Abstract
The structure of ammonium azide is also based on a modification of the basic CsCl cubic structure although hydrogen bonding plays a dominant role in the distortion. The azide anions are broadly organised into layers, but half of the anions are rotated out of the plane to allow hydrogen bonding between the ammonium ion and the negative termini of the azide ions.
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Millar, D.I.A. (2012). Structural Investigation of a Series of Inorganic Azides. In: Energetic Materials at Extreme Conditions. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-23132-2_6
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