Abstract
The difference in charges on the even and odd carbon atoms in the chain and the ring, and in the positive charge on the hydrogen atoms, and the existence of the essentially unshared 2s2(c)-electron pair on the carbon atom result in the formation of specific interactions in the saturated and unsaturated linear and cyclic hydrocarbons. The characteristic feature of the hydrocarbons consists in the formation by ethane and butane, and ethylene and butylenes, respectively, of dissimilar types of specific interactions existing together in liquid propane, pentane, propylene, and pentene and further in the members of their homologous series. The energies were estimated of the unlike two types of specific interactions in alkanes, alkenes, and alkynes remaining practically constant throughout all the compounds in the homologous series. The increase in the vaporization enthalpy is determined by the practically equivalent contribution of the growing number of CH2 or CH groups. The energies of the specific interactions in the cyclic hydrocarbons and the energies of the interactions formed by the isostructural methyl groups were estimated.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Talrose VL, Lubimova AL (1952) Secondary process in the ion source of the mass spectrograph. Doclady Chem Technol Doclady Chem USSR 86:99–104
Coylson AC (1961) Valence. Oxford University Press, Oxford, p 428
Schustorovich EM (1975) Chemical bonds at co-coordinated compounds. Knowledge, Moscow
Nefedov VI, Vovna VI (1989) Electronic structure of organic and elementorganic compounds. Nauka, Moscow
Baev AK (1996) Five-coordinated carbon atom at intermolecular interactions. Russ J Coord Chem 22:399–402
Baev AK (2001) Pentacoordinated carbon atom at intermolecular interaction in solutions of alkyl compounds of non-transition elements. In: Book of abstract of VIth international symposium on carbonion chemistry, Marburg, Germany, p 75
Baev AK (2001) Thermodynamics and specific intermolecular interactions in solutions of non-electrolytes with pentacoordinated carbon atom. In: Book of abstract of 27th international conference on solution chemistry, Vaals, Netherlands, p 36
Baev AK (2001) Specific interactions in solvates of solutions of non-electrolytes with isostructural molecules components and pentacoordinated carbon atom. In: Book of abstract of VIIIth international conference. The problems of solution and complex formation in solution, Ivanovo, Russia, p 246
Baev AK (2002) Thermodynamic solutions of non-electrolytes with pentacoordinated carbon atom, at specific interactions. In: Book of abstract of XIVth international conference on chemical thermodynamics, St. Peterburg, Russia, p 132
Baev AK, Korolkov DV (2003) Phenomenon of dativу bond in elementorganic compounds. In: Book of abstract the XVth FECHEM conference on organometallic chemistry, University of Zurich, Switzerland, p 350
Baev AK (2003) Novel approaches to the structure of functional solvents and elementorganic compounds with saturated hydrocarbon ligands and their solvates in binary systems. In: Book of abstract of 27th international conference on solution chemistry, Debrecen, Hungary, p 79
Baev AK (2004) Insolvency of sp3-gibrydixation model of carbon atom and chemistry of non-electrolytes solutions. In: Book of abstract of IXth international conference. The problems of solvation and complex formation in solution, Ivanovo, Russia, pp 62–64
Baev AK (2009) Phenomenological significance of no identical sp3-hubridization model and nature of interaction in chemistry of liquid non-electrolytes and chemical thermodynamics. In: Book of abstract of the Xth international conference on physical and coordination chemistry of porphyrines and them analogous, Ivanovo, Russia, p 86
Legen AC, Roberns BP, Wakkwork AL (1990) Equilibrium conformation of four- and five- membered cycle molecules in the gas phase determination and classification. Chem Phys Lett 191:97
Hobza P, Havlas Z (2000) Blue-shifting hydrogen bonds. Chem Rev 100:4254–4264
Krupin SV, Puhovskoi VA (2004) Investigation of new configuration hydrogen bonding dimer of methanol by method of molecular orbital and functional density. In: Book of abstract. IX international conference. The problem of solvation and complex formation in solutions, Plyos, Russia, p 136
Mandado M, Graria AM, Musquera RA (2002) Approximate transferability in alkanols. J Mol Struct 584(1–3):221–234
Ivanov EV, Puchovskie YuP, Abrosimov VK (2004) About formation of weak hydrogen bonds \( {\hbox{CH}} \cdots {\hbox{O}} \) in liquid methanol. In: Book of abstract. IX intenational conference. The problems of solvation and complex formation in solution, Plyos, Russia, p 345
Baev AK (1972) Complex formation ability halogenides of second – six groups periodical system. General and applied chemistry, vol 5. Vaisheshika Educating, Minsk, pp 35–51
Chickos JS, Acree WE Jr (2003) Enthalpies of sublimation of organic and organometallic compounds, 1910–2001. J Phys Chem Rev Data 32:537–698
Chickos JS, Acree WE Jr (2002) Enthalpies of vaporization of organic and organometallic compounds, 1880–2002. J Phys Chem Rev Data 31:519–879
Papulov YuG, Smuliak VM (1981) Physical properties and chemical structures. Kalinin State University, Kalinin
Baev AK (1969) Problems of chemical nature of phase transformation. General and applied chemistry, vol 1. Vaisheshika Educating, Minsk, pp 197–206
Baev AK (1969) Phase condition and complex formation ability of halogenide metals. General and applied chemistry, vol 1. Vaisheshika Educating, Minsk, pp 207–218
Podkovyrov AI, Baev AK, Kozyrkin BI (1990) Thermodynamics of vaporization of alkylchalcogenides. In: Book of abstract. VI conference of USSR on thermodynamic of organic compounds, Minsk, Belarus, p 73
Kozyrkin BI, Larionova LM, Socolovscei AE, Baev AK (1990) Thermo stability and volatility of tin alkyl compounds. Russ J Appl Chem 50:1798
Socolovskei AE, Baev AK (1984) Thermodynamic study of vaporization process of dimethyl- and diethylzink. Russ J Gen Chem 54(1):103
Socolovskei AE, Baev AK (1984) Thermodynamic study of vaporization process of butylzink organic compounds. Russ J Phys Chem 58:2692–2694
Magaril PZ (1970) Mechanism and kinetics homogeny thermal of transformation hydrocarbon. Chemistry, Moscow, p 223
Vasiliev IA, Petrov VM (1984) Thermodynamic properties of oxygen organic compounds. Chemistry, Leningrad
Lebedev YuA, Miroschnichenko EA (1981) Thermochemistry of the vaporization of organic compounds. The vaporization and sublimation enthalpy and saturated pressure. Nauka, Moscow
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2012 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Baev, A.K. (2012). Specific Intermolecular Interactions of Hydrocarbons. In: Specific Intermolecular Interactions of Organic Compounds. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-21622-0_8
Download citation
DOI: https://doi.org/10.1007/978-3-642-21622-0_8
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-21621-3
Online ISBN: 978-3-642-21622-0
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)