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The Reactions of CF n + (n = 1–3) with C2H4, C2H3F, C2H2F2 and C2HF3

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Two Studies in Gas-Phase Ion Spectroscopy

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Abstract

This chapter reports a fundamental study which investigates on two fronts the effects of fluorination on the reactivity of small molecules. First, how increasing fluorine substitution in neutral ethene affects its reactivity, and second how using different fluorocarbon cation species in the reactions changes the outcome. These data were collected by myself, Dr Michael Parkes, Dr Victor Mikhailov and Dr Chris Mayhew in the Department of Physics and Astronomy at The University of Birmingham between Spring 2007 and Autumn 2009.

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References

  1. Mikhailov V, Parkes MA, Simpson MJ, Tuckett RP, Mayhew CA (2008) J Phys Chem A 112:9012

    Article  CAS  Google Scholar 

  2. Mikhailov V, Parkes MA, Tuckett RP, Mayhew CA (2006) J Phys Chem A 110:5760

    Article  CAS  Google Scholar 

  3. Derwish GAW, Galli A, Giardini-Guidoni A, Volpi GG (1964) J Am Chem Soc 86:4563

    Article  CAS  Google Scholar 

  4. Anicich VG, Bowers MT, O’Malley RM, Jennings KR (1973) Int J Mass Spectrom Ion Phys 11:99

    Article  CAS  Google Scholar 

  5. Morris RA, Viggiano AA, Paulson JF (1993) J Phys Chem 97:6208

    Article  CAS  Google Scholar 

  6. Morris RA, Brown ER, Viggiano AA, Van Doren JM, Paulson JF, Motevalli V (1992) Int J Mass Spectrom Ion Processes 121:95

    Article  CAS  Google Scholar 

  7. Tsuji M, Aizawa M, Nishimura Y (1995) J Phys Chem 99:3195

    Article  CAS  Google Scholar 

  8. O’Malley RM, Jennings KR, Bowers MT, Anicich VG (1973) Int J Mass Spectrom 11:89

    Article  Google Scholar 

  9. Williams BA, Cool TA (1991) J Chem Phys 94:6358

    Article  CAS  Google Scholar 

  10. Bieri G, Von Niessen W, Åsbrink L, Svensson A (1981) Chem Phys 60:61

    Article  CAS  Google Scholar 

  11. Dyke JM, Lewis AE, Morris A (1984) J Chem Phys 80:1382

    Article  CAS  Google Scholar 

  12. National Institute of Standards and Technology website (http://webbook.nist.gov/chemistry/)

  13. Garcia GA, Guyon PM, Powis I (2001) J Phys Chem A 105:8296

    Article  CAS  Google Scholar 

  14. Eden S, Limao-Vieira P, Kendall PA, Mason NJ, Delwiche J, Hubin-Franskin MJ, Tanaka T, Kitajima M, Tanaka H, Cho H, Hoffmann SV (2004) Chem Phys 297:257

    Article  CAS  Google Scholar 

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Correspondence to Matthew J. Simpson .

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Simpson, M.J. (2012). The Reactions of CF n + (n = 1–3) with C2H4, C2H3F, C2H2F2 and C2HF3 . In: Two Studies in Gas-Phase Ion Spectroscopy. Springer Theses. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-23129-2_7

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