Abstract
This chapter takes a new approach in the investigation of fluorination in ethene by looking at some anion-molecule reactions. The data presented were collected by Drs Richard Kennedy and Chris Mayhew many years ago. The raw data was given to me for a project which I started in the fourth year of my undergraduate MSci degree, and continued over the first few years of my Ph.D. The discussion and interpretation of the results presented here is almost entirely my own work, but I would like to thank Dr Liam Cox for many helpful discussions about organic chemistry reaction mechanisms, and Dr Michael Parkes and Professor Richard Tuckett for continued guidance during these early stages of my research.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Notes
- 1.
The enthalpy changes for reactions 9.5–9.9 are considered incorrect, because of uncertainty in the value of Δ f H° (C2F3 −) used, −420 kJ mol−1. A new value, −504 kJ mol−1, is evaluated from recent theoretical calculations, and from the presented experimental observations shown by reactions 9.5–9.9. The updated reaction enthalpies are +38, −113, −76, −69, and −36 kJ mol−1, respectively. See text for a more detailed discussion.
References
Sullivan SA, Beauchamp JL (1976) J Am Chem Soc 98:1160
Sullivan SA, Beauchamp JL (1977) J Am Chem Soc 99:5017
Parkes DA (1972) J Chem Soc Faraday Trans 68:613
Lindinger W, Albritton DL, Fehsenfeld FC, Ferguson EE (1975) J Chem Phys 63:3238
Viggiano AA, Paulson JF (1983) J Chem Phys 79:2241
Dawson J, Jennings KR (1976) J Chem Soc Faraday Trans 72:700
Bohme DK, Brewster Young L (1970) J Am Chem Soc 92:3301
Morris RA (1992) J Chem Phys 97:2372
Su T, Su A, Viggiano AA, Paulson JF (1987) J Phys Chem 91:3683
Kennedy RA, Mayhew CA, Peverall R, Watts P (2000) Phys Chem Chem Phys 2:3145
Simmonett AC, Wheeler SE, Schaefer HF (2004) J Phys Chem 108:1608
Lias SG, Bartmess JE, Liebman JF, Holmes JL, Levin RD, Mallard WG (1988) J Phys Chem Ref Data 17:1
Spyrou S, Sauers I, Christophorou LG (1983) J Chem Phys 78:7200
Harland PW, Thynne JCJ (1975) Int J Mass Spectrom 18:73
Lifshitz C, Grajower R (1972) Int J Mass Spectrom 10:25
Bauschlicher CW, Ricca A (2000) J Phys Chem A 104:4581
Rienstra-Kiracofe JC, Tschumper GS, Schaefer HF, Nandi S, Ellison B (2002) Chem Rev 102:231
Schleyer PVR, Kos A (1983) Tetrahedron 39:1141
Bach RD, Evans C (1986) J Am Chem Soc 108:1374
Roy M, McMahon TB (1985) Can J Chem 63:708
Rabasco JJ, Kass SR (1992) J Am Soc Mass Spectrom 3:91
Knorr R (2004) Chem Rev 104:3795
McDonald RN, Kasem Chowdhury A (1985) J Am Chem Soc 107:4123
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2012 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Simpson, M.J. (2012). The Reactions of OH−, O−, CF3 −, F−, and O− 2 with C2H4, C2H3F, C2H2F2, C2HF3 and C2F4 . In: Two Studies in Gas-Phase Ion Spectroscopy. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-23129-2_9
Download citation
DOI: https://doi.org/10.1007/978-3-642-23129-2_9
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-23128-5
Online ISBN: 978-3-642-23129-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)