Abstract
Condensation polymerizations (polycondensations) are stepwise reactions between bifunctional or polyfunctional components, with elimination of small molecules such as water, alcohol, or hydrogen and the formation of macromolecular substances. For the preparation of linear condensation polymers from bifunctional compounds (the same considerations apply to polyfunctional compounds which then lead to branched, hyperbranched, or crosslinked condensation polymers) there are basically two possibilities. One either starts from a monomer which has two unlike groups suitable for polycondensation (AB type), or one starts from two different monomers, each possessing a pair of identical reactive groups that can react with each other (AABB type). An example of the AB type is the polycondensation of hydroxycarboxylic acids:
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Bibliography
Allen G, Bevington J (eds) (1989) Comprehensive polymer science, vol 5. Pergamon, Oxford
Becker GW, Braun D, Oertel G (eds) (1993) Kunststoff-Handbuch, vol 7, Polyurethanes. Hanser, München
Brook MA (1999) Silicon in organic, organometallic, and polymer chemistry. Wiley, New York
Eisenbach CD, Baumgartner M, Guenter C (1986) In: Lal J, Mark JE (eds) Advances in elastomers and rubber elasticity (Polyurethanes). Plenum, New York
Elias HG (1984) Macromolecules. Plenum, New York
Flory PJ (1953) Principles of polymer chemistry. Cornell University Press, Ithaca
Houben-Weyl (1987) Methoden der organischen Chemie, vol E20, Makromolekulare Stoffe, Thieme, Stuttgart
Kricheldorf HR (ed) (1992) Handbook of polymer synthesis, part A and B. Marcel Dekker, New York
Mitsutoshi Jikei J, Kakimato M (2001) Hyperbranched polymers: a promising new class of materials. Prog Polym Sci 26:1233–1288
Rösch L, Weidner R Polymerization chemistry of silicones. In: Encyclopedia of materials: science and technology. Pergamon, Amsterdam, (Online Resource 2001)
Schlüter AD (2000) Synthesis of polymers. Wiley-VCH, Weinheim
Schmaljohan D, Voit BI, Jansen JFGA, Hendrdriks P, Loontjens JA (2000) New coating systems based on vinyl ether- and Oxetane-modified hyperbranched polyester. Macromol Mater Eng 275:31–41
Voit BI (2000) New developments in hyperbranched polymers. J Polymer Sci Part A Polym Chem 38:2505–2525
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Braun, D., Cherdron, H., Rehahn, M., Ritter, H., Voit, B. (2013). Synthesis of Macromolecules by Step Growth Polymerization. In: Polymer Synthesis: Theory and Practice. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-28980-4_4
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DOI: https://doi.org/10.1007/978-3-642-28980-4_4
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