphene: experimental demonstration of strong dependence on stacking sequence. Phys Rev Lett 104:176404
Muszynski R, Seger B, Kamat PV (2008) Decorating graphene sheets with gold nanoparticles. J Phys Chem C 112:5263
Chen S, Wu Q, Mishra C, Kang J, Zhang H, Cho K, Cai W, Balandin AA, Ruoff RS (2012) Thermal conductivity of isotopically modified graphene. Nat Mater 11:203
Cai W, Moore AL, Zhu Y, Li X, Chen S, Shi L, Ruoff RS (2010) Thermal transport in suspended and supported monolayer graphene grown by chemical vapor deposition. Nano Lett 10:1645–1651
Saito K, Nakamura J, Natori A (2007) Ballistic thermal conductance of a graphene sheet. Phys Rev B 76:115409
Ghosh S, Bao W, Nika DL, Subrina S, Pokatilov EP, Lau CN, Balandin AA (2010) Dimensional crossover of thermal transport in few-layer graphene. Nat Mater 9:555–558
Schabel MC, Martins JL (1992) Energetics of interplanar binding in graphite. Phys Rev B 46:7185
Liao AD, Wu JZ, Wang XR, Tahy K, Jena D, Dai HJ, Pop E (2011) Thermally limited current carrying ability of graphene nanoribbons. Phys Rev Lett 106:256801
Seol JH, Jo I, Moore AL, Lindsay L, Aitken ZH, Pettes MT, Li XS, Yao Z, Huang R, Broido D, Mingo N, Ruoff RS, Shi L (2010) Two-dimensional phonon transport in supported graphene. Science 328:213
Jang W, Chen Z, Bao W, Lau CN, Dames C (2010) Thickness-dependent thermal conductivity of encased graphene and ultrathin graphite. Nano Lett 10:3909
Qiu B, Ruan X (2012) Reduction of spectral phonon relaxation times from suspended to supported graphene. Appl Phys Lett 100:193101
Aksamija Z, Knezevic I (2011) Lattice thermal conductivity of graphene nanoribbons: anisotropy and edge roughness scattering. Appl Phys Lett 98:141919
Yamamoto T, Watanabe K (2004) Empirical-potential study of phonon transport in graphitic ribbons. Phys Rev B 70:245402
Li W, Sevincli H, Cuniberti G, Roche S (2010) Phonon transport in large scale carbon-based disordered materials: implementation of an efficient order-N and real-space Kubo methodology. Phys Rev B 82:041410 (R)
Murali R, Yang Y, Brenner K, Beck T, Meindl JD (2009) Breakdown current density of graphene nano ribbons. Appl Phys Lett 94:243114-1-3
Ong ZY, Pop E (2011) Effect of substrate modes on thermal transport in supported graphene. Phys Rev B 84:075471
Huang Z, Fisher TS, Murthy JY (2010) Simulation of phonon transmission through graphene and graphene nanoribbons with a Green’s function method. J Appl Phys 108:094319
Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56
Dai H, Hafner JH, Rinzler AG, Colbert DT, Smalley RE (1996) Nanotubes as nanoprobes in scanning probe microscopy. Nature 384:147
Mahar B, Laslau C, Yip R, Sun Y (2007) Development of carbon nanotube-based sensors – a review. IEEE Sens J 7:266
Bianco A, Kostarelos K, Prato M (2005) Applications of carbon nanotubes in drug delivery. Curr Opin Chem Biol 9:674–679
Ebbesen TW, Ajayan PM (1992) Large-scale synthesis of carbon nanotubes. Nature 358:220–222
Iijima S, Ichihashi T (1993) Single-shell carbon nanotubes of 1-nm diameter. Nature 363:603–605
Journet C, Maser WK, Bernier P, Loiseau A, Lamy De La Chapelle M, Lefrant S, Deniard P, Lee R, Fischer JE (1997) Large-scale production of single-walled carbon nanotubes by the electric-arc technique. Nature 388:756–758
Seraphin S, Zhou D, Jiao J, Minke MA, Wang S, Yadav T, Withers JC (1994) Catalytic role of nickel, palladium, and platinum in the formation of carbon nanoclusters. Chem Phys Lett 217:191–198
Saito Y, Okuda M, Fujimoto N, Yoshikawa T, Tomita M, Hayashi T (1994) Single-wall carbon nanotubes growing radially from Ni fine particles formed by arc evaporation. Jpn J Appl Phys 33:L526–L529
Chen B, Zhao X, Inoue S, Ando Y (2010) Fabrication and dispersion evaluation of single-wall carbon nanotubes produced by FH-arc discharge method. J Nanosci Nanotechnol 10:3973–3977
Fan WW, Zhao J, Lv YK, Bao WR, Liu XG (2010) Synthesis of SWNTs from charcoal by arc-discharging. J Wuhan Univ Technol Mater Sci Ed 25:194–196
Wang HF, Li ZH, Inoue S, Ando Y (2010) Influence of Mo on the growth of single-walled carbon nanotubes in arc discharge. J Nanosci Nanotechnol 10:3988–3993
Shimotani K, Anazawa K, Watanabe H, Shimizu M (2001) New synthesis of multi-walled carbon nanotubes using an arc discharge technique under organic molecular atmospheres. Appl Phys A Mater Sci Process 73:451–454
Jiang Y, Wang H, Shang XF, Li ZH, Wang M (2009) Influence of NH3 atmosphere on the growth and structures of carbon nanotubes synthesized by the arc-discharge method. Inorg Mater 45:1237–1239
Parkansky N, Boxman RL, Alterkop B, Zontag I, Lereah Y, Barkay Z (2004) Single-pulse arc production of carbon nanotubes in ambient air. J Phys D Appl Phys 37:2715–2719
Jung SH, Kim MR, Jeong SH, Kim SU, Lee OJ, Lee KH, Suh JH, Park CK (2003) High-yield synthesis of multi-walled carbon nanotubes by arc discharge in liquid nitrogen. Appl Phys A Mater Sci Process 76:285–286
Guo JJ, Wang XM, Yao YL, Yang XW, Liu XG, Xu BS (2007) Structure of nanocarbons prepared by arc discharge in water. Mater Chem Phys 105:175–178
Guo T, Nikolaev P, Thess A, Colbert DT, Smalley RE (1995) Catalytic growth of single-walled manotubes by laser vaporization. Chem Phys Lett 243:49–54
Lebel LL, Aissa B, El Khakani MA, Therriault D (2010) Preparation and mechanical characterization of laser ablated single-walled carbon-nanotubes/polyurethane nanocomposite microbeams. Comp Sci Technol 70:518–524
Kusaba M, Tsunawaki Y (2006) Production of single-wall carbon nanotubes by a XeCl excimer laser ablation. Thin Solid Films 506:255–258
Zhang H, Ding Y, Wu C, Chen Y, Zhu Y, He Y, Zhong S (2003) The effect of laser power on the formation of carbon nanotubes prepared in CO2 continuous wave laser ablation at room temperature. Phys B 325:224–229
Stramel AA, Gupta MC, Lee HR, Yu J, Edwards WC (2010) Pulsed laser deposition of carbon nanotube and polystyrene-carbon nanotube composite thin films. Opt Lasers Eng 48:1291–1295
Scott CD, Arepalli S, Nikolaev P, Smalley RE (2001) Growth mechanisms for single-wall carbon nanotubes in a laser-ablation process. Appl Phys A 72:573–580
Kumar M, Ando Y (2010) Chemical vapor deposition of carbon nanotubes: a review on growth mechanism and mass production. J Nanosci Nanotechnol 10:3739–3758
Ren ZF, Huang ZP, Wang DZ, Wen JG, Xu JW, Wang JH, Calvet LE, Chen J, Klemic JF, Reed MA (1999) Growth of a single freestanding multiwall carbon nanotube on each nanonickel dot. Appl Phys Lett 75:1086
Meyyappan M (2009) A review of plasma enhanced chemical vapour deposition of carbon nanotubes. J Phys D Appl Phys 42:213001
Ren ZF, Huang ZP, Xu JW, Wang JH, Bush P, Siegel MP, Provencio PN (1998) Synthesis of large arrays of well-aligned carbon nanotubes on glass. Science 282:1105–1107
Masako Y, Rie K, Takeo M, Yoshimasa O, Susumu Y, Etsuro O (1995) Specific conditions for Ni catalyzed carbon nanotube growth by chemical vapor deposition. Appl Phys Lett 67:2477–2479
Byon HR, Lim H, Song HJ, Choi HC (2007) A synthesis of high purity single-walled carbon nanotubes from small diameters of cobalt nanoparticles by using oxygen-assisted chemical vapor deposition process. Bull Korean Chem Soc 28:2056–2060
Chen YM, Zhang HY (2011) In: Bu JL, Jiang ZY, Jiao S (eds) The super-capacitor properties of aligned carbon nanotubes array prepared by radio frequency plasma-enhanced hot filament chemical vapor deposition. Advanced Materials Research 150–151:1560–1563
Kim HD, Lee JH, Choi WS (2011) Direct growth of carbon nanotubes with a catalyst of nickel nanoparticle-coated alumina powders. J Korean Phys Soc 58:112–115
Xu Y, Dervishi E, Biris AR, Biris AS (2011) Chirality-enriched semiconducting carbon nanotubes synthesized on high surface area MgO-supported catalyst. Mater Lett 65:1878–1881
Zhu YJ, Lin TJ, Liu QX, Chen YL, Zhang GF, Xiong HF, Zhang HY (2006) The effect of nickel content of composite catalysts synthesized by hydrothermal method on the preparation of carbon nanotubes. Mater Sci Eng B 127:198–202
Lee O, Jung J, Doo S, Kim SS, Noh TH, Kim KI, Lim YS (2010) Effects of temperature and catalysts on the synthesis of carbon nanotubes by chemical vapor deposition. Met Mater Int 16:663–667
Afolabi AS, Abdulkareem AS, Mhlanga SD, Iyuke SE (2011) Synthesis and purification of bimetallic catalysed carbon nanotubes in a horizontal CVD reactor. J Exp Nanosci 6:248–262
Dumpala S, Jasinski JB, Sumanasekera GU, Sunkara MK (2011) Large area synthesis of conical carbon nanotube arrays on graphite and tungsten foil substrates. Carbon 49:2725–2734
Zhu J, Yudasaka M, Iijima S (2003) A catalytic chemical vapor deposition synthesis of double-walled carbon nanotubes over metal catalysts supported on a mesoporous material. Chem Phys Lett 380:496–502
Ramesh P, Okazaki T, Taniguchi R, Kimura J, Sugai T, Sato K, Ozeki Y, Shinohara H (2005) Selective chemical vapor deposition synthesis of double-wall carbon nanotubes on mesoporous silica. J Phys Chem B 109:1141–1147
Flahaut E, Laurent C, Peigney A (2005) Catalytic CVD synthesis of double and triple-walled carbon nanotubes by the control of the catalyst preparation. Carbon 43:375–383
Fotopoulos N, Xanthakis JP (2010) A molecular level model for the nucleation of a single-wall carbon nanotube cap over a transition metal catalytic particle. Diamond Relat Mater 19:557–561
Zhang DS, Shi LY, Fang JH, Dai K, Li XK (2006) Preparation and desalination performance of multiwall carbon nanotubes. Mater Chem Phys 97:415–419
Li G (2010) Synthesis of well-aligned carbon nanotubes on the NH3 pretreatment Ni catalyst films. Russ J Phys Chem A 84:1560–1565
Cui T, Lv RT, Kang FY, Hu Q, Gu JL, Wang KL, Wu DH (2010) Synthesis and enhanced field-emission of thin-walled, open-ended, and well-aligned N-doped carbon nanotubes. Nanoscale Res Lett 5:941–948
Novoselov KS, Jiang D, Schedin F, Booth TJ, Khotkevich VV, Morozov SV, Geim AK (2005) Two-dimensional atomic crystals. Proc Natl Acad Sci USA 102:10451
Yu OK, Lian J, Siriponglert S, Li H, Chen YP, Pei SS (2008) Graphene segregated on Ni surfaces and transferred to insulators. Appl Phys Lett 93:113103
De Arco LG, Zhang Y, Kumar A, Zhou C (2009) Synthesis, transfer, and devices of single and few-layer graphene by chemical vapor deposition. IEEE Trans Nanotechnol 8:135
Reina A, Jia X, Ho J, Nezich D, Son H, Bulovic V, Dresselhaus MS, Kong J (2009) Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition. Nano Lett 9:30
Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Kim KS, Ahn J-H, Kim P, Choi J-Y, Hong BH (2009) Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457:706
Li X, Cai W, An J, Kim S, Nah J, Yang D, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee SK, Colombo L, Ruoff RS (2009) Large-area synthesis of high-quality and uniform graphene films on copper foils. Science 324:1312
Bae S, Kim H, Lee Y, Xu X, Park J-S, Zheng Y, Balakrishnan J, Lei T, Kim HR, Song YI, Kim Y-J, Kim KS, Ozyilmaz B, Ahn J-H, Hong BH, Iijima S (2010) Roll-to-roll production of 30-inch graphene films for transparent electrodes. Nat Nanotechnol 5:574
Yu Q, Jauregui LA, Wu W, Colby R, Tian J, Su Z, Cao H, Liu Z, Pandey D, Wei D, Chung TF, Peng P, Guisinger NP, Stach EA, Bao J, Pei S-S, Chen YP (2011) Control and characterization of individual grains and grain boundaries in graphene grown by chemical vapour deposition. Nat Mater 10:443
Kim H, Mattevi C, Calvo MR, Oberg JC, Artiglia L, Agnoli S, Hirjibehedin CF, Chhowalla M, Saiz E (2012) Activation energy paths for graphene nucleation and growth on Cu. ACS Nano 6:3614
Vlassiouk I, Fulvio P, Meyer H, Lavrik N, Dai S, Datskos P, Smirnov S (2013) Large scale atmospheric pressure chemical vapor deposition of graphene. Carbon 54:58
Han GH, Gunes F, Bae JJ, Kim ES, Chae SJ, Shin H-J, Choi J-Y, Pribat D, Lee YH (2011) Influence of copper morphology in forming nucleation seeds for graphene growth. Nano Lett 11:4144
Luo Z, Lu Y, Singer DW, Berck ME, Somers LA, Goldsmith BR, Johnson ATC (2011) Effect of substrate roughness and feedstock concentration on growth of wafer-scale graphene at atmospheric pressure. Chem Mater 23:1441
Tao L, Lee J, Holt M, Chou H, McDonnell SJ, Ferrer DA, Babenco MG, Wallace RM, Banerjee SK, Ruoff RS, Akinwande D (2012) Uniform wafer-scale chemical vapor deposition of graphene on evaporated Cu (111) film with quality comparable to exfoliated monolayer. J Phys Chem C 116:24068
Murdock AT, Koos A, Britton TB, Houben L, Batten T, Zhang T, Wilkinson AJ, Dunin-Borkowski RE, Lekka CE, Grobert N (2013) Controlling the orientation, edge geometry, and thickness of chemical vapor deposition graphene. ACS Nano 7:1351
Wang H, Wang G, Bao P, Yang S, Zhu W, Xie X, Zhang W-J (2012) Controllable synthesis of submillimeter single-crystal monolayer graphene domains on copper foils by suppressing nucleation. J Am Chem Soc 134:3627
Yan Z, Lin J, Peng Z, Sun Z, Zhu Y, Li L, Xiang C, Samuel EL, Kittrell C, Tour JM (2012) Toward the synthesis of wafer-scale single-crystal graphene on copper foils. ACS Nano 6:9110
Vlassiouk I, Regmi M, Fulvio R, Dai S, Datskos P, Eres G, Smirnov S (2011) Role of hydrogen in chemical vapor deposition growth of large single-crystal graphene. ACS Nano 5:6069
Wang J, Zhu M, Outlaw RA, Zhao X, Manos DM, Holloway BC (2004) Synthesis of carbon nanosheets by inductively coupled radio-frequency plasma enhanced chemical vapor deposition. Carbon 42:2867
Wang JJ, Zhu MY, Outlaw RA, Zhao X, Manos DM, Holloway BC, Mammana VP (2004) Free-standing subnanometer graphite sheets. Appl Phys Lett 85:1265
Nandamuri G, Roumimov S, Solanki R (2010) Remote plasma assisted growth of graphene films. Appl Phys Lett 96:154101
Qi JL, Zheng WT, Zheng XH, Wang X, Tian HW (2011) Relatively low temperature synthesis of graphene by radio frequency plasma enhanced chemical vapor deposition. Appl Surf Sci 257:6531
Kim Y, Song W, Lee SY, Jeon C, Jung W, Kim M, Park C-Y (2011) Low-temperature synthesis of graphene on nickel foil by microwave plasma chemical vapor deposition. Appl Phys Lett 98:263106
Kalita G, Kayastha MS, Uchida H, Wakita K, Umeno M (2012) Direct growth of nanographene films by surface wave plasma chemical vapor deposition and their application in photovoltaic devices. RSC Advances 2:3225
Sutter P (2009) How silicon leaves the scene. Nat Mater 8:171
Kageshima H, Hibino H, Tanabe S (2012) The physics of epitaxial graphene on SiC(0001). J Phys: Condens Matter 24:314215
Badami DV (1962) Graphitization of α-silicon carbide. Nature 193:569
Zhou SY, G–H G, Graf J, Fedorav AV, Spataru CD, Diehl RD, Kopelevich Y, D–H L, Louie SG, Lanzara A (2006) First direct observation of dirac Fermions in graphite. Nat Phys 2:595
Ohta T, Bostwick A, McChesney JL, Seyller T, Horn K, Rotenberg E (2007) Interlayer interaction and electronic screening in multilayer graphene investigated with angle-resolved photoemission spectroscopy. Phys Rev Lett 98:206802
Kageshima H, Hibino H, Yamaguchi H, Nagase M (2011) Theoretical study on epitaxial graphene growth by Si sublimation from SiC (0001) surface. Jpn J Appl Phys 50:095601
Dmitriev AN, Cherednichenko DI (2011) Formation of graphene layers by vacuum sublimation of silicon carbide using a scanning heat source. Semiconductors 45:1656
Hibino H, Kageshima H, Maeda F, Nagase M, Kobayasi Y, Yamaguchi H (2008) Microscopic thickness determination of thin graphite films formed on SiC from quantized oscillation in reflectivity of low-energy electrons. Phys Rev B 77:075413
Hibino H, Tanabe S, Mizuno S, Kageshima H (2012) Growth and electronic transport properties of epitaxial graphene on SiC. J Phys D:Appl Phys 45:154008
Kim K, Park J, Kim C, Choi W, Seo Y, Ahn J, Park I-S (2012) Removing graphite flakes for preparing mechanically exfoliated graphene sample. Micro Nano Lett 7:1133
Jayasena B, Reddy CD, Subbiah S (2013) Separation, folding and shearing of graphene layers during wedge-based mechanical exfoliation. Nanotechnology 24:205301
Cai D, Song M (2007) Preparation of fully exfoliated graphite oxide nanoplatelets in organic solvents. J Mater Chem 17:3678
Israelachvili J (2011) Intermolecular and surface force, 3rd edn. Academic, Boston
Paredes JI, Villar-Rodil S, Martinez-Alonso A, Tascon JMD (2008) Graphene oxide dispersions in organic solvents. Langmuir 24:10564
Liu W, Wang JN (2011) Direct exfoliation of graphene in organic solvents with addition of NaOH. Chem Commun 47:6888
Pei S, Cheng H-M (2012) The reduction of graphene oxide. Carbon 50:3210
Srivastava PK, Ghosh S (2013) Eliminating defects from graphene monolayers during chemical exfoliation. Appl Phys Lett 102:043102
Schniepp HC, J–L L, McAllister MJ, Sai H, Alonso MH, Adamson DH, Prud’homme RK, Car R, Saville DA, Aksay IA (2006) Functionalized single graphene sheets derived from splitting graphite oxide. J Phys Chem B 110:8535
McAllister MJ, Li JL, Adamson DH, Schnlepp HC, Abdalam AA, Liu J, Aksay IA (2007) Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater 19:4396
Chen W, Yan L (2010) Preparation of graphene by a low-temperature thermal reduction at atmosphere pressure. Nanoscale 2:559
Liu X, Kim H, Guo LJ (2013) Optimization of thermally reduced graphene oxide for an efficient hole transport layer in polymer solar cells. Organ Electron 14:591
Park O-K, Hahm MG, Lee S, Joh HI, Na SI, Vajtai R, Lee JH, Ku B-C, Ajayan PM (2012) In situ synthesis of thermochemically reduced graphene oxide conducting nanocomposites. Nano Lett 12:1789
Al-Temimy A, Riedl C, Starke U (2009) Low temperature growth of epitaxial graphene on SiC induced by carbon evaporation. Appl Phys Lett 95:231907
Hackley J, Ali D, DiPasquale J, Demaree JD, Richardson CJK (2009) Graphitic carbon growth on Si(111) using solid source molecular beam epitaxy. Appl Phys Lett 95:133114
Garcia JM, He R, Jiang MP, Yan J, Pinczuk A, Zuev YM, Kim KS, Kim P, Baldwin K, West KW, Pfeiffer LN (2010) Multilayer graphene films grown by molecular beam deposition. Solid State Commun 150:809
Garcia JM, Wurstbauer U, Levy A, Pfeiffer LN, Pinczuk A, Plaut AS, Wang L, Dean CR, Buizza R, Van Der Zande AM, Hone J, Watanabe K, Taniguchi T (2012) Graphene growth on h-BN by molecular beam epitaxy. Solid State Commun 152:975
Li J-L, Kudin KN, McAllister MJ, Prud’homme RK, Aksay IA, Car P (2006) Oxygen-driven unzipping of graphitic materials. Phys Rev Lett 96:176101
Ajayan PM, Yakobson BI (2006) Oxygen breaks into carbon world. Nature 441:818
Kosynkin DV, Higginbotham AL, Sinitskii A, Lomeda JR, Dimiev A, Price BK, Tour JM (2009) Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature 458:872
Jiao L, Zhang L, Wang X, Diankov G, Dai H (2009) Narrow graphene nanoribbons from carbon nanotubes. Nature 458:877
Zhuang N, Liu C, Jia L, Wei L, Cai J, Guo Y, Zhang Y, Hu X, Chen J, Chen X, Tang Y (2013) Clean unzipping by steam etching to synthesize graphene nanoribbons. Nanotechnology 24:325604
Iwai H (2009) Roadmap for 22 nm and beyond. Microelectron Eng 86:1520–1528
Wang C, Takei K, Takahashi T, Javey A (2013) Carbon nanotube electronics–moving forward. Chem Soc Rev 42:2592
Charlier J-C, Blase X, Roche S (2007) Electronic and transport properties of nanotubes. Rev Mod Phys 79:677–732
Javey A, Guo J, Wang Q, Lundstrom M, Dai H (2003) Ballistic carbon nanotube transistors. Nature 424:654–657
Bradley K, Gabriel JCP, Star A, Gruner G (2003) Short-channel effects in contact-passivated nanotube chemical sensors. Appl Phys Lett 83:3821
Ionescu AM, Riel H (2011) Tunnel field-effect transistors as energy-efficient electronic switches. Nature 479:329
Jensen K, Weldon J, Garcia H, Zettl A (2007) Nanotube radio. Nano Lett 7:3508
Franklin AD, Luisier M, Han SJ, Tulevski G, Breslin CM, Gignac L, Lundstrom MS, Haensch W (2012) Sub – 10 nm carbon nanotube transistor. Nano Lett 12:758
Cao Q, Rogers JA (2009) Ultrathin films of single-walled carbon nanotubes for electronics and sensors: a review of fundamental and applied aspects. Adv Mater 21:29
Park H, Afzali A, Han S-J, Tulevski GS, Franklin AD, Tersoff J, Hannon JB, Haensch W (2012) High-density integration of carbon nanotubes via chemical self-assembly. Nat Nanotechnol 7:787–791
Snow ES, Campbell PM, Ancona MG, Novak JP (2005) High-mobility carbon-nanotube thin film transistors on a polymeric substrate. Appl Phys Lett 86:033105
Sun DM, Timmermans MY, Tian Y, Nasibulin AG, Kauppinen EI, Kishimoto S, Mizutani T, Ohno Y (2011) Flexible high-performance carbon nanotube integrated circuits. Nat Nanotechnol 6:156
McCarthy MA, Liu B, Donoghue EP, Kravchenko I, Kim DY, So F, Rinzler AG (2011) Low-voltage, low-power, organic light-emitting transistors for active matrix displays. Science 332:570
van der Veen MH, Vereecke B, Sugiura M, Kashiwagi Y, Ke X, Cott DJ, Vanpaemel JKM, Vereecken PM, Gendt SD, Huyghebaert C, Tökei Z (2012) Electrical and structural characterization of 150 nm CNT contacts with Cu damascene top metallization. In: Paper presented at the 2012 I.E. international interconnect technology conference (IITC), San Jose, 4 to 6 June 2012
Rinzler AG, Hafner JH, Nikolaev P, Nordlander P, Colbert DT, Smalley RE, Lou L, Kim SG, Tománek D (1995) Unraveling nanotubes: field emission from an atomic wire. Science 269:1550–1553
Saito Y, Uemura S (2000) Field emission from carbon nanotubes and its applications to electron sources. Carbon 38:169–182
Modi A, Koratkar N, Lass E, Wei B, Ajayan PM (2003) Miniaturized gas ionization sensors using carbon nanotubes. Nature 424:171
Bower C, Zhu W, Shalom D, Lopez D, Chen LH, Gammel PL, Jin S (2002) On-chip vacuum microtriode using carbon nanotube field emitters. Appl Phys Lett 80:3820
Choi WB, Jin YW, Kim HY, Lee SJ, Yun MJ, Kang JH, Choi YS, Park NS, Lee NS, Kim JM (2001) Electrophoresis deposition of carbon nanotubes for triode-type field emission display. Appl Phys Lett 1547:78
Choi WB, Lee YH, Chung DS, Lee NS, Kim JM (2000) Field emission from 4.5˝ single-walled and multi-walled carbon nanotube films. J Vac Sci Tech B 18(2):1054–1058
Cheng Y, Zhou O (2003) Electron field emission from carbon nanotubes. CR Phys 4:1021
Bonard JM, Salvetat JP, Stockli T, Deheer WA, Forro L, Chatelain A (1998) Field emission from single-wall carbon nanotube film. Appl Phys Lett 73:918–920
Seko K, Kinoshita J, Saito Y (2005) In situ transmission electron microscopy of field-emitting bundles of double wall carbon nanotubes. Jpn J Appl Phys 44:L743–L745
Son Y-W, Oh S, Ihm J, Han S (2005) Field emission properties of double-wall carbon nanotubes. Nanotechnol 16:125–128
Hiraoka T, Yamada T, Hata K, Futaba DN, Kurachi H, Uemura S, Yumura M, Iijima S (2006) Synthesis of single and double walled carbon nanotubes forests on conducting metal foils. J Am Chem Soc 128:13338–13339
Charlier J-C, Terrones M, Baxendale M, Meunier V, Zacharia T, Ru-pesinghe NL, Hsu WK, Grobert N, Terrones H, Amaratunga GAJ (2002) Enhanced electron field emission in B-doped carbon nanotubes. Nano Lett 2:1191
Golberg D, Dorozhkin PS, Bando Y, Dong ZC, Tang CC, Uemura Y, Grobert N, Reyes-Reyes M, Terrones H, Terrones M (2003) Structure, transport and field-emission properties of compound nanotubes: CNx vs. BNCx (x < 0.1). Appl Phys A Mater 76:499
Doytcheva M, Kaiser M, Reyes-Reyes M, Terrones M, de Jonge N (2004) Electron emission from individual nitrogen-doped multi-walled carbon nanotubes. Chem Phys Lett 396:126
Lahiri I, Seelaboyina R, Hwang JY, Banerjee R, Choi W (2010) Enhanced field emission from multi-walled carbon nanotubes grown on pure copper substrate. Carbon 48:1531–1538
Seelaboyina R, Huang J, Choi WB (2006) Enhanced field emission of thin-multiwall carbon nanotubes by electron multiplication from microchannel plate. Appl Phys Lett 88:194104
Seelaboyina R, Bodepalli S, Noh K, Jeon M, Choi W (2008) Enhanced field emission from aligned multistage carbon nanotube emitter arrays. Nanotechnology 19:065605
Dai L, Chang DW, Baek J-B, Lu W (2012) Carbon nanomaterials for advanced energy conversion and storage. Small 8:1130
Evanoff K, Khan J, Balandin AA, Magasinski A, Ready WJ, Fuller TF, Yushin G (2012) Towards ultrathick battery electrodes: aligned carbon nanotube-enabled architecture. Adv Mater 24:533
Verma VP, Das S, Lahiri I, Choi W (2010) Large-area graphene on polymer film for flexible and transparent anode in field emission device. Appl Phys Lett 96:203108
Lahiri I, Oh SW, Hwang JY, Cho S, Sun YK, Banerjee R, Choi W (2010) High capacity and excellent stability of lithium ion battery anode using interface-controlled binder-free multiwall carbon nanotubes grown on copper. ACS Nano 4(6):3440–3446
Lahiri I, Das S, Kang C, Choi W (2011) Application of carbon nanostructures – energy to electronics. JOM 63:70
Leroux F, Metenier K, Gautier S, Frackowiak E, Bonnamy S, Beguin F (1999) Electrochemical insertion of lithium in catalytic multi-walled carbon nano-tubes. J Power Sources 81:317–322
Claye AS, Fischer JE, Huffman CB, Rinzler AG, Smalley RE (2000) Solid-state electrochemistry of the Li single wall carbon nanotube system. J Electrochem Soc 147:2845–2852
Sato M, Noguchi A, Demachi N, Oki N, Endo M (1994) A mechanism of lithium storage in disordered carbons. Science 264:556–558
Endo M, Kim YA, Hayashi T, Nishimura K, Matsushita T, Miyashita K, Dresselhaus MS (2001) Vapor-grown carbon fibers (VGCFs) basic properties and battery application. Carbon 39:1287–1297
An KH, Kim WS, Park YS, Moon JM, Bae DJ, Lim SC, Lee YS, Lee YH (2001) Electrochemical properties of high-power supercapacitors using single-walled carbon nanotube electrodes. Adv Funct Mater 11:387–392
Matsumoto T, Komatsu T, Arai K, Yamazaki T, Kijima M, Shimizu H, Takasawab Y, Nakamura J (2004) Reduction of Pt usage in fuel cell electrocatalysts with carbon nanotube electrodes. Chem Commun 2004:840–841
Goff AL, Artero V, Jousselme B, Tran PD, Guillet N, Métayé R, Fihri A, Palacin S, Fontecave M (2009) From hydrogenases to noble metal -free catalytic nanomaterials for H2 production and uptake. Science 326:1384–1387
Lee JM, Park JS, Lee SH, Kim H, Yoo S, Kim SO (2011) Selective electron-or hole-transport enhancement in bulk-heterojunction organic solar cells with N-or B-doped carbon nanotubes. Adv Mater 23:629
Xu ZH, Wu Y, Hu B, Ivanov IN, Geohegan DB (2005) Carbon nanotubes effects on electroluminescence and photovoltaic response in conjugated polymers. Appl Phys Lett 87:263118
Gabor NM, Zhong Z, Bosnick K, Park J, McEuen PL (2009) Extremely efficient multiple electron – hole pair generation in carbon nanotube photodiodes. Science 325:1367
Kam NWS, Jessop TC, Wender PA, Dai HJ (2004) Nanotube molecular transporters: internalization of car bon nanotube-protein conjugates into mammalian cells. J Am Chem Soc 126:6850–6851
Bianco A, Kostarelos K, Partido CD, Prato M (2005) Biomedical applications of functionalised carbon nanotubes. Chem Commun 5:571–577
Kam NWS, O’Connell M, Wisdom JA, Dai H (2005) Carbon nanotubes as multifunctional biological transporters and near-infrared agents for selective cancer cell destruction. Proc Natl Acad Sci USA 102:11600–11605
Zerda ADL, Zavaleta C, Keren S, Vaithilingam S, Bodapati S, Liu Z, Levi J, Ma T-J, Oralkan O, Cheng Z (2008) Photoacoustic molecular imaging in living mice utilizing targeted carbon nanotubes. Nat Nanotech 3:557–562
Welsher K, Liu Z, Daranciang D, Dai H (2008) Selective probing and imaging of cells with single walled carbon nanotubes as near-infrared fluorescent molecules. Nano Lett 8:586–590
Cherukuri P, Gannon CJ, Leeuw TK, Schmidt HK, Smalley RE, Curley SA, Weisman RB (2006) Mammalian pharmacokinetics of carbon nanotubes using intrinsic near-infrared fluorescence. Proc Natl Acad Sci USA 103:18882–18886
Heller DA, Baik S, Eurell TE, Strano MS (2005) Single-walled carbon nanotube spectroscopy in live cells: towards long-term labels and optical sensors. Adv Mater 17:2793–2799
Kam NWS, Liu Z, Dai HJ (2005) Functionalization of carbon nanotubes via cleavable disulfide bonds for efficient intracellular delivery of siRNA and potent gene silencing. J Am Chem Soc 127:12492–12493
Roy S, Vedala H, Prasad V, Choi W (2006) Vertically aligned multiwall carbon nanotube bioprobes on silicon platform for cholesterol detection. Nanotechnology 17:S14–S18
Hong SY, Tobias G, Jamal KTA, Ballesteros B, Boucetta HA, Perez SL, Nellist PD, Sim RB, Finucane C, Mather SJ, Green ML, Kostarelos K, Davis BG (2010) Filled and glycosylated carbon nanotubes for in vivo radioemitter localization and imaging. Nat Mater 9:485
Liu Z, Sun X, Ratchford NN, Dai H (2007) Supramolecular chemistry on water-soluble carbon nanotubes for drug loading and delivery. ACS Nano 1(1):50–56
Bianco A, Kostarelos K, Prato M (2011) Making carbon nanotubes biocompatible and biodegradable. Chem Commun 47:10182
Cai D, Mataraza JM, Qin ZH, Huang Z, Huang J, Chiles TC, Carnahan D, Kempa K, Ren Z (2005) Highly efficient molecular delivery into mammalian cells using carbon nanotube spearing. Nat Method 2:449–454
Roy S, Vedala H, Roy A, Kim D, Doud M, Mathee K, Shin H, Shimamoto N, Prasad V, Choi W (2008) Direct electrical measurements on single-molecule genomic DNA using single-walled carbon nanotubes. Nano Lett 8:26–30
Vedala H, Roy S, Doud M, Mathee K, Choi W (2008) The effect of environmental factors on the electrical conductivity of a single oligo-DNA molecule measured using single-walled carbon nanotube nanoelectrodes. Nanotechnology 19:265704
Meric I, Han MY, Young AF, Ozyilmaz B, Kim P, Shepard KL (2008) Current saturation in zero-bandgap, top-gated graphene field-effect transistors. Nat Nanotechnol 3:654–659
Barone V, Hod O, Scuseria GE (2006) Electronic structure and stability of semiconducting graphene nanoribbons. Nano Lett 6:2748
Liang GC, Neophytou N, Nikonov DE, Lund-strom MS (2007) Performance projections for ballistic graphene nanoribbon field-effect transistors. IEEE Trans Electron Dev 54:677
Chen Z, Lin YM, Rooks MJ, Avouris P (2007) Graphene nano-ribbon electronics. Physica E 40:228
Obradovic B, Kotlyar R, Heinz F, Matagne P, Rakshit T, Giles MD, Stettler MA (2006) Analysis of graphene nanoribbons as a channel material for field-effect transistors. Appl Phys Lett 88:142102
Ohta T, Bostwick A, Seyller T, Horn K, Rotenberg E (2006) Controlling the electronic structure of bilayer graphene. Science 313:951
Bai J, Duan X, Huang Y (2009) Rational fabrication of graphene nanoribbons using a nanowire etch mask. Nanoletters 9:2083
Tseng F, Unluer D, Holcomb K, Stan MR, Ghosh AW (2009) Diluted chirality dependence in edge rough graphene nanoribbons field-effect transistors. Appl Phys Lett 94:223112
Farmer DB, Mojarad RG, Perebeinos V, Lin YM, Tulevski GS, Tsang JC, Avouris P (2009) Chemical doping and electron–hole conduction asymmetry in graphene devices. Nanoletters 9:388
Ouyang Y, Wang X, Dai H, Guo J (2008) Carrier scattering in graphene nanoribbon field-effect transistors. Appl Phys Lett 92:243124
Ryzhii V, Ryzhii M, Otsuji T (2008) Thermionic and tunneling transport mechanisms in graphene field-effect transistors. Phys Stat Sol (a) 205(1527)
Ryzhii V, Ryzhii M, Satou A, Otsuji T (2008) Current–voltage characteristics of a graphene-nanoribbon field-effect transistor. J Appl Phys 103:094510
Wang X, Zhi L, Mullen K (2008) Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nanoletters 8:323
Han T-H, Lee Y, Choi MR, Woo SH, Bae SH, Hong BH, Ahn JH, Lee TW (2012) Extremely efficient flexible organic light emitting diodes with modified graphene anode. Nat Photonics 6:105–110
Gomez DAL, Zhang Y, Schlenker CW, Ryu K, Thompson ME, Zhou C (2010) Continuous, highly flexible, and transparent graphene films by chemical vapor deposition for organic photovoltaics. ACS Nano 4:2865
Li S, Tu KH, Lin CC, Chen CW, Chhowalla M (2010) Solution-process-able graphene oxide as an efficient hole transport layer in polymer solar cells. ACS Nano 4:3169
Liao L, Lin Y-C, Duan X (2010) High speed graphene transistors with a self-aligned nanowire gate. Nature 467:305
Moon JS, Curtis D, Hu M, Wong D, McGuire C, Campbell PM, Jernigan G, Tedesco JL, VanMil B, Myers-Ward R, Eddy C Jr, Gaskill DK (2009) Epitaxial-graphene RF field-effect transistors on Si-face 6H-SiC substrates. IEEE Electron Device Lett 30:650–652
Lin Y-M, Dimitrakopoulos C, Jenkins KA, Farmer DB, Chiu H-Y, Grill A, Avouris P (2010) 100-GHz transistors from wafer-scale epitaxial graphene. Science 327:662
Szafranek BN, Fiori G, Schall D, Neumaier D, Kurz H (2012) Current saturation and voltage gain in bilayer graphene field effect transistors. Nano Lett 12:1324
Rangel NL, Gimenez A, Sinitskii A, Seminario JM (2011) Graphene signal mixer for sensing applications. J Phys Chem C 115(24):12128–12134
Wang H, Nezich D, Kong J, Palacios T (2009) Graphene frequency multipliers. IEEE Electron Device Lett 30:547–549
Wang Z, Zhang Z, Xu H, Ding L, Wang S, Peng L-M (2010) A high-performance top-gate graphene field-effect transistor based frequency doubler. Appl Phys Lett 96:173104
Milaninia KM, Baldo MA, Reina A, Kong J (2009) All graphene electromechanical switch fabricated by chemical vapor deposition. Appl Phys Lett 95:183105
Schedin F, Geim AK, Morozov SV, Hill EW, Blake P, Katsnelson MI, Novoselov KS (2007) Detection of individual gas molecules adsorbed on graphene. Nat Mater 6:652
Fowler JD, Allen MJ, Tung VC, Yang Y, Kaner RB, Weiller BH (2009) Practical chemical sensors from chemically derived graphene. ACS Nano 3:201
Sundaram RS, Navarro CG, Balasubramaniam K, Burghard M, Kern K (2008) Electrochemical modification of graphene. Adv Mater 20:3050
Lu J, Do I, Drzal LT, Worden RM, Lee I (2008) Nanometal-decorated exfoliated graphite nanoplatelet based glucose biosensors with high sensitivity and fast response. ACS Nano 2:1825–1832
Huang B, Li Z, Liu Z, Zhou G, Hao S, Wu J, Gu B-L, Duan W (2008) Adsorption of gas molecules on graphene nanoribbons and its implication for nanoscale molecule sensor. J Phys Chem C 112:13442–13446
Shan C, Yang H, Song J, Han D, Ivaska A, Niu L (2009) Direct electrochemistry of glucose oxidase and biosensing for glucose based on graphene. Anal Chem 81:2378
Alwarappan S, Erdem A, Liu C, Li CZ (2009) Probing the electrochemical properties of graphene nanosheets for biosensing applications. J Phys Chem C 113:8853
Li J, Guo S, Zhai Y, Wang E (2009) Nafion–graphene nanocomposite film as enhanced sensing platform for ultrasensitive de-termination of cadmium. Electrochem Commun 11(1085)
Bae S-H, Lee Y, Sharma BK, Lee HJ, Kim J-H, Ahn J-H (2013) Graphene-based transparent strain sensor. Carbon 51:236–242
Lee Y, Bae S, Jang H, Jang S, Zhu S-E, Sim SH, Song Y, Hong BH, Ahn J-H (2010) Wafer-scale synthesis and transfer of graphene films. Nano Lett 10(2):490–493
Fu X-W, Liao Z-M, Zhou JX, Zhou YB, Wu HC, Zhang R (2011) Strain dependent resistance in chemical vapor deposition grown graphene. Appl Phys Lett 99(21):213107
Wang Y, Yang R, Shi Z, Zhang L, Shi D, Wang E, Zhang G (2011) Super-elastic graphene ripples for flexible strain sensors. ACS Nano 5(5):3645–3650
Smith AD, Niklaus F, Paussa A, Vaziri S, Fischer AC, Sterner M, Forsberg F, Delin A, Esseni D, Palestri P, Palestri P, Palestri P, Ostling M, Lemme MC (2013) Electromechanical piezoresistive sensing in suspended graphene membranes. Nano Lett 13:3237–3242
Hierold C, Jungen A, Stampfer C, Helbling T (2007) Nano electromechanical sensors based on carbon nanotubes. Sens Actuators A 136(1):51–61
Kalvesten E, Smith L, Tenerz L, Stemme G (1998) The first surface micromachined pressure sensor for cardiovascular pressure measurements. In Proceedings 11th Annu. Int. Workshop on Micro Electro Mech Syst 574–579
Lee SW, Lee SS, Yang EH (2009) A study on field emission characteristics of planar graphene layers obtained from a highly oriented pyrolyzed graphite block. Nanoscale Res Lett 4:1218–1221
Koh ATT, Foong YM, Pan L, Sun Z, Chua DHC (2012) Effective large-area free-standing graphene field emitters by electrophoretic deposition. Appl Phys Lett 101:183107
Malesevic A, Kemps R, Vanhulsel A, Chowdhury MP, Volodin A, Haesendonck CV (2008) Field emission from vertically aligned few-layer graphene. J Appl Phys 104:084301
Geim AK, Kim P (2008) Carbon wonderland. Sci Am 298:90
Eda G, Unalan HE, Rupesinghe N, Amartunga GAJ, Chhowalla M (2008) Field emission from graphene based composite films. Appl Phys Lett 93:233502
Wu ZS, Pei S, Ren W, Tang D, Gao L, Liu B, Li F, Liu C, Cheng HM (2009) Field emission from single layer graphene films prepared by electrophoretic deposition. Adv Mater 21:1756
Lahiri I, Verma VP, Choi W (2011) An all-graphene based transparent and flexible field emission device. Carbon 49(5):1614–1619
Watcharotone S, Ruoff RS, Read FH (2008) Possibilities for graphene for field emission: modeling studies using the BEM. Phys Procedia 1:71
Babenko AY, Dideykin AT, Eidelman ED (2009) Graphene ladder: a model of field emission center on the surface of loose nanocarbon materials. Phys Solid State 51:435
Yoo E, Kim J, Hosono E, Zhou H, Kudo T, Honma I (2008) Large reversible li storage of graphene nanosheet families for use in rechargeable lithium ion batteries. Nano Lett 8:2277
Xiang HF, Li ZD, Xie K, Jiang JZ, Chen JJ, Lian PC, Wu JS, Yud Y, Wang HH (2012) Graphene sheets as anode materials for Li-ion batteries: preparation, structure, electrochemical properties and mechanism for lithium storage. RSC Adv 2:6792–6799
Paek S-M, Yoo EJ, Honma I (2009) Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three dimensionally delaminated flexible structure. Nano Lett 9:72
Wang D, Choi D, Li J, Yang Z, Nie Z, Kou R, Hu D, Wang C, Saraf LV, Zhang J, Aksay IA, Jiu J (2009) Self-assembled TiO2-graphene hybrid nanostructures for enhanced Li-ion insertion. ACS Nano 3:907
Xie J, Song W, Zheng Y, Liu S, Zhu T, Cao G, Zhao X (2011) Preparation and Li-storage properties of SnSb/graphene hybrid nanostructure by a facile one-step solvothermal route. Int J Smart Nano Mat 2(4):261–271
Xiao JD, Mei D, Li X, Xu W, Wang D, Graff GL, Bennett WD, Nie Z, Saraf LV, Aksay IA, Liu J, Zhang JG (2011) Hierarchically porous graphene as a lithium-air battery electrode. Nano Lett 11(11):5071–5078
Xu C, Wang X, Zhu J (2008) Graphene-metal particle nanocomposites. J Phys Chem C 112:19841–19845
Seger B, Kamat PV (2009) Electrocatalytically active graphene-platinum nanocomposites. Role of 2-D carbon support in PEM fuel cells. J Phys Chem C 113:7990–7995
Kou R, Shao YY, Wang DH, Engelhard MH, Kwak JH, Wang J, Viswanathan VV, Wang CM, Lin YH, Wang Y, Aksay IA, Liu J (2009) Enhanced activity and stability of Pt catalysts on functionalized graphene sheets for electrocatalytic oxygen reduction. Electrochem Commun 11:954
Jafri RI, Rajalakshmi N, Ramaprabhu S (2010) Nitrogen doped graphene nanoplatelets as catalyst support for oxygen reduction reaction in proton exchange membrane fuel cell. J Mater Chem 20:7114
Wu J, Becerril HA, Bao Z, Liu Z, Chen Y, Peumans P (2008) Organic solar cells with solution-processed graphene transparent electrodes. Appl Phys Lett 92:263302–263304
Eda G, Lin YY, Miller S, Chen CW, Su WF, Chhowalla M (2008) Transparent and conducting electrodes for organic electronics from reduced graphene oxide. Appl Phys Lett 92:233305–233307
Hong W, Xu Y, Lu G, Li C, Shi G (2008) Transparent graphene/PEDOT-PSS composite films as counter electrodes of dye-sensitized solar cells. Electrochem Comm 10:1555–1558
Li X, Zhu H, Wang K, Cao A, Wei J, Li C, Jia Y, Li Z, Li X, Wu D (2010) Graphene-on-silicon schottky junction solar cells. Adv Mater 22:2743–2748
Ye Y, Dai Y, Dai L, Shi Z, Liu N, Wang F, Fu L, Peng R, Wen X, Chen Z, Liu Z, Qin G (2010) High-oerformance single CdS nanowire (nanobelt) schottky junction solar cells with Au/Graphene Schottky electrodes. ACS Appl Mater Interfaces 2:3406–3410
Gratzel M (2001) Photoelectrochemical cells. Nature 414:338–344
Grätzel M (2004) Conversion of sunlight to electric power by nanocrystalline dye-sensitized solar cells. J Photochem Photobiol A Chem 164:3–14
Trancik JE, Barton SC, Hone J (2008) Transparent and catalytic carbon nanotube films. Nano Lett 8:982–987
Li GR, Wang F, Jiang QW, Gao XP, Shen PW (2010) Carbon nanotubes with titanium nitride as a low-cost counter-electrode material for dye-sensitized solar cells. Angew Chem Int Ed 49:3653–3656
Das S, Sudhagar P, Verma V, Song D, Ito E, Lee SY, Kang YS, Choi W (2011) Amplifying charge-transfer characteristics of graphene for triiodide reduction in dye-sensitized solar cells. Adv Funct Mater 21:3729–3736
Das S, Sudhagar P, Nagarajan S, Ito E, Lee SY, Kang YS, Choi W (2012) Synthesis of graphene-CoS electro-catalytic electrodes for dye sensitized solar cells. Carbon 50:4815–4821
Das S, Sudhagar P, Ito E, Lee DY, Nagarajan S, Lee SY, Kang YS, Choi W (2012) Effect of HNO3 functionalization on large scale graphene for enhanced tri-iodide reduction in dye-sensitized solar cells. J Mater Chem 22:20490–20497
Li D, Müller MB, Gilje S, Kaner RB, Wallace GG (2008) Processable aqueous dispersions of graphene nanosheets. Nat Nanotechnol 3:101
Sofo JO, Chaudhari AS, Barber GD (2007) Graphane: a two dimensional hydrocarbon. Phys Rev B 75:153401
U.S. Department of Energy. Energy efficiency and renewable energy. http://www1.eere.energy.gov/hydrogenandfuelcells/storage/current_technology.html
Ao ZM, Peeters FM (2010) High-capacity hydrogen storage in Al-adsorbed graphene. Phys Rev B 81:205406
Beheshti E, Nojeh A, Servati PA (2011) A first-principles study of calcium-decorated, boron-doped graphene for high capacity hydrogen storage. Carbon 49:1561–1567
Balog R, Jørgensen B, Wells J, Lægsgaard E, Hofmann P, Besenbacher F, Hornekær L (2009) Atomic hydrogen adsorbate structures on graphene. J Am Chem Soc 131:8744–8745
Goler S, Coletti C, Tozzini V, Piazza V, Mashoff T, Beltram F, Pellegrini V, Heun S (2013) Influence of graphene curvature on hydrogen adsorption: toward hydrogen storage devices. J Phys Chem C 117:11506–11513
Tozzini V, Pellegrini V (2011) Reversible hydrogen storage by controlled Buckling of graphene layers. J Phys Chem C 115:25523–25528
Boukhvalov DW, Katsnelson MI (2009) Enhancement of chemical activity in corrugated graphene. J Phys Chem C 113:14176–14178
Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, Piner RD, Nguyen ST, Ruoff RS (2006) Graphene-based composite materials. Nature 442:282
Dreyer DR, Park S, Bielawski CW, Ruoff RS (2010) The chemistry of graphene oxide. Chem Soc Rev 39:228–240
Chen T, Zeng B, Liu JL, Dong JH, Liu XQ, Wu Z, Yang XZ, Li ZM (2009) High throughput exfoliation of graphene oxide from expanded graphite with assistance of strong oxidant in modified Hummers method. J Phys: Conf Ser 188:012051
Zhou X, Huang X, Qi X, Wu S, Xue C, Boey FYC, Yan Q, Chen P, Zhang H (2009) In situ synthesis of metal nanoparticles on single-layer graphene oxide and reduced graphene oxide surfaces. J Phys Chem C 113:10842
Liu J, Bai H, Wang Y, Liu Z, Zhang X, Sun DD (2010) Self-assembling TiO2 nanorods on large graphene oxide sheets at a two-phase interface and their anti-recombination in photocatalytic applications. Adv Funct Mater 20:4175–4181
Shen J, Hu Y, Shi M, Li N, Ma H, Ye M (2010) One step synthesis of graphene oxide – magnetic nanoparticle composite. J Phys Chem C 114:1498–1503
Zhou H, Qiu C, Liu Z, Yang H, Hu L, Liu J, Yang H, Gu C, Sun L (2010) Thickness-dependent morphologies of gold on N-layer graphenes. J Am Chem Soc 132:944–946
Yu K, Lu G, Mao S, Chen K, Kim H, Wen Z, Chen J (2011) Selective deposition of CdSe nanoparticles on reduced graphene oxide to understand photoinduced charge transfer in hybrid nanostructures. ACS Appl Mater Interfaces 3:2703–2709
Meng X, Geng D, Liu J, Banis MN, Zhang Y, Li R, Sun X (2010) Non-aqueous approach to synthesize amorphous/crystalline metal oxide-graphene nanosheet hybrid composites. J Phys Chem C 114:18330–18337
Wang H, Cui L-F, Yang Y, Casalongue HS, Robinson JT, Liang Y, Cui Y, Dai H (2010) Mn3O4 – graphene hybrid as a high-capacity anode material for lithium Ion batteries. J Am Chem Soc 132:13978–13980
Yang S, Feng X, Ivanovici S, Mullen K (2010) Fabrication of graphene-encapsulated oxide nanoparticles: towards high-performance anode materials for lithium storage. Angew Chem Int Ed 49:8408–8411
Wang D, Kou R, Choi D, Yang Z, Nie Z, Li J, Saraf LV, Hu D, Zhang J, Graff GL, Liu J, Pope MA, Aksay IA (2010) Ternary self-assembly of ordered metal oxide – graphene nanocomposites for electrochemical energy storage. ACS Nano 4:1587–1595
Wu Q, Xu Y, Yao Z, Liu A, Shi G (2010) Supercapacitors based on flexible graphene/polyaniline nanofiber composite films. ACS Nano 4:1963–1970
Dong L, Gari RRS, Li Z, Craig MM, Hou S (2010) Graphene-supported platinum and platinum–ruthenium nanoparticles with high electrocatalytic activity for methanol and ethanol oxidation. Carbon 48:781–787
Zhang L-S, Liang X-Q, Song W-G, Wu Z-Y (2010) Identification of the nitrogen species on N-doped graphene layers and Pt/NG composite catalyst for direct methanol fuel cell. Phys Chem Chem Phys 12:12055–12059
Yu D, Yang Y, Durstock M, Baek J-B, Dai L (2010) Soluble P3HT-grafted graphene for efficient bilayer – heterojunction photovoltaic devices. ACS Nano 4:5633–5640
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Choudhary, N., Hwang, S., Choi, W. (2014). Carbon Nanomaterials: A Review. In: Bhushan, B., Luo, D., Schricker, S., Sigmund, W., Zauscher, S. (eds) Handbook of Nanomaterials Properties. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-31107-9_37
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