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Copper Complexes of Star-Shaped Cholic Acid Oligomers With 1,2,3-Triazole Moieties

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Assessing the Functional Structure of Molecular Transporters by EPR Spectroscopy

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Abstract

Oligomers based on cholic acid are known to form hydrophobic cavities in hydrophilic solvents due to the facial amphiphilicity of their building blocks. In such pockets, non-polar molecules such as pyrene can be hosted. Oligomers with 1,2,3-triazole moieties are also able to coordinate heavy metal ions. Depending on their position in the cholic acid oligomer, the triazole groups may either cooperatively bind to the metal ion in analogy to a tridentate ligand or act as single entities.

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  1. Max Planck Institute for Polymer Research, Mainz, Germany

    Matthias J. N. Junk

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Junk, M.J. (2012). Copper Complexes of Star-Shaped Cholic Acid Oligomers With 1,2,3-Triazole Moieties. In: Assessing the Functional Structure of Molecular Transporters by EPR Spectroscopy. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-25135-1_4

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