Skip to main content

Impact of Process Parameters on EFRRPP

  • Chapter
  • First Online:
  • 667 Accesses

Abstract

The ability to deliver controlled architecture copolymers from FRRPP in an emulsion form requires a working knowledge of the stabilization of emulsions containing several components through the choice of suitable surfactant package and emulsification conditions. This chapter describes work that was done to make complex emulsions that included polymer in oil-in-water dispersions that were ultimately modified to polymer-in-water emulsions, as well as the manipulation of preemulsified systems that provided stable final products. Some additional details are provided in Dar and Caneba (2002, 2004).

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  • Dar YL, Caneba GT (2002) Transport phenomena aspects of the free-radical retrograde-precipitation polymerization (FRRPP) process. Chem Eng Commun 189:571

    Article  CAS  Google Scholar 

  • Dar YL, Caneba GT (2004) Free-radical retrograde-precipitation polymerization: mathematical modeling of styrene polymerization in diethyl ether. Chem Eng Commun 191:1634

    Article  CAS  Google Scholar 

  • de Gennes PG (1979) Polymer physics. McGraw Hill, New York, NY

    Google Scholar 

  • Immergut EH, Brandrup J (1989) Polymer handbook, 3rd edn. Wiley, New York, NY

    Google Scholar 

  • Li Z (1996) Polymer thin films on selected surfaces. Ph.D. Dissertation, State University of New York at Stony Brook, NY

    Google Scholar 

  • Nierlich M, Cotton JP, Farnoux B (1978) J Chem Phys 69:1379

    Article  CAS  Google Scholar 

  • Sigma-Aldrich Catalog (2001) Sigma-Aldrich Corporation, Milwaukee, WI

    Google Scholar 

  • Zielinski JM, Duda JL (1992) AIChE J 38:405

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Gerard Caneba .

Rights and permissions

Reprints and permissions

Copyright information

© 2011 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Caneba, G., Dar, Y. (2011). Impact of Process Parameters on EFRRPP. In: Emulsion-based Free-Radical Retrograde-Precipitation Polymerization. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-19872-4_9

Download citation

Publish with us

Policies and ethics