Abstract
The interaction of the pulsed laser beam with the material causes an ablation of mass from a liquid or solid measuring object. This mass is partially evaporated and transferred into the plasma state, where the species are excited to emit element-specific radiation used for LIBS. However, a part of the ablated mass leaves the measuring object as material vapor, particle, or liquid. At a later stage, this vapor condenses, forms particulates, or precipitates in the neighborhood of the interaction region. The particles ejected may be carried away by a gas flow or they propagate back to the surface of the measuring object forming a deposition. If a melt phase occurs – e.g., in case of the interaction of pulsed laser radiation with metals – a part of the mass is ejected as a liquid forming splashes or droplets which resolidify in the surrounding atmosphere or on the surface of the measuring object. Due to the complexity of processes, it is generally a difficult task to determine quantitatively the amount of ablated mass for single laser pulses or laser bursts.
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References
C. Lorenzen, C. Carlhoff, U. Hahn, M. Jogwich, Applications of laser-induced emission spectral analysis for industrial process and quality control. J. Anal. At. Spectrom. 7, 1029–1035 (1992)
R. De Young, W. Situ, Elemental mass spectroscopy of remote surfaces from laser-induced plasmas. Appl. Spectrosc. 48, 1297–1306 (1994)
E. Piepmeier, D. Osten, Atmospheric influences on Q-switched laser sampling and resulting plumes. Appl. Spectrosc. 25, 642–652 (1971)
A. Felske, Über einige Erfahrungen bei der Makrospektralanalyse mit Laserlichtquellen. Spectrochim. Acta 27B, 1–21 (1972)
F. Leis, W. Sdorra, J. Ko, K. Niemax, Basic investigations for laser microanalysis: I. Optical emission spectrometry of laser-produced sample plumes. Mikrochim. Acta II 98, 185–199 (1989)
R. Jowitt, Direct analysis of liquid steel by laser, Proceedings of 38. Chemistry Conf., BSC Teesside Laboratories, 1985, 19–29
R. Sattmann, V. Sturm, R. Noll, Laser-induced breakdown spectroscopy of steel samples using multiple Q-switch Nd:YAG laser pulses. J. Phys. D Appl. Phys. 28, 2181–2187 (1995)
A. Semerok, C. Chaléard, V. Detalle, J. Lacour, P. Mauchien, P. Meynadier, C. Nouvellon, B. Sallé, P. Palianov, M. Perdrix, G. Petite, Experimental investigations of laser ablation efficiency of pure metals with femto, pico and nanosecond pulses. Appl. Surf. Sci. 138–139, 311–314 (1999)
V. Sturm, L. Peter, R. Noll, Steel analysis with laser-induced breakdown spectrometry in the vacuum ultraviolet. Appl. Spectrosc. 54, 1275–1278 (2000)
L. Peter, V. Sturm, R. Noll, Liquid steel analysis with laser-induced breakdown spectrometry in the vacuum ultraviolet. Appl. Optics 42, 6199–6203 (2003)
J. Vrenegor, R. Noll, V. Sturm, Investigation of matrix effects in LIBS plasmas of high-alloy steel for matrix and minor elements. Spectrochim. Acta B 60, 1083–1091 (2005)
J. Aguilera, C. Aragón, F. Penalba, Plasma shielding effect in laser ablation of metallic samples and its influence on LIBS analysis. Appl. Surf. Sci. 127–129, 309–314 (1998)
J. Aguilera, C. Aragón, A comparison of the temperatures and electron densities of laser-produced plasmas obtained in air, argon, and helium at atmospheric pressure. Appl. Phys. A 69, S475–S478 (1999)
I. Horn, D. Günther, The influence of ablation carrier gasses Ar, He and Ne on the particle size distribution and transport efficiencies of laser ablation-induced aerosols: implications for LA–ICP–MS. Appl. Surf. Sci. 207, 144–157 (2003)
W. Sdorra, K. Niemax, Basic investigations for laser microanalysis: III. Application of different buffer gases for laser-produced sample plumes. Mikrochim. Acta 107, 319–327 (1992)
R. Russo, Laser ablation. Appl. Spectrosc. 49, 14A–28A (1995)
M. Guillong, I. Horn, D. Günther, Description and characterization of a homogenized high power 266 nm Nd:YAG laser ablation systems for LA-ICP-MS. J. Anal. At. Spectrom. 17, 8–14 (2002)
A. Löbe, J. Vrenegor, R. Fleige, V. Sturm, R. Noll, Laser-induced ablation of a steel sample in different ambient gases by use of collinear multiple laser pulses. Anal. Bioanal. Chem. 385, 326–332 (2006)
C. Wegst, Stahlschlüssel 2001, Marbach, Stahlschlüssel Wegst GmbH, 19. Auflage
L. St-Onge, V. Detalle, M. Sabsabi, Enhanced laser-induced breakdown spectroscopy using the combination of fourth-harmonic and fundamental Nd:YAG laser pulses. Spectrochim. Acta B 57, 121–135 (2002)
R. Noll, R. Sattmann, V. Sturm, S. Winkelmann, Space- and time-resolved dynamics of plasmas generated by laser double pulses interacting with metallic samples. J. Anal. At. Spectrom. 19, 419–428 (2004)
J. Vadillo, J. Romero, C. Rodriguez, J. Laserna, Depth-resolved analysis by laser-induced breakdown spectrometry at reduced pressure. Surf. Interface Anal. 26, 995–1000 (1998)
Y. Iida, Effect of atmosphere on laser vaporization and excitation processes of solid samples. Spectrochim. Acta B 45, 1353–1367 (1990)
S. Harilal, C. Bindhu, M. Tillack, F. Najmabadi, A. Gaeris, Internal structure and expansion dynamics of laser ablation plumes into ambient gases. J. Appl. Phys. 93, 2380–2388 (2003)
J. Heitz, J. Gruber, N. Arnold, D. Bäuerle, N. Ramaseder, W. Meyer, J. Hochörtler, In-situ analysis of steel under reduced ambient pressure by laser-induced break-down spectroscopy. Proc. SPIE 5120, 588–595 (2003)
S. Lui, N. Cheung, Resonance-enhanced laser-induced plasma spectroscopy: ambient gas effects. Spectrochim. Acta B 58, 1613–1623 (2003)
L. Peter, R. Noll, Material ablation and plasma state for single and collinear double pulses interacting with iron samples at ambient gas pressures below 1 bar. Appl. Phys. B 86, 159–167 (2007)
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Noll, R. (2012). Material Ablation. In: Laser-Induced Breakdown Spectroscopy. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-20668-9_7
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DOI: https://doi.org/10.1007/978-3-642-20668-9_7
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