Skip to main content

Characterization of Olive Waste Ashes as Fertilizers

  • Chapter
  • First Online:
Recycling of Biomass Ashes

Abstract

Wet and dry olive cakes are the most important wastes generated when olive oil is produced. In recent years, both olive wastes have been incinerated to produce electricity, and thereby large amounts of fly and bottom ash are generated. In this study, physical, physicochemical, and chemical characteristics of olive waste ashes produced in Andalusian biomass power plants were analyzed to evaluate their suitability for agriculture. High variability among fly and bottom ashes may be ascribed to the origin of the olive waste and the combustion temperature. Waste olive ashes, which contained all particle sizes, showed high values of pH, salinity, water holding capacity, calcium carbonate equivalent, and P, K, Cu, and B contents. In contrast, moderate values were recorded for Ca, Mg, Zn, and Ni. Nitrogen is scarce in olive waste ashes; they thus can only be part of any fertilization strategy.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • 10th EurObserv´ER report (2010) The state of renewable energies in Europe. Paris, France. Available via EurObserv´ER. http://www.eurobserv-er.org/pdf/barobilan10.pdf. Accessed 4 April 2011

  • Agencia Andaluza de Energía (1999) Potencial y aprovechamiento energetico de la biomasa de olivaren Andalucia. http://www.agenciaandaluzadelaenergia.es/agenciadelaenergia/portal/com/bin/contenidos/publicaciones/aprovechamiento_energetico/1130059713839_potencial_y_aprovechamiento.pdf. Accessed 11 May 2010

  • Ahmaruzzarman M (2010) A review on the utilization of fly ash. Prog Energy Combust Sci 36:327–363

    Article  Google Scholar 

  • Alburquerque JA, Gonzalvez J, Garcia D, Cegarra J (2004) Agrochemical characterisation of “alperujo”, a solid by-product of the two-phase centrifugation method for olive oil extraction. Bioresour Technol 91:195–200

    Article  PubMed  CAS  Google Scholar 

  • Belevi H, Moench H (2000) Factors determining the element behaviour in municipal solid waste incinerators. 1. Field study. Environ Sci Technol 34:2501–2506

    Article  CAS  Google Scholar 

  • Benítez E, Romero E, Gómez M, Gallardo Lara F, Nogales R (2001) Biosolids and biosolids ash as sources of trace elements in the plant soil system. Water Air Soil Pollut 132:75–87

    Article  Google Scholar 

  • Bremner JM, Mulvaney CS (1982) Nitrogen-total. In: Page AL, Miller RH, Keeney DR (eds) Methods of soil analysis, part 2. American Society for Agronomy, Madison, pp 594–624

    Google Scholar 

  • Campbell DJ, Fox WE, Aitken RL, Bell LC (1983) Physical characteristics of sands amended with fly ash. Aust J Soil Res 21:147–154

    Article  Google Scholar 

  • Caputo AC, Scacchia F, Pelagagge PM (2003) Disposal of by-products in olive oil industry: waste-to-energy solutions. Appl Therm Eng 23:197–214

    Article  Google Scholar 

  • Demeyer A, Voundi JC, Verloo MG (2001) Characteristics of wood ash and influence on soil properties and nutrient uptake: an overview. Bioresour Technol 77:287–295

    Article  PubMed  CAS  Google Scholar 

  • Etiegni L, Campbell AG (1991) Physical and chemical characteristics of wood ash. Bioresour Technol 37:173–178

    Article  CAS  Google Scholar 

  • Etiegni L, Campbell AG, Mahler RL (1991) Evaluation of wood ash disposal on agricultural land. I. Potential as soil additive liming agent. Commun Soil Sci Plant Anal 22:243–256

    Article  CAS  Google Scholar 

  • Haglund N, Expert group (2008) Guideline for classification of ash from solid biofuels and peat utilised for recycling and fertilizing in forestry and agriculture. NT technical 613. Nordic Innovation Centre, Oslo, Norway. Available via Nordic Innovation Centre. http://www.nordicinnovation.net/nordtestfiler/rep613.pdf. Accessed 14 Jun 2010

  • Hakkila P (1989) Utilisation of residual forest biomass, Springer series in wood science. Springer, Berlin

    Google Scholar 

  • Huang H, Campbell AG, Folk R, Mahler RL (1992) Wood ash as a soil additive and liming agent for wheat. Field studies. Commun Soil Sci Plant Anal 23:25–33

    Article  Google Scholar 

  • Hytonen J (1998) Effect of peat ash fertilization on the nutrient status and biomass production of short-rotation willow on cut-away peatland area. Biomass Bioenergy 15:83–92

    Article  CAS  Google Scholar 

  • INE (2010). Anuario Estadístico de España. Instituto Nacional de EstadÚstica. Madrid. Available via INE. http://www.ine.es/prodyser/pubweb/anuario10/anu10_13indus.pdf. Accessed 5 April 2011

  • Jackson ML (1970) Análisis químico de suelos. Omega, Barcelona

    Google Scholar 

  • Jala S, Goyal D (2006) Fly ash as a soil ameliorant for improving crop production – a review. Bioresour Technol 97:1136–1147

    Article  PubMed  CAS  Google Scholar 

  • Kuba T, Tschöll A, Partl C, Meyer K, Insam H (2008) Wood ash admixture to organic wastes improves compost and its performance. Agric Ecosyst Environ 127:43–49

    Article  Google Scholar 

  • Lewis MN, Schmidt E (1986) Agricultural use of wood ash as a a fertilizer and liming material: field trials. TAPPI J 69:114–119

    Google Scholar 

  • Maas EV (1990) Crop salt tolerance. In: Tanji KK (ed) Agricultural salinity assessment and management. ASCE manuals and reports on engineering 71. American Society of Civil Engineering, New York, pp 262–304

    Google Scholar 

  • MAPA (1986) Métodos oficiales de análisis. Tomo III. Plantas, productos organicos, fertilizantes, suelos, agua, productos fitosanitarios y fertilizantes organicos. Publicaciones del Ministerio de Agricultura, Pesca y Alimentacion, Madrid

    Google Scholar 

  • McGrath SP, Cunliffe CH (1985) A simplified meted for the extraction of the metals Fe, Zn, Cu, Ni, Cd, Pb, Cr, Co and Mn from soil and sewage sludge. J Sci Food Agric 36:794–798

    Article  CAS  Google Scholar 

  • Meiwes KJ (1995) Application of lime and wood ash to decrease acidification of forest soils. Water Air Soil Pollut 85:143–152

    Article  CAS  Google Scholar 

  • Melgar R, Benítez E, Nogales R (2009) Bioconversion of wastes from olive oil industries using the epigeic earthworm Eisenia andrei. J Environ Sci Health B 44:488–495

    Article  PubMed  CAS  Google Scholar 

  • Merino I, Arevalo LF, Romero F (2005) Characterization and possible uses of ashes from wastewater treatment plants. Waste Manag 25:1046–1054

    Article  PubMed  CAS  Google Scholar 

  • Mozaffari M, Rosen CJ, Russelle MP, Nater EA (2000) Chemical characterization of ash from gasification of alfalfa stem: implications for ash management. J Environ Qual 29:963–972

    Article  CAS  Google Scholar 

  • Muse JK, Mitchell CC (1995) Paper mill boiler-ash and lime byproducts as soil liming materials. Agron J 87:432–438

    Article  Google Scholar 

  • Naylor LM, Schmidt EJ (1989) Paper mill wood ash as a fertilizer and liming material: field trials. TAPPI J 72:199–206

    CAS  Google Scholar 

  • Nogales R, Thompson R, Calmet A, Benitez E, Gómez M, Elvira C (1998) Feasibility of vermicomposting residues from oil production obtained using two stages centrifuge. J Environ Sci Health A 33:1491–1506

    Article  Google Scholar 

  • Nogales R, Melgar R, Benitez E (2006) Potential use of olive-waste ash from cogeneration plants as soil amendment. J Environ Sci Health B 41:1405–1415

    PubMed  CAS  Google Scholar 

  • Nurmesniemi H, Pöykió R, Perämäki P, Kuokkanen T (2005) The use of a sequential leaching procedure for heavy metal fractionation in green liquor dregs from a causticizing process at a pulp mill. Chemosphere 61:1475–1484

    Article  PubMed  CAS  Google Scholar 

  • Obernberger I, Supancic K (2009) Possibilities of ash utilisation from biomass combustion plants. In: Proceedings of the 17th European Biomass Conference & Exhibition, June/July 2009, Hamburg, 2009, pp 2373–2384

    Google Scholar 

  • Obernberger I, Biedermann F, Widmann W, Riedl R (1997) Concentrations of inorganic elements in biomass fuels and recovery in the different ash fractions. Biomass Bioenergy 12:211–224

    Article  CAS  Google Scholar 

  • Ohno T, Erich MS (1993) Incubation-derived calcium carbonate equivalence of papermill boiler-ashes derived from sludge and wood sources. Environ Pollut 79:175–180

    Article  PubMed  CAS  Google Scholar 

  • Omil B, Sanchez-Rodríguez F, Merino A (2011) Effects of ash applications on soil status, nutrition and growth of Pinus radiata D. Don plantations. In: Insam H, Knapp BA (eds) Recycling of biomass ashes. Springer, Heidelberg, pp 1–16

    Google Scholar 

  • Pathan SM, Aylmore LAG, Colmer TD (2003) Properties of several fly ash materials in relation to use as soil amendments. J Environ Qual 32:687–693

    Article  PubMed  CAS  Google Scholar 

  • Pitman RM (2006) Wood ash use in forestry – a review of the environmental impacts. Forestry 79:563–588

    Article  Google Scholar 

  • Sharma BM, Aggarwal RK, Kumar P (1990) Water retention and nutrient availability in a fly ash amended desert sandy soil: a study in vitro. Arid Soil Res Rehab 4:53–58

    Google Scholar 

  • Someshwar AV (1996) Wood and combination wood-fired boiler ash characterisation. J Environ Qual 25:962–972

    Article  CAS  Google Scholar 

  • Ulery AL, Graham RC, Amrhein C (1993) Wood-ash composition and soil pH following intense burning. Soil Sci 156:358–364

    Article  CAS  Google Scholar 

  • Vance ED (1996) Land application of wood-fired and combination boiler ashes: an overview. J Environ Qual 25:937–944

    Article  CAS  Google Scholar 

  • Yeomans J, Bremner JM (1989) A rapid and precise method for routine determination of organic carbon in soil. Commun Soil Sci Plant Anal 19:1467–1476

    Article  Google Scholar 

  • Zhang FS, Yamasaki S, Nanzyo M (2002) Waste ashes for use in agricultural production: I. Liming effect, contents of plant nutrients and chemical characteristics of some metals. Sci Total Environ 284:215–225

    Article  PubMed  CAS  Google Scholar 

Download references

Acknowledgements

This study was financed by the Junta de Andalucia, Spain, through project P07-RNM-2746. M.Q. and M.R. thank the Junta de Andalucia and CSIC, respectively, for their doctoral grants. We thank the biomass power plants of Agroenergetica de Baena, Vetejar, Agroeneregetica de Algodonales, El Tejar Autogeneración, and Planta de Biomasa La Loma for providing the fly and bottom ash from olive wastes used in this study.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Rogelio Nogales .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2011 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Nogales, R., Delgado, G., Quirantes, M., Romero, M., Romero, E., Molina-Alcaide, E. (2011). Characterization of Olive Waste Ashes as Fertilizers. In: Insam, H., Knapp, B. (eds) Recycling of Biomass Ashes. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-19354-5_5

Download citation

Publish with us

Policies and ethics