Abstract
The practical application of modeling methods requires extensive knowledge of the laws governing the processes that occur in a metal–slag–gas system. Therefore, we will turn to well-known thermodynamic and kinetic methods of analysis which provide ways to reveal both the general laws of interaction and the special features of the individual steps of reactions and of the behavior of the components of the system.
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Moiseev, G.K., Vatolin, N.A.: Thermodynamic modeling: concentration, application, examples. Rasplavy 5, 15–40 (1990)
Marshuk, L.A., et al.: Use of thermodynamic modeling for devising theoretical principles for obtaining new ferroalloys. In: Physicochemical Principles of Metallurgical Processes. Part III (in Russian), pp. 179–180. Chermetinformazia, Moscow (1991)
Grigoryan, V.A., Belyanchikov, L.P., Stomakhin, A.Ya.: Theoretical Foundations of Electro-Steelmaking Processes (in Russian), p. 272. Metallurgiya, Moscow (1987)
Kulikov, I.S.: Deoxidation of Metals (in Russian), p. 504. Metallurgiya, Moscow (1975)
Sabirzyanov, T.G.: Activity and solubility of carbon in iron melts. Izv Vyssh Uchebn Zaved Chern Metall 1, 1–4 (1989)
Mikhailov, G.G.: Thermodynamic principles of the optimization of the deoxidation of steel and the modification of nonmetallic inclusions. Doctoral dissertation, Moscow (1985)
Ponomarenko, A.G.: Questions in the thermodynamics of phases of variable composition with an itinerant electronic system. Zh Fiz Khim 7, 1668–1674 (1974)
Kireev, P.S.: Physics of Semiconductors (in Russian), p. 584. Vysshaya Shkola, Moscow (1975)
Mikhailets, V.N., et al.: Physicochemical models for predicting the distribution of components between a metal and a slag under oxidative conditions. In: Physicochemical and Technological Databases for Optimizing Metallurgical Technologies (in Russian), pp. 154–161. Dnepropetrovsk (1988)
Laptev, D.M.: Analysis of inaccuracies in the literature on the thermodynamics of solutions. Izv Vyssh Uchebn Zaved Chern Metall 12, 5–11 (1987)
Yanagase, T., Suginahara, Y.: Studies on constitution of vitreous silicates by infrared absorption spectra. Trans Jpn Inst Metals 11, 4000–4003 (1970)
Ezikov, V.I., Pasishnik, S.V., Chuchmarev, S.K.: Application of trimethylsilylation and rapid quenching to the investigation of the constitution of anions in silicate melts. In: Abstracts of Reports to the 6th All-Union Conference on the Constitution and Properties of Metallic and Oxide Melts. Part 3 (in Russian), pp. 229–230, Sverdlovsk, 1986
Stolyarova, V., et al.: High temperature mass spectrometric study of multicomponent silicate systems. In: Proceedings 4th International Conference on Molten Slags and Fluxes, pp. 185–188. Sendai, Japan (1992)
Kozheurov, V.A.: Thermodynamics of Metallurgical Slags (in Russian), p. 163. Metallurgizdat, Sverdlovsk (1995)
Ban-Ya, S.: Mathematical expression of slag-metal reactions in steelmaking process by quadratic formalism based on the regular solution model. In: Proceedings 4th International Conference on Molten Slags and Fluxes, pp. 8–13. Sendai, Japan (1992)
Jahanshaki, S., Wright, S.: Aspects of the regular solution model and its application to metallurgical slags. In: Proceedings 4th International Conference on Molten Slags and Fluxes, pp. 61–66. Sendai, Japan (1992)
Snitko, Yu.P., Surova, Yu.N., Lyakishev, N.P.: Method for determining the heats of mixing of oxides. In: Abstracts of Reports to the 5th All-Union Conference on the Constitution and Properties of Metallic and Slag Melts. Part 3 (in Russian), pp. 39–41. Sverdlovsk, 1983
Gyae, H., et al.: A statistical thermodynamics model of slags: applications to systems containing S, P, P2O5, and Cr oxides. In: Proceedings 4th International Conference on Molten Slags and Fluxes, pp. 103–108. Sendai, Japan (1992)
Popel’, S.I., Sotnikov, A.I., Boronenkov, V.N.: Theory of Metallurgical Processes (in Russian), p. 403. Metallurgiya, Moscow (1986)
Sinyarev, G.B., et al.: Application of Computers to Thermodynamic Calculations of Metallurgical Processes (in Russian), p. 263. Nauka, Moscow (1982)
Mochalov, S.P., et al.: Method for the mathematical modeling and calculation of the equilibrium conditions in complex steelmaking systems. In: Modeling of Physicochemical Systems and Technological Processes in Metallurgy (in Russian), pp. 132–133. Novokuznetsk Institute of Metal Press, Novokuznetsk (1991)
Gasik, M.M.: Carbon–oxygen equilibrium in liquid iron during vacuum–carbon deoxidation. Izv Vyssh Uchebn Zaved Chern Metall 10, 9–13 (1991)
Zhancheng, G., et al.: A model on slag-metal reaction kinetics. In: Proceedings 4th International Conference on Molten Slags and Fluxes, pp. 308–313. Sendai, Japan (1992)
Kazachkov, E.A.: Calculations Based on the Theory of Metallurgical Processes (in Russian), p. 288. Metallurgiya, Moscow (1988)
Shalimov, M.P., et al.: Calculation of the equilibrium distribution of elements between metallic and slag melts. In: Structure and Properties of Slag Melts (in Russian), pp. 62–66. Kurgan Mach Build Institute Press, Kurgan (1984)
Ban-Ya, S., Dong-Shim, Y.: Application of the regular solution model to steelmaking slags. In: Proceeding of the 10th Soviet-Japanese Symposium on the Physicochemical Principles of Metallurgical Processes (in Russian), pp. 21–41. Metallurgiya, Moscow (1983)
Turkdogan, E.T.: Physical Chemistry of High-Temperature Processes (in Russian), p. 344. Metallurgiya, Moscow (1985)
Zinigrad, M.I.: Kinetics and mechanism of the interaction of metals and oxide melts. Doctoral dissertation, p. 419, Sverdlovsk (1981)
Medzhibozhskii, M.Ya., Konoplya, V.G., Plokhikh, G.A.: Some laws governing the distribution of phosphorus between a metal with a high phosphorus content and a slag. In: Electrochemistry and Melts (in Russian), pp. 201–207. Nauka, Moscow (1974)
Chuiko, N.M., Zaozernyi, M.T.: Distribution of tungsten between a metal, a slag, and a gas phase during the smelting of high-speed steels. Metally 6, 20–26 (1974)
Zamoruev, V.M.: Tungsten in Steel (in Russian), p. 199. GNTI, Moscow (1962)
Adel’shin, Yu.G., et al.: Thermodynamic analysis of the oxidation of tungsten in a steelmaking arc furnace. Izv Vyssh Uchebn Zaved Chern Metall 11, 51–54 (1984)
Perevalov, N.M., Mogutnov, B.M., Shvartsman, L.A.: Influence of the basicity of a slag on the oxidation of elements of the chromium subgroup dissolved in liquid iron. Dokl Akad Nauk SSSR 124(1), 150–152 (1959)
Perevalov, N.M., Mogutnov, B.M., Shvartsman, L.A.: Influence of calcium oxide on the distribution of tungsten between liquid iron and a slag. Izv Akad Nauk SSSR Metall Topl 1, 22–28 (1959)
Merkulov, V.F., et al.: Technology for recovering tungsten from boring bit scrap. Stal’ 10, 30–32 (1984)
Okol’zdaev, A.G., et al.: Influence of the oxidative capacity of the slag on the distribution of tungsten between the metallic and oxide phases. In: Abstracts of Reports to the 6th All-Union Conference on the Constitution and Properties of Metallic and Slag Melts, Part 3 (in Russian), pp. 238–239. Sverdlovsk, 1986
Yavoiskii, V.I.: Theory of Steel Production Processes (in Russian), p. 792. Metallurgizdat, Moscow (1967)
Bagryanskii, K.V.: Electric-Arc Welding and Surfacing under Ceramic Fluxes (in Russian), p. 184. Tekhnika, Kiev (1976)
Ignatov, M.N.: Improving the quality of welded joints of nickel and nickel alloys by using transition metal carbides in the electrode coatings. Candidate dissertation, p. 145, Perm′ Polytechnic Institute, Perm′ (1987)
Burylev, B.P., Kretov, A.I., Moisov, L.P.: Thermodynamic activity of components of welding fluxes. Avtom Svarka 2, 67–69 (1978)
Burylev, B.P., Kretov, A.I.: Influence of the thermodynamic activity of the slag components on the properties of the metal. In: Physicochemical Investigations of Metallurgical Processes (in Russian), vol. 8, pp. 88–90. Ural Polytechnic Institute Press, Sverdlovsk (1980)
Hideaki, S., Ryo, J.: Manganese equilibrium between molten iron and MgO-saturated CaO–FetO–SiO2–MnO–P2O5 slags. Trans. Iron Steel Inst. Jpn. 24(4), 257–265 (1984)
Globovskii, V.G., Burtsev, V.T.: Melting Metals and Alloys in the Suspended State (in Russian), p. 176. Metallurgiya, Moscow (1974)
Boronenkov, V.N., Esin, O.A.: Kinetics of the simultaneous occurrence of several heterogeneous reactions with common reactants. Zh Fiz Khim 8, 2022–2027 (1970)
Frank-Kamenetskii, D.A.: Diffusion and Heat Transfer in Chemical Kinetics, 2nd edn. Plenum Press, New York (1969)
Levich, V.G.: Physicochemical Hydrodynamics. Prentice-Hall, Englewood Cliffs (1962)
Medzhibozhskii, M.Ya., Zinov’ev, V.T., Geineman, A.V.: Influence of several factors on the rate of carbon boil in an open-hearth bath. Izv Vyssh Uchebn Zaved Chern Metall 6, 47–53 (1960)
Kazakov, N.I., Filippov, S.I.: Kinetics of the oxidation of carbon by liquid steel with electromagnetic stirring. Izv Vyssh Uchebn Zaved Chern Metall 11, 15–21 (1961)
Boronenkov, V.N.: Kinetic analysis of the oxidation of impurities in iron by a molten slag. In: Physicochemical Investigations of Metallurgical Processes: Proceedings of Institutions of Higher Education of the Russian Federation, No. 1 (in Russian), pp. 18–34. Sverdlovsk (1973)
Boronenkov, V.N., Esin, O.A.: Kinetic equation of a multicomponent reaction in a diffusion-controlled regime. Izv Vyssh Uchebn Zaved Chern Metall 9, 17–20 (1970)
Boronenkov, V.N., Shanchurov, S.M., Zinigrad, M.I.: Kinetics of the interaction of a multicomponent metal with a slag in a diffusion-controlled regime. Izv Akad Nauk SSSR Met 6, 21–27 (1979)
Boronenkov, V.N., Salamatov, A.M.: Mathematical estimation of the kinetics of the interaction of a multicomponent metal with the slag during submerged-arc welding. Avtomat Svarka 8, 19–24 (1985)
Churkin, A.S., Toporishchev, G.A., Esin, O.A.: Kinetic features of the desulfurization of high-silicon pig iron by a flux of the CaO–SiO2–Αl2Ο3 system. Izv Akad Nauk SSSR Met 1, 37–44 (1971)
Boronenkov, V.N., Pozdnyakov, A.D.: Mathematical model of the kinetics of the simultaneous oxidation of impurities in iron by a molten slag. In: Physicochemical Principles of Metallurgical Processes. No. 7 (in Russian), pp. 75–83. Ural Polytechnic Institute Press, Sverdlovsk (1979)
Damaskin, B.B., Petrii, O.A.: Introduction to Electrochemical Kinetics (in Russian), p 416. Vyshaya Shkola, Moscow (1975)
Boronenkov, V.N., Shalimov, M.P., Shanchurov, S.M.: Method for analyzing the kinetics of simultaneously occurring electrode reactions under non-steady-state conditions. Rasplavy 5, 12–17 (1994)
Vetter, K.: Electrochemical Kinetics. Academic, New York (1967)
Delahay, P.: Double Layer and Electrode Kinetics. Interscience, New York (1965)
Turchak, L.I.: Fundamentals of Numerical Methods (in Russian), p. 320. Nauka, Moscow (1987)
Boronenkov, V.N., Shanchurov, S.M.: Kinetics of reactions between a metal and a slag under a non-steady-state diffusion regime. Metally 3, 5–11 (1992)
Kostin, N.A., Kublanovskii, V.S., Zabludovskii, V.A.: Pulsed Electrolysis (in Russian), p. 167. Naukova Dumka, Kiev (1989)
Tsymbal, V.P.: Mathematical Modeling of Metallurgical Processes, p. 240. Metallurgiya, Moscow (1986)
Esin, O.A.: Application of polymer theory to molten slags. In: Physicochemical Investigations of Metallurgical Processes (in Russian), vol. 1, pp. 5–17. Ural Polytechnic Institute Press, Sverdlovsk (1973)
Zalomov, N.I., Boronenkov, V.N., Shanchurov, S.M.: Method for kinetic analysis of the oxidation of silicon by polymeric oxide melts. Rasplavy 2(1), 12–17 (1988)
Zalomov, N.I., Shalimov, M.P., Boronenkov, V.N.: Kinetics of electrochemical processes on a metal/polymeric-oxide-melt interface. In: Constitution and Properties of Metallic and Slag Melts, Part 2 (in Russian), Vol. 3, pp. 199–203. Chelyabinsk Polytechnic Institute Press, Chelyabinsk (1990)
Esin, O.A., Gavrilov, L.K.: Electrode polarization at high temperatures. Zh Fiz Khim 29(3), 566–575 (1955)
Novikov, V.K.: Influence of the composition of the molten metal and the molten slag on the kinetics of the transport of silicon and sulfur through the interface between them. Candidate dissertation, p. 175, Sverdlovsk (1972)
Esin, O.A., Gel’d, P.V.: Physical Chemistry of Pyrometallurgical Processes (in Russian), p. 704. Metallurgizdat, Moscow (1966)
Delahay, P.: New Instrumental Methods in Electrochemistry. Interscience, New York (1954)
Damaskin, B.B.: Principles of Modern Methods for Studying Electrochemical Reactions (in Russian), p. 104. Moscow State University Press, Moscow (1965)
Sotnikov, A.I.: Structure of the metal/oxide-melt interface and special features of electrochemical methods in metallurgical systems. In: Physicochemical Investigations of Metallurgical Processes, vol. 2, pp. 40–49. Ural Polytechnic Institute Press, Sverdlovsk (1974)
Voinov, S.G., Shalimov, A.G., Kosoi, L.F., Kalinnikov, E.S.: Refining Steel by Synthetic Slags (in Russian), p. 186. Metallurgiya, Moscow (1970)
Fefelov, A.S.: Metallurgical and technological features of alloying a metal with boron. Candidate dissertation, p. 190, Ural Polytechnic Institute Press, Sverdlovsk (1982)
Zinigrad, M.I., et al.: Kinetics of the interaction of a boron-containing metallic melt with an oxide electrolyte. Élektrokhimiya 13(1), 74–78 (1986)
Flyagin, A.A., Zinigrad, M.I.: Kinetics of the passage of aluminum and boron through a liquid-steel/oxide-melt interface. Izv Akad Nauk SSSR Met 1, 50–55 (1986)
Sotnikov, A.I., Esin, O.A., Nikitin, Yu.P.: Chemical polarization at high temperatures. Dokl Akad Nauk SSSR 152(5), 1173–1176 (1963)
Melamud, S.G.: Investigation of the kinetics of high-temperature electrode processes involving carbon, silicon, and chromium in a metal–oxide-melt system. Candidate dissertation, p. 185, Sverdlovsk (1970)
Lepinskikh, B.M., Kaibichev, A.V., Savel’ev, Yu.A.: Diffusion of Elements in Liquid Iron-Group Metals (in Russian), p. 192. Nauka, Moscow (1974)
Flyagin, A.A.: Features of the passage of aluminum through a metal/slag interface during the treatment of steel with a synthetic slag. Candidate dissertation, p. 167, Sverdlovsk (1980)
Barmin, L.N., et al.: Application of a coulostatic method to the study of the rate of ion exchange between liquid manganese and an oxide melt. In: Physical Chemistry and Electrochemistry of Molten Salts and Slags. Part II (in Russian), pp. 99–102. Institute Electrochemistry Press, Kiev (1969)
Panov, S.P., Zinigrad, M.I., Barmin, L.M.: Investigation of the fast step of the desulfurization of an iron–carbon melt by a slag. In: Scientific Reports to the 6th All-Union Conference on the Constitution and Properties of Metallic and Slag Melts: Investigations of Slag Melts (in Russian), vol. 3, pp. 60–63. Sverdlovsk (1980)
Sotnikov, A.I.: Structure of the metal/oxide-melt interface and features of electrochemical relaxation methods of investigation in metallurgical systems. In: Physicochemical Investigations of Metallurgical Processes: Proceedings of Institutions of Higher Education of the Russian Federation (in Russian), vol. 1, pp. 40–54 (1974)
Frumkin, A.N.: Kinetics of Electrode Processes (in Russian), p. 318. Izd MGU, Moscow (1952)
Damaskin, B.B., Petrii, O.A.: Foundations of Theoretical Electrochemistry (in Russian), p. 239. Vysshaya Shkola, Moscow (1978)
Popel’, S.I.: Investigation of phenomena on phase boundaries in the steelmaking process. Doctoral dissertation, pp 347, Sverdlovsk (1959)
Pavlov, V.V., Popel’, S.I., Esin, O.A.: Dependence of the interfacial tension on the composition and temperature. In: Surface Phenomena in Melts and Solid Phases Derived from them (in Russian), pp. 136–141. Kabardino Balkar Publishing, Nal’chik (1965)
Yakobashvili, S.B.: Surface Properties of Welding Fluxes and Slags (in Russian), p. 207. Technika, Kiev (1970)
Andronov, V.N., Chekin, B.V., Nesterenko, S.V.: Liquid Metals and Slags. Handbook Edition (in Russian), p. 128. Metallurgiya, Moscow (1977)
Zinigrad, M.I., et al.: Investigations of the distribution of sulfur between an Fe–C–S melt and a CaO–Al2O3–MgO slag. In: Physicochemical Investigations of Metallurgical Processes, vol. 9, pp. 60–64. Ural Polytechnic Institute Press, Sverdlovsk (1981)
Zinigrad, M.I., et al.: Kinetic features of the desulfurization of an iron–carbon melt by a slag. Izv Vyssh Uchebn Zaved Chern Metall 2, 4–6 (1981)
Losev, V.V., Gorodetskii, R.V.: Stepwise occurrence of the discharge and ionization of metals. Élektrokhimiya 3(9), 1061–1070 (1967)
Shantarin, V.D., Esin, O.A., Boronenkov, V.N.: Chemical component of the anodic polarization of molten iron saturated with carbon. Élektrokhimiya 3(6), 775–778 (1967)
Buler, P.I., Esin, O.A., Nikitin, Yu.P.: Influence of the composition on the anodic polarization of iron alloys with carbon and nickel. Élektrokhimiya 3(3), 288–293 (1967)
Fugman, G.I.: Kinetics of metallurgical reactions involving titanium and carbon. Candidate dissertation, p. 185, Sverdlovsk (1972)
Sotnikov, A.I.: Kinetics of Electrode Processes on a Metal/Oxide-Melt Interface (in Russian), p. 80. Ural Polytechnic Institute Press, Sverdlovsk (1981)
Shalimov, M.P., Zinigrad, M.I.: Kinetic features of ion exchange on an iron–carbon-melt/slag interface. In: Physicochemical Principles of Metallurgical Processes. Part II (in Russian), pp. 7–9. Chermetinformazia, Moscow (1991)
Medzhibozhskii, M.Ya., et al.: Dynamic computer simulation of the decarbonization of steel. Izv Vyssh Uchebn Zaved Chern Metall 7, 158–161 (1977)
Sevic, D., Cureija, D.: Temperaturna ovisnost rastvorljivosti uglika u troskama. Zelez Zb 16(4), 123–126 (1982)
Novikov, V.K.: Development of the polymer model of silicate melts. Rasplavy 1(6), 21–33 (1987)
Zinigrad, M.I., et al.: Investigation of the distribution of sulfur between Fe–C–S and CaO–Al2O3–MgO melts. In: Physicochemical Investigations of Metallurgical Processes, No. 9 (in Russian), pp. 60–64. Ural Polytechnic Institute Press, Sverdlovsk (1981)
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Boronenkov, V., Zinigrad, M., Leontiev, L., Pastukhov, E., Shalimov, M., Shanchurov, S. (2012). Modeling and Simulation of High-Temperature Processes. In: Phase Interaction in the Metal - Oxide Melts - Gas -System. Engineering Materials, vol 18. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-22377-8_4
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