Abstract
Rapid coal pyrolysis is a very important step in the early stage of combustion. Rapid pyrolysis experiments of a brown coal at high temperature have been studied on a laminar drop tube furnace. The volatile mass release measured in this study is high for low rank coal. The activation energy and pre-exponential factor of pyrolysis are 19901.22 kJ/mol and 102.71, respectively. The nitrogen distribution between volatile and char is 0.54. With the increase of temperature, the yields of NH3 decreases, while those of HCN increases, leading the value of HCN/NH3 to become larger. At high temperature, the main nitrogen- containing species of pyrolysis in volatile is HCN.
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Acknowledgment
The authors greatly acknowledge the financial support for this research provided by the National High Technology Research and Development Program of China (No. 2007AA05Z336).
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Qian, L., Sun, S., Meng, S., Meng, X., Guo, Y. (2013). Experimental Study of Rapid Brown Coal Pyrolysis at High Temperature. In: Qi, H., Zhao, B. (eds) Cleaner Combustion and Sustainable World. ISCC 2011. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-30445-3_30
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DOI: https://doi.org/10.1007/978-3-642-30445-3_30
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