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Liquid Metals, Molten Salts, and Ionic Liquids: Some Basic Properties

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Coulombic Fluids

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 168))

Abstract

In the second chapter, some basic concepts of statistical thermodynamics of liquids and of the nearly free electron model are introduced including quantities such as the pair distribution function g(r), the structure factor S(q), and the dielectric function of electronic screening. This is followed by a more detailed description of intermolecular potentials and microscopic structures of liquid metals, molten salts, and ionic liquids, both their theoretical foundation and experimental determination. A summary of the bulk phase behaviour of Coulombic fluids with emphasis on the liquid range is given. Specific thermodynamic characteristics such as undercooling, the vapour pressures of ionic liquids, or their criticality in binary mixtures are discussed. The mechanisms of electronic and ionic transport are briefly described. In the final section on interfacial characteristics, a few fundamental relations such as the Gibbs adsorption equation and the basic equations of wetting and electrowettting together with the scenario of wetting transitions are introduced. Furthermore, topics such as the stratification at liquid metal/vapour interfaces and charge ordering at electrified liquid/solid interfaces of molten salts and ionic liquids are presented. All sections contain tables with representative numbers for the properties considered.

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Notes

  1. 1.

    In the following, we also use R for the intermolecular distance in the pair potentials.

  2. 2.

    The term surface often is used for interfaces where one of the neighbouring phases is a vapour phase or vacuum.

References

  1. H.T. Davis, Statistical Mechanics of Phases, Interfaces, and Thin Films (Wiley-VCH,New York, 1996)

    Google Scholar 

  2. D.M. Heyes, The Liquid State (Wiley, Chichester, 1998)

    Google Scholar 

  3. J.P. Hansen, I.R. McDonald, Theory of Simple Liquids (Academic, London, 1976)

    Google Scholar 

  4. N.W. Ashcroft, N.D. Mermin, Solid State Physics (Saunders College, Philadelphia, 1976)

    Google Scholar 

  5. J. Hafner, From Hamiltonians to Phase Diagrams (Springer, Berlin, 1987)

    Google Scholar 

  6. J.M. Ziman, Principle of the Theory of Solids (Cambridge University Press,Cambridge, 1965)

    Google Scholar 

  7. N.E. Cusack, The Physics of Structurally Disordered Matter (Hilger, Bristol, 1987)

    Google Scholar 

  8. J. Lindhard, Kgl. Danske Videnskab Selska. Mat-Fys. Medd. 28 (1954)

    Google Scholar 

  9. A. Rahman, Phys. Rev. B 9, 1667 (1974)

    ADS  Google Scholar 

  10. D.L. Price, K.S. Singwi, M.P. Tosi, Phys. Rev. B 2, 2983 (1970)

    ADS  Google Scholar 

  11. J.R.D. Copley, J.M. Rowe, Phys. Rev. A 9, 1656 (1974)

    ADS  Google Scholar 

  12. G. Mamantov, R. Marassi, (eds.), Molten Salt Chemistry (D. Reidel, Dordrecht, 1987)

    Google Scholar 

  13. P. Wasserscheid, T. Welton (eds.), Ionic Liquids in Synthesis (Wiley-VCH, Weinheim, 2008)

    Google Scholar 

  14. R.J. Gale, B. Gilbert, R.A. Osteryoung, Inorg. Chem. 17, 2728 (1978)

    Google Scholar 

  15. J.S. Wilkies, J.A. Levisky, R.A. Wilson, C.L. Hussey, Inorg. Chem. 21, 1263 (1982)

    Google Scholar 

  16. A.A. Famin, D.A. Floreani, L.A. King, J.S. Landers, B.J. Piersma, D.J. Steck, R.L. Vaughn, J.S. Wilkes, J.L. Williams, J. Phys. Chem. 88, 2614 (1984)

    Google Scholar 

  17. E.W.J. Mitchell, P.F.J. Poncet, R.J. Stewart, Phil. Mag. 34, 72 (1976)

    Google Scholar 

  18. M. Rovere, M.P. Tosi, Rep. Progr. Phys. 49, 1001 (1986)

    ADS  Google Scholar 

  19. G.J. Janz, Molten Salts (Academic, New York, 1967)

    Google Scholar 

  20. F.G. Edwards, J.E. Enderby, R.A. Howe, D.I. Page, J. Phys. C:. Solid. State. Phys. 8, 3483 (1975)

    ADS  Google Scholar 

  21. J.Y. Derrien, J. Dupuy, J. Phys. Paris. 36, 191 (1975)

    Google Scholar 

  22. N.H. March, M.P. Tosi, Coulomb Liquids (Academic, London, 1984)

    Google Scholar 

  23. M. Born, K. Huang, Dynamical Theory of Crystal Lattices (Oxford University Press, Oxford, 1954)

    MATH  Google Scholar 

  24. M.P. Tosi, F.G. Fumi, J. Phys. Chem. Solids 23, 45 (1964)

    ADS  Google Scholar 

  25. D.J. Adams, I.R. McDonald, J. Phys. C: Solid State Phys. 8, 2198 (1975)

    ADS  Google Scholar 

  26. L.V. Woodcock, Chem. Phys. Lett. 10, 257 (1971)

    ADS  Google Scholar 

  27. L.V. Woodcock, K. Singer, Trans. Faraday Soc. 67, 12 (1971)

    Google Scholar 

  28. S. Biggin, J. Enderby, J. Phys. C: Solid State Phys. 15, L305 (1982)

    ADS  Google Scholar 

  29. J.W. Lewis, K. Singer, L.V. Woodcock, J. Chem. Soc. Faraday Trans. 71, 41 (1975)

    Google Scholar 

  30. P. Ballone, G. Pastore, M. Tosi, J. Chem. Phys. 81, 3174 (1984)

    ADS  Google Scholar 

  31. S. Eisenberg, J.F. Jal, J. Dupuy, P. Chieux, P. Knoll, Philos. Mag. A 46, 195 (1982)

    ADS  Google Scholar 

  32. W. Andreoni, G. Galli, M.P. Tosi, Phys. Rev. Lett. 55, 1734 (1985)

    ADS  Google Scholar 

  33. J.E. Enderby, S. Biggin, in Advances in Molten Salt Chemistry, vol. 5, ed. by G. Mamantov (Elsevier, Amsterdam, 1983)

    Google Scholar 

  34. R. Triolo, A.H. Narten, J. Chem. Phys. 74, 703 (1981)

    ADS  Google Scholar 

  35. D.A. Allen, R.R. Howe, N.D. Wood, W.S. Howells, J. Chem. Phys. 94, 5071 (1991)

    ADS  Google Scholar 

  36. J. Neuefeind, Phys. Chem. Chem. Phys. 3, 3987 (2001)

    Google Scholar 

  37. A.K. Scoper, Phys. Rev. B 72, 104204 (2005)

    ADS  Google Scholar 

  38. M.H. Brooker, G.N. Papatheodorou, in Advances in Molten Salt Chemistry, vol 5, ed. by G. Mamantov (Elsevier, Amsterdam, 1983)

    Google Scholar 

  39. E.A. Pavlatou, P.A. Madden, M. Wilson, J. Chem. Phys. 107, 10446 (1997)

    ADS  Google Scholar 

  40. V.V. Brazhkin, Y. Katayama, A.G. Lyapin, S.V. Propova, Y. Inamure, H. Saitoh, W. Utsumi, JETP. Lett. 83, 13 (2005)

    Google Scholar 

  41. R. Roberto, G. Pastore, M.P. Tosi, Phys. Lett. A 373, 1083 (2009)

    ADS  Google Scholar 

  42. F. Hutchinson, M.K. Walters, A.J. Rowley, P.A. Madden, J. Chem. Phys. 110, 15821 (1999)

    ADS  Google Scholar 

  43. J.L. Gray, G.E. Maciel, J. Am. Chem. Soc. 103, 7141 (1981)

    Google Scholar 

  44. M.P. Tosi, D.L. Price, M.L. Saboungi, in Annual Review Physical Chemistry, vol 44, ed. by H.R. Strauss (Ann Review Inc, Palo Alto, 1993)

    Google Scholar 

  45. P.A. Hunt, E.J. Magime, R.M. Lynden-Bell, M.G. Del Populo, in Ionic Liquids in Synthesis, ed. by P. Wasserscheid, T. Welton (Wiley-VCH, Weinheim, 2008)

    Google Scholar 

  46. C.G. Hanke, S.L. Price, R.M. Lynden-Bell, Mol. Phys. 99, 801 (2001)

    ADS  Google Scholar 

  47. Y. Wang, G.A. Voth, J. Am. Chem. Soc. 127, 12192 (2005)

    Google Scholar 

  48. Y. Wang, S. Feng, G.A. Voth, J. Chem. Theor. Comput. 5, 1091 (2009)

    Google Scholar 

  49. B.L. Bhargava, M.L. Klein, J. Phys. Chem. A 113, 1898 (2009)

    Google Scholar 

  50. C. Spickermann et al., J. Chem. Phys. 129, 104505/1 (2008)

    Google Scholar 

  51. R.C. Remsing et al, Abstracts of Paper, 236th ACS National Meeting, Philadelphia (2008)

    Google Scholar 

  52. A.R. Porter, S.Y. Liem, P.L.A. Popelier, Phys. Chem. Chem. Phys. 10, 4240 (2008)

    Google Scholar 

  53. R.C. Remsing, Z. Liu, I. Sergeyev, G. Moyna, Phys. Chem. Chem. Phys. 10, 4240 (2008)

    Google Scholar 

  54. C. Schroder, T. Rudars, G. Neumayr, S. Benkner, O. Steinhauser, J. Chem. Phys. 127, 234503/1 (2008)

    Google Scholar 

  55. X. Wu, Z. Liu, S. Huang, W. Wang, Phys. Chem. Chem. Phys. 7, 2771 (2005)

    Google Scholar 

  56. A. Chaumont, G. Wipff, Inorg. Chem. 48, 4277 (2009)

    Google Scholar 

  57. A. Chaumont, G. Wipff, Chem.: A Eur. J. 10, 3919 (2004)

    Google Scholar 

  58. C. Hardacre, in Ionic Liquids in Synthesis, ed. by P. Wasserscheid, T. Welton (Wiley-VCH, Weinheim, 2008)

    Google Scholar 

  59. K. Fujii et al., J. Phys. Chem. B 112, 4329 (2008) and further references therein

    Google Scholar 

  60. J.R. Wilson, Metall. Rev. 10, 381 (1965)

    Google Scholar 

  61. F. Hensel, W.W. Warren, Fluid Metals – The Liquid-Vapour Transition of Metals (Princeton University Press, Princeton, 1999)

    Google Scholar 

  62. W. Freyland, F. Hensel, Ber. Bunsenges Phys. Chem. 76, 16 (1972)

    Google Scholar 

  63. G. Treiber, K. Tödheide, Ber. Bunsenges Phys. Chem. 77, 540 (1973)

    Google Scholar 

  64. N.N. Greenwood, A. Earnshaw, Chemistry of the Elements (Pergamon, Oxford, 1984)

    Google Scholar 

  65. http://www.wikipedia.org/critical point (thermodynamics)

  66. G. Raabe, J. Köhler, J. Chem. Phys. 129, 144503 (2008)

    ADS  Google Scholar 

  67. H. Ohno, in Electrodeposition from Ionic Liquids, ed. by F. Endres, D. Mac-Farlane, A. Abbot (VCH-Wiley, Weinheim, 2008)

    Google Scholar 

  68. R.F. Tournier, Physica. B 392, 79 (2007)

    ADS  Google Scholar 

  69. D. Turnbull, J. Appl. Phys. 20, 817 (1949)

    ADS  Google Scholar 

  70. J.H. Perepezko, J.S. Paik, J. Non. Cryst. Solids 61, 113 (1984)

    ADS  Google Scholar 

  71. J.H. Perepezko, J.S. Paik, Rapid solidified amorphous and crystalline alloys. Conference Proceedings Boston, Boston, MA, 1982

    Google Scholar 

  72. J.H. Perepezko, P.H. Rasmussen, I.E. Anderson, C.R. Loper, Proceedings of International Conference on Solidification 1977, Boston, MA, 1979

    Google Scholar 

  73. H. Tostmann, W. Freyland, J. Non-Crystalline Solids, 156–158:551 (1993)

    Google Scholar 

  74. W. Freyland, F. Hensel, in The Metallic and Non-Metallic States of Matter, ed. byP.P. Edwards, C.N.R. Rao (Taylor and Francis, London, 1985)

    Google Scholar 

  75. K.H. Simmrock, R. Janowski, A. Ohnsorge, Critical Data of Pure Substances (Dechema, Frankfurt/M, 1986)

    Google Scholar 

  76. D.M. Fox, W.H. Awad, J.W. Gilmann, P.H. Maupin, H.C. De Long, P.C. Trulove, Green Chem. 5, 724 (2003)

    Google Scholar 

  77. Y. Shimizu, Y. Ohte, Y. Yamanura, K. Saito, Chem. Phys. Lett. 470, 295 (2009)

    ADS  Google Scholar 

  78. A.J. Easteal, C.A. Angell, J. Phys. Chem. 74, 3987 (1970)

    Google Scholar 

  79. V. Halka, W. Freyland, Z. Phys. Chem. 222, 117 (2008)

    Google Scholar 

  80. K.R. Lovelock, C. Kolbeck, T. Cremer, N. Paape, P.S. Schulz, P. Wasserscheid, F. Maier, H.P. Steinbrück, J. Phys. Chem. B. 113, 2854 (2009)

    Google Scholar 

  81. L.P.N. Rebelo, J.N. Comingia Lopez, J.M.S. Esperanca, E. Filipe, J. Phys. Chem. B 109, 6041 (2005)

    Google Scholar 

  82. J.P. Armstrong, C. Hurst, R.G. Jones, P. Licence, K.R.J. Lovelock, R.G. Satterley, J. Villar-Garcia, Phys. Chem. Chem. Phys. 9, 982 (2007)

    Google Scholar 

  83. D.H. Zaitsau, G.H. Kabo, A.A. Strechan, Y.U. Paulechka, A. Tschersich, S.P. Verevkin, A. Heintz, J. Phys. Chem. A. 110, 7303 (2006)

    Google Scholar 

  84. V.N. Emel’yanenko, S.P. Verevkin, A. Heintz, J. Am. Chem. Soc. 129, 3930 (2007)

    Google Scholar 

  85. P. Scamwells, Aust. J. Chem. 58, 155 (2005)

    Google Scholar 

  86. J.V. Senger, J.M.H. Levelt Sengers, Ann. Rev. Phys. Chem. 37, 189 (1986)

    ADS  Google Scholar 

  87. Y. Levin, X. Li, M.E. Fisher, Phys. Rev. Lett. 73, 2716 (1994)

    ADS  Google Scholar 

  88. M.E. Fisher J. Phys. Condens Matter 8:9103 (1996)

    Google Scholar 

  89. A.G. Moreira, M.M. Telo da Gama, M.E. Fisher J. Chem. Phys. 110:10058 (1999)

    Google Scholar 

  90. Y.C. Kim, M.E. Fisher Chem. Phys. Lett. 414, 185 (2005)

    Google Scholar 

  91. S.K. Das, J. Horbach, K. Binder, M.E. Fisher, J.V. Sengers J. Chem. Phys. 125:024501/1 (2006)

    Google Scholar 

  92. K.S. Pitzer, J. Phys. Chem. 99, 13070 (1995)

    Google Scholar 

  93. T. Narayana, K.S. Pitzer Phys. Rev. Lett. 73, 3002 (1994)

    ADS  Google Scholar 

  94. K.S. Pitzer, Acc. Chem. Res. 23, 333 (1990)

    Google Scholar 

  95. H. Weingärtner, W. Schröer, J. Mol. Liquids. 66, 107 (1995)

    Google Scholar 

  96. W. Freyland, in Metal-Insulator Transitions Revisited, ed. by P.P. Edwards, C.N.R. Rao (Taylor and Francis, London, 1995)

    Google Scholar 

  97. P. Chieux, M.J. Sienko, J. Chem. Phys. 53, 566 (1970)

    ADS  Google Scholar 

  98. J.F. Jal, P. Chieux, J. Dupuy, J.P. Dupin, J. Phys. 41, 657 (1980)

    Google Scholar 

  99. H. Weingärtner, T. Merkel, U. Maurer, J.P. Lonzen, H. Glasbrenner, S. Kaeshammer, Ber. Bunsenges Phys. Chem. 95, 1579 (1991)

    Google Scholar 

  100. M. Kleemaier, S. Wiegand, W. Schröer, H. Weingärtner, J. Chem. Phys. 110, 3085 (1999)

    ADS  Google Scholar 

  101. W. Schröer, J. Mol. Liquids. 125, 164 (2006)

    Google Scholar 

  102. W.H. Young, A. Meyer, G.E. Kilby, Phys. Rev. 160, 482 (1967)

    ADS  Google Scholar 

  103. J.E. Enderby, in Liquid Metals, Chemistry and Physics, ed. by S.Z. Beer (Marcel Dekker, New York, 1972)

    Google Scholar 

  104. U. Even, W. Freyland, J. Phys. F 5, 104 (1975)

    ADS  Google Scholar 

  105. A.A. Dworkin, H.R. Bronstein, M.A. Bredig, J. Phys. Chem. 67, 2715 (1963)

    Google Scholar 

  106. S. Zein El Abedin, O. Terakado, F. Endres, D. Nattland, W. Freyland, Phys. Chem. Chem. Phys. 4, 5335 (2002)

    Google Scholar 

  107. O. Terakado, P. Poh, W. Freyland, J. Phys. Condens. Matter 15, 1553 (2003)

    ADS  Google Scholar 

  108. L.F. Grantham, S.J. Yosim, in Characterization and Analysis, G. Mamantov ed. by (Marcel Dekker, New York, 1969)

    Google Scholar 

  109. U. Stöhr, W. Freyland, Phys. Chem. Chem. Phys. 1, 4383 (1999)

    Google Scholar 

  110. J.P. Hansen, I.R. McDonald, J. Phys. C Solid State Phys. 7, L384 (1974)

    ADS  Google Scholar 

  111. A. Noda, M. Watanabe, K. Hayamizu, J. Phys. Chem. B 105, 4603 (2001)

    Google Scholar 

  112. N.A. Stolwijk, S. Obeidi, Electrochimica Acta. 54, 1645 (2009)

    Google Scholar 

  113. A.W. Adamson, A.P. Gast, Physical Chemistry of Surfaces, 3rd edn. (Wiley, New York 1997)

    Google Scholar 

  114. D.R. Clarke, M. Rühle, A.P. Tomsia (eds.), Annual Review of Materials Research, vol 38. (Annual Reviews, Palo Alto, 2008)

    Google Scholar 

  115. S.A. Rice, J. Gryko, V. Mohanty, in Fluid Interfacial Phenomena, ed. by C.A. Croxton (Wiley, New York, 1986)

    Google Scholar 

  116. B.C. Lu, S.A. Rice, J. Chem. Phys. 68, 5588 (1978)

    ADS  Google Scholar 

  117. M.J. Regan, E.H. Kawamoto, S. Lee, P.S. Pershan, N. Maskil, M. Deutch, O.M. Magnussen, B.M. Ocko, L.E. Berman, Phys. Rev. Lett. 75, 2498 (1995); Phys. Rev. Lett. 74, 444

    Google Scholar 

  118. P.S. Pershan, S.E. Stoltz, O.G. Shpyrko, M. Deutsch, V.S. Balagurusamy, M. Meron, B. Liu, R. Streitel, Phys. Rev. B 79, 115417/1 (2009)

    Google Scholar 

  119. M. Zhao, D.S. Chekmarev, Z.H. Lai, S.A. Rice, Phys. Rev. E. 56, 7033 (1997)

    ADS  Google Scholar 

  120. A. Gross, Theoretical Surface Science (Springer, Berlin, 2003)

    Google Scholar 

  121. B.C. Allen, in Liquid Metals,Chemistry and Physics, ed. by S.Z. Beer (Marcel Dekker, New York, 1972)

    Google Scholar 

  122. A. Ayyad, W. Freyland, Surf. Sci. 506, 1 (2002)

    ADS  Google Scholar 

  123. V.K. Kurnikov, K.B. Khokonov, J. Appl. Phys. 54, 1346 (1983)

    ADS  Google Scholar 

  124. B. Vinet, L. Magnusson, H. Fredriksson, P.J. Desrè, J. Colloid Interface Sci. 255, 363 (2002)

    Google Scholar 

  125. H.M. Lu, Q. Jiang, J. Phys. Chem. B 109, 15463 (2005)

    Google Scholar 

  126. M.C. Desjonqueres, F. Cyrot-Lackmann, Surf. Sci. 50, 257 (1975)

    ADS  Google Scholar 

  127. D. Turnbull, Sol. State Phys. 3, 225 (1956)

    Google Scholar 

  128. R.M. Digilov, Physica. B 352, 53 (2004)

    ADS  Google Scholar 

  129. J.W. Cahn, J. Chem. Phys. 66, 3667 (1977)

    ADS  Google Scholar 

  130. W. Freyland, D. Nattland, Ber. Bunsenges Phys. Chem. 102, 1 (1998)

    Google Scholar 

  131. S. Dietrich, Wetting Phenomena. in Phase Transitions and Critical Phenomena, vol 12, ed. by C.Domb, J.L. Lebowiz (Academic, London, 1988)

    Google Scholar 

  132. M. Rauscher, S. Dietrich, Wetting Phenomena in Nanofludics, in Annual Review of Materials Research, vol 38, ed. by D.R. Clarke, M. Rühle, A.P. Tomsia (Annual Reviews, Palo Alto, 2008)

    Google Scholar 

  133. D. Bonn, J. Eggers, J. Indekeu, J. Meunier, E. Rolley, Rev. Mod. Phys. 81, 739 (2009)

    ADS  Google Scholar 

  134. M.M. Telo da Gama, R. Evans, T.J. Sluckin, Mol. Phys. 41, 1355 (1980)

    ADS  Google Scholar 

  135. R. Evans, T.J. Sluckin, Mol. Phys. 40, 413 (1980)

    ADS  MathSciNet  Google Scholar 

  136. D.M. Heyes, J.H.R. Clarke, J. Chem. Soc. Faraday Trans. 77, 1089 (1981)

    Google Scholar 

  137. D.M. Heyes, Phys. Rev. B 30, 1282 (1984)

    ADS  Google Scholar 

  138. G. Navasmés, P. Tarazona, Mol. Phys. 37, 1077 (1979)

    ADS  Google Scholar 

  139. U. Tartaglino, T. Zykova-Timan, F. Ercolessi, E. Tossati, Phys. Rep. 411, 291 (2005)

    ADS  Google Scholar 

  140. G. Grange, B. Mutaftschiev, Surf. Sci. 47, 723 (1975)

    ADS  Google Scholar 

  141. T. Zykova-Timan, D. Ceresoli, U. Tartaglino, E. Tosatti, Phys. Rev. Lett. 94, 176105–1 (2005)

    ADS  Google Scholar 

  142. R.M. Lynden-Bell, Mol. Phys. 101, 2625 (2003)

    ADS  Google Scholar 

  143. B.L. Bhargava, S. Balasubramanian, J. Am. Chem. Soc. 128, 10073 (2006)

    Google Scholar 

  144. P.G. Law, P.R. Watson, A.I. Carmichael, K.R. Seddon, Phys. Chem. Chem. Phys. 3, 2879 (2001)

    Google Scholar 

  145. S. Rivera-Rubero, S. Baldelli, J. Am. Chem. Soc. 126, 11788 (2004)

    Google Scholar 

  146. E. Sloutskin, B.N. Ocko, L. Tamann, L. Kuzmenko, T. Gog, M. Deutsch, J. Am. Chem. Soc. 127, 7796 (2005)

    Google Scholar 

  147. Y. Jeon, J. Sung, W. Bru, D. Vaknin, Y. Ouchi, D. Kim, J. Phys. Chem. C. 112, 19649 (2008)

    Google Scholar 

  148. I. Langmuir, Science 88, 430 (1938)

    ADS  Google Scholar 

  149. S. Staroske, W. Freyland, D. Nattland, J. Chem. Phys. 115, 7669 (2001)

    ADS  Google Scholar 

  150. M. Mezger, H. Schröer, H. Reichert, S. Schramm, J.S. Okasinski, S. Schöder, V. Honkimaki, M. Deutsch, B.M. Ocko, J. Ralston, M. Rohwerder, M. Stramann, H. Dosch, Science 322, 424 (2008)

    ADS  Google Scholar 

  151. F. Mugele, J.C. Baret, J. Phys. Condens. Matter. 17, R705 (2005)

    ADS  Google Scholar 

  152. P. Dubois, G. Marchand, Y. Fouillet, J. Berthier, T. Douki, F. Hassine, S. Gmout, M. Vaultier, Anal. Chem. 78, 4909 (2006)

    Google Scholar 

  153. S. Millefiorini, A.H. Tkaxzyk, R. Sedev, J. Efthimiais, J. Ralston, J. Am. Chem. Soc. 128, 308 (2006)

    Google Scholar 

  154. Y. Sato, T. Ejima, M. Fukasawa, K. Abe, J. Phys. Chem. 94, 1991 (1990)

    Google Scholar 

  155. V. Halka, R. Tsekov, W. Freyland, J. Phys. Condensed Matter 17, S3325 (2005)

    ADS  Google Scholar 

  156. V. Halka, R. Tsekov, W. Freyland, Phys. Chem. Chem. Phys. 7, 2038 (2005)

    Google Scholar 

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    Werner Freyland

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Freyland, W. (2011). Liquid Metals, Molten Salts, and Ionic Liquids: Some Basic Properties. In: Coulombic Fluids. Springer Series in Solid-State Sciences, vol 168. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-17779-8_2

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