Abstract
In this chapter, we review the recent results on graphene films epitaxially grown on 3d − 5d transition-metal surfaces focussing mainly on their atomic structure, aspects of chemical interaction both with the substrate and with adsorbates and the electronic structure of graphene at the interface. We discuss a possibility to prepare sandwich-like structures in the form of intercalates as a possible way to controllably tailor the electronic properties of graphene. Recent works on the templated growth of metallic nanostructures on graphene moiré are also reviewed.
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Acknowledgements
We thank all co-workers and collaborators for their contributions to this work, in particular, M. Weser, S. Böttcher, C. Enderlein, E. Voloshina, E. Goering, M. Sicot, P. Leicht, A. Zusan, O. Zander, A. S. Vinogradov, M. L. Ng, and S. Bouvron. This work has been supported by the European Science Foundation (ESF) under the EUROCORES Programme EuroGRAPHENE (Project “SpinGraph”). Y. D. acknowledges the financial support by the German Research Foundation (DFG) under project DE 1679/2-1. M. F. gratefully acknowledges the financial support by the Research Center “UltraQuantum” (Excellence Initiative), by the German Research Foundation (DFG) via the Collaborative Research Center (SFB) 767, and the Baden-Württemberg Stiftung. A. P. is grateful for the financial support from the Swedish Research Council.
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Dedkov, Y., Horn, K., Preobrajenski, A., Fonin, M. (2011). Epitaxial Graphene on Metals. In: Raza, H. (eds) Graphene Nanoelectronics. NanoScience and Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-22984-8_7
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