Skip to main content
SpringerLink
Log in
Book cover

Molecular Conformation and Organic Photochemistry pp 75–88Cite as

Paracyclophanes I: [2\(+\)2]cycloaddition of Ethylenes

  • Chapter
  • First Online:

  • 891 Accesses

Part of the book series: Springer Theses ((Springer Theses))

Abstract

This chapter presents the first of two studies of photochemical reaction dynamics. The first section reviews the fundamental issue related to studying bimolecular reactions with fs time-resolution. This is followed by a presentation of the time-resolved investigation of the [2+2]cycloaddition reaction, which was published in Ref. II. The experiments were carried out on the magnetic bottle spectrometer in Ottawa (Sect. 6.2.2 xx). Readers interested in specific experimental parameters not mentioned in this thesis are referred to the paper.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. Scherer, N.F., Sipes, C., Bernstein, R.B., Zewail, A.H.: J. Chem. Phys. 92, 5239–5259 (1990)

    Article  CAS  Google Scholar 

  2. Scherer, N.F., Khundkar, L.R., Bernstein, R.B., Zewail, A.H.: J. Chem. Phys. 87, 1451–1453 (1987)

    Article  CAS  Google Scholar 

  3. van Zee, R.D., Stephenson, J.C.: J. Chem. Phys. 102, 6946–6948 (1995)

    Article  Google Scholar 

  4. Miller, C.C., van Zee, R.D., Stephenson, J.C.: J. Chem. Phys. 114, 1214–1232 (2001)

    Article  CAS  Google Scholar 

  5. Wester, R., Bragg, A.E., Davis, A.V., Neumark, D.M.: J. Chem. Phys. 119, 10032–10039 (2003)

    Article  CAS  Google Scholar 

  6. Bondarenko, L., Hentschel, S., Greiving, H., Grunenberg, J., Hopf, H., Dix, I., Jones, P.G., Ernst, L.: Chem. Eur. J. 13, 3950–3963 (2007)

    Article  CAS  Google Scholar 

  7. Cadet, J., Vigny, P.: Chapter the photochemistry of nucleic acids. In: Morrison, H. (ed.) Bioorganic Photochemistry, vol. 1, pp. 1–272. John Wiley and Sons Inc., New York (1990)

    Google Scholar 

  8. Douki, T., Reynaud-Angelin, A., Cadet, J., Sage, E.: Biochemistry 42, 9221–9226 (2003)

    Article  CAS  Google Scholar 

  9. Taylor, J.S.: Acc. Chem. Res. 27, 76–82 (1994)

    Article  CAS  Google Scholar 

  10. Vink, A.A., Roza, L.: J. Photochem. Photobiol. B 65, 101–104 (2001)

    Google Scholar 

  11. Schreier, W.J., Schrader, T.E., Koller, F.O., Gilch, P., Crespo-Herná¡ndez, C.E., Swaminathan, V.N., Carell, T., Zinth, W., Kohler, B.: Science 315, 625–629 (2007)

    Article  CAS  Google Scholar 

  12. Caramori, G.F., Galembeck, S.E., Laali, K.K.: J. Org. Chem. 70, 3242–3250 (2005)

    Article  CAS  Google Scholar 

  13. Henseler, D., Hohlneicher, G.: J. Phys. Chem. A 102, 10828–10833 (1998)

    Article  CAS  Google Scholar 

  14. Hope, H., Bernstein, J., Trueblood, K.N.: Acta Crystallogr. Sect. B: Struct. Crystallogr. Cryst. Chem. 28, 1733–1743 (1972)

    Article  CAS  Google Scholar 

  15. Kobayashi, T., Yokota, K., Nagakura, S.: J. Electron Spectrosc. Relat. Phenom. 2, 449–454 (1973)

    CAS  Google Scholar 

  16. Heilbronner, E., Yang, Z.-Z.: The electronic structure of cyclophanes as suggested by their photoelectron spectra. In: Vögtle, F. (ed.) Topics in Current Chemistry, vol. 115, pp. 1–55 (1983)

    Google Scholar 

  17. Ribblett, J.W., Borst, D.R., Pratt, D.W.: J. Chem. Phys. 111, 8454–8461 (1999)

    Article  CAS  Google Scholar 

  18. Bernardi, F., De, S., Olivucci, M., Robb, M.A.: J. Am. Chem. Soc. 112, 1737–1744 (1990)

    Article  CAS  Google Scholar 

  19. Dallos, M., Lischka, H., Shepard, R., Yarkony, D.R., Szalay, P.G.: J. Chem. Phys. 120, 7330–7339 (2004)

    Article  CAS  Google Scholar 

  20. Lee, A.M.D., Coe, J.D., Ullrich, S., Ho, M.-L., Lee, S.-J., Cheng, B.-M., Zgierski, M.Z., Chen, I.-C., Martinez, T.J., Stolow, A.: J. Phys. Chem. A 111, 11948–11960 (2007)

    Article  CAS  Google Scholar 

  21. Yang, Z., Heilbronner, E., Hopf, H., Ehrhardt, S., Hentschel, S.: J. Phys. Chem. 92, 914–917 (1988)

    Article  Google Scholar 

  22. Lee, S.-H., Tang, K.-C., Chen, I.-C., Schmitt, M., Shaffer, J.P., Schultz, T., Underwood, J.G., Zgierski, M.Z., Stolow, A.: J. Phys. Chem. A 106, 8979–8991 (2002)

    Article  CAS  Google Scholar 

  23. Radloff, W., Freudenberg, T., Ritze, H.H., Stert, V., Noack, F., Hertel, I.V.: Chem. Phys. Lett. 261, 301–306 (1996)

    Article  CAS  Google Scholar 

  24. Lasorne, B., Sicilia, F., Bearpark, M.J., Robb, M.A., Worth, G.A., Blancafort, L.: J. Chem. Phys. 128, 124307 (2008)

    Article  Google Scholar 

  25. Diau, E.W.-G., Kötting, C., Sølling, T.I., Zewail, A.H.: Chem. Phys. Chem 3, 57–78 (2002)

    Article  CAS  Google Scholar 

  26. Sølling, T.I., Diau, E.W.-G., Kötting, C., Feyter, S.D., Zewail, A.H.: Chem. Phys. Chem 3, 79–97 (2002)

    Article  Google Scholar 

  27. Schalk, O., Boguslavskiy, A.E., Stolow, A.: J. Phys. Chem. A 114, 4058–4064 (2010)

    Article  CAS  Google Scholar 

  28. Crespo-Herná¡ndez, C.E., Cohen, B., Hare, P.M., Kohler, B.: Chem. Rev. 104, 1977–2020 (2004)

    Article  Google Scholar 

  29. Ullrich, S., Schultz, T., Zgierski, M.Z., Stolow, A.: Phys. Chem. Chem. Phys. 6, 2796–2801 (2004)

    Article  CAS  Google Scholar 

  30. Ullrich, S., Schultz, T., Zgierski, M.Z., Stolow, A.: J. Am. Chem. Soc. 126, 2262–2263 (2004)

    Article  CAS  Google Scholar 

  31. Nielsen, S.B., Sølling, T.I.: ChemPhysChem 6, 1276–1281 (2005)

    Article  CAS  Google Scholar 

  32. Satzger, H., Townsend, D., Zgierski, M., Patchkovskii, S., Ullrich, S., Stolow, A.: Proc. Natl. Acad. Sci. U. S. A. 103, 10196–10201 (2006)

    Article  CAS  Google Scholar 

  33. Hudock, H.R., Levine, B.G., Thompson, A.L., Satzger, H., Townsend, D., Gador, N., Ullrich, S., Stolow, A., Martínez, T.J.: J. Phys. Chem. A 111, 8500–8508 (2007)

    Article  CAS  Google Scholar 

  34. Middleton, C.T., de La Harpe, K., Su, C., Law, Y.K., Crespo-Hernández, C.E., Kohler, B.: Annu. Rev. Phys. Chem. 60, 217–239 (2009)

    Article  CAS  Google Scholar 

  35. Bisgaard, C.Z., Satzger, H., Ullrich, S., Stolow, A.: ChemPhysChem 10, 101–110 (2009)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, SUNCAT Center for Interface Science and Catalysis, Stanford University, Stanford, CA, 94305, USA

    Rasmus Y. Brogaard

Authors
  1. Rasmus Y. Brogaard
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Rasmus Y. Brogaard .

Rights and permissions

Reprints and permissions

Copyright information

© 2012 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Brogaard, R.Y. (2012). Paracyclophanes I: [2\(+\)2]cycloaddition of Ethylenes . In: Molecular Conformation and Organic Photochemistry. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-29381-8_7

Download citation

Publish with us

Policies and ethics

Search

Navigation