Abstract
The calculation about the kinetics and thermal decomposition of dicumyl peroxide (DCPO) is required for safety concerns, because of its wide applications and accident cases. The isoconversional kinetic study on the thermal behaviour of DCPO has been carried out by differential scanning calorimetry. The apparent activation energy Ea and pre-exponential factor A are not constant during the reaction. Application of accurate decomposition kinetics enabled the determination of the time to maximun rate under adiabatic conditions (TMRad) with a precision given by the confidence interval of the predicitons. This analysis can then be applied for the examination of the effects of the surrounding termperature for safe storage or transportation conditions
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© 2012 Springer-Verlag Berlin Heidelberg
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Na, Z. (2012). Time to Maximum Rate Calculation of Dicumyl Peroxide Based on Thermal Experimental Analysis. In: Zeng, D. (eds) Advances in Control and Communication. Lecture Notes in Electrical Engineering, vol 137. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-26007-0_34
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DOI: https://doi.org/10.1007/978-3-642-26007-0_34
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