Abstract
The reaction of acetone with hydrogen peroxide gives various types of organic peroxides of acetone, in a reaction involving several stages. The simple linear hydroperoxides and hydroxyperoxides form at first and then condense to the linear dimer and trimer analogs. The linear dihydroperoxide 2,2-dihydroperoxypropane (I) and its dimer bis(2-hydroperoxypropane)peroxide (II) form as a main product in an acetone and hydrogen peroxide mixture, in the absence of an acidic catalyst [1].
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Matyáš, R., Pachman, J. (2013). Organic Peroxides. In: Primary Explosives. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-28436-6_10
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