Abstract
After it had become clear that equilibrium fractionation between chemical phases containing different hydrogen isotopes could be both theoretically and experimentally determined with perfect agreement (Urey and Rittenberg in J Chem Phys 1:137–143, 1933; Rittenberg and Urey in J Amer Chem Soc 56:1885–1889, 1934; Rittenberg et al. in J Chem Phys 2:48–49, 1934) interest in the equilibria between isotopes of the other light elements also grew.
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Ader M, Coleman ML, Doyle SP, Stroud M, Wakelin D (2001) Methods for the stable isotopic analysis of chlorine in chlorate and perchlorate compounds. Anal Chem 73:4946–4950
Ader M, Chaudhuri S, Coates JD, Coleman M (2008) Microbial perchlorate reduction: a precise laboratory determination of the chlorine isotope fractionation and its possible biochemical basis. Earth Planet Sci Lett 269:604–612
Brejneva N, Roginsky S, Schilinsky A (1936) Methodology of the introduction of radioactive halogens to organic molecules. Acta Physicochemical URSS 7:549–574
Bruce RA, Achenbach LA, Coates JD (1999) Reduction of (per)chlorate by a novel organism isolated from a paper mill waste. Environ Microbiol 1:319–331
Coates JD, Michaelidou U, Bruce RA, O’Connor SM, Crespi JN, Achenbach LA (1999) The ubiquity and diversity of dissimilatory (per)chlorate-reducing bacteria. Appl Environ Microbiol 65:5234–5241
Coleman ML, Ader M, Chaudhuri S, Coates JD (2003) Microbial isotopic fractionation of perchlorate chlorine. Appl Environ Microbiol 69:4997–5000
Czarnacki M, Hałas S (2012) Isotope fractionation in aqua-gas systems: Cl2–HCl–Cl–, Br 2-HBr–Br- and H2S–S2–. Isot Environ Health Stud 48:55–64
Dodgen HW, Libby WF (1949) The exchange reaction between the hydrogen halides and the halogens in the gaseous state. J Chem Phys 17:951–957
Ericksen GE (1981) Geology and origin of the Chilean nitrate deposits. USGS Prof Paper 1188:37 pp
Giunta T, Labadi J, Eggenkamp HGM (2013) Experimental determination of chlorine isotope fractionation in Cl2–\({{\text{Cl}}^{ - } }_{\text{aq}}\) and ClOHaq–\({{\text{Cl}}^{ - } }_{\text{aq}}\). In: 23th annual V.M. Goldschmidt conference. Firenze, Italy
Hoering TC, Parker PL (1961) The geochemistry of the stable isotopes of chlorine. Geochim Cosmochim Acta 23:186–199
Johnston WH, Libby WF (1951) The exchange reaction between hydrogen chloride and chlorine in the gaseous state. J Amer Chem Soc 73:854–855
Libby WF (1940) Mechanism of the exchange reaction between gaseous bromine and hydrogen bromide. J Chem Phys 8:348
Liberatore LC, Wiig EO (1940) Exchange reaction of gaseous bromine and hydrogen bromide. J Chem Phys 8:165–170
Malmqvist A, Welander T, Moore E, Ternstrom A, Molin G, Stenstrom IM (1994) Ideonella dechloratans gen. nov., sp. nov., a new bacterium capable of growing anaerobically with chlorate as an electron acceptor. Syst Appl Microbiol 17:58–64
Michaelidou U, Achenbach LA, Coates JD (2000) Isolation and characterization of two novel (per)chlorate-reducing bacteria from swine waste lagoons. In: Urbansky ED (ed) Perchlorate in the environment. Kluwer Academic/Plenum, New York, pp 271–283
Richet P, Bottinga Y, Javoy M (1977) A review of hydrogen, carbon, nitrogen, oxygen, sulphur, and chlorine stable isotope fractionation among gaseous molecules. Ann Rev Earth Planet Sci 5:65–110
Rikken G, Kroon A, Van Ginkel C (1996) Transformation of (per)chlorate into chloride by a newly isolated bacterium: reduction and dismutation. Appl Microbiol Biotechnol 45:420–426
Rittenberg D, Urey HC (1934) The thermal decomposition of deuterium iodide. J Amer Chem Soc 56:1885–1889
Rittenberg D, Bleakney W, Urey HC (1934) The equilibrium between the three hydrogens. J Chem Phys 2:48–49
Romanenko VI, Korenkov VN, Kuznetsov SI (1976) Bacterial decomposition of ammonium perchlorate. Mikrobiologiia 45:204–209
Schauble EA, Rossman GR, Taylor HP (2003) Theoretical estimates of equilibrium chlorine-isotope fractionations. Geochim Cosmochim Acta 67:3267–3281
Stepanyuk V, Smirnova G, Klyushnikova T, Kanyuk N, Panchenko L, Nogina T, Prima V (1992) New species of the Acinetobacter genus Acinetobacter thermotoleranticus sp. nov. Microbiology 61:347–356
Sturchio NC, Hatzinger PB, Arkins MD, Suh C, Heraty LJ (2003) Chlorine isotope fractionation during microbial reduction of perchlorate. Environ Sci Technol 37:3859–3863
Sturchio NC, Böhlke JK, Beloso AD Jr, Streger SH, Heraty LJ, Hatzinger PB (2007) Oxygen and chlorine isotopic fractionation during perchlorate biodegradation: laboratory results and implications for forensics and natural attenuation studies. Environ Sci Technol 41:2796–2802
Urbansky ET (1998) Perchlorate chemistry: implications for analysis and remediation. Bioremediat J 2:81–95
Urey HC (1947) The thermodynamic properties of isotopic substances. J Chem Soc 1947:562–581
Urey HC, Greiff LJ (1935) Isotope exchange equilibria. J Chem Soc Amer 57:321–327
Urey HC, Rittenberg D (1933) Some thermodynamic properties of the H1H2, H2H2 molecules and compounds containing the H2 atom. J Chem Phys 1:137–143
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Eggenkamp, H. (2014). Theoretical and Experimental Fractionation Between Species with Different Oxidation States. In: The Geochemistry of Stable Chlorine and Bromine Isotopes. Advances in Isotope Geochemistry. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-28506-6_8
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DOI: https://doi.org/10.1007/978-3-642-28506-6_8
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