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Characterization of the Functionality of Karstic Systems Based on the Study of the SIc–Pco2 Relation

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Part of the book series: Environmental Earth Sciences ((EESCI,volume 1))

Abstract

This paper aims at characterizing the functionality of karstic systems. In order to do so, an extend of a method based on the saturated index with respect to calcite (SIc) and CO2 partial pressure (Pco2) is used. The initial method already applied by Peyraube et al. (2012) uses the Pco2 of water at equilibrium with atmosphere (Pco2_eq) and the Pco2 of water for a SIc equal to zero (Pco2_sat). The Pco2_sat variation gives information on flows conditions within the karstic system. It describes the degree of karstification of the system. Systems with developed saturated zone are characterized by under-saturated waters as well as saturated ones with variable Pco2_sat. At last, fissured system has Pco2_sat which vary only slightly. Moreover, variations of Pco2_sat show homogenization capacities of a karst.

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References

  • Batiot C, Emblanch C, Blavoux B (2003) Total organic carbon (TOC) and magnesium (Mg2+): two complementary tracers of residence time in karstic systems. C R Geosci 335:205–214

    Article  Google Scholar 

  • Couturaud A (1993) Hydrogéologie de la partie occidentale du système karstique de Vaucluse, Thèse doctorale Université d’Avignon

    Google Scholar 

  • Cowan D, Osborne MC, Banner JL (2013) Temporal variability of cave-air CO2 in Central Texas. J Cave Karst Studies 75:38–50

    Google Scholar 

  • Lastennet R, Mudry J (1997) Role of karstification and rainfall in the behavior of heterogeneous karst system. Environ Geol 32(2):114–123

    Article  Google Scholar 

  • Peyraube N, Lastennet R, Denis A (2012) Geochemical evolution of groundwater in the unsaturated zone of karstic massif, using the Pco2–SIc relationship. J Hydrol 430:13–24

    Article  Google Scholar 

  • Plummer LN, Busenberg E (1982) The solubility of calcite, aragonite and waterite in CO2–H2O solutions between 0 and 90 °C, and evaluation of the aqueous model of the system CaCO3–CO2–H2O. Geochim Cosmochim Acta 46:1011–1040

    Article  Google Scholar 

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Correspondence to S. Minvielle .

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Minvielle, S., Peyraube, N., Lastennet, R., Denis, A. (2015). Characterization of the Functionality of Karstic Systems Based on the Study of the SIc–Pco2 Relation. In: Andreo, B., Carrasco, F., Durán, J., Jiménez, P., LaMoreaux, J. (eds) Hydrogeological and Environmental Investigations in Karst Systems. Environmental Earth Sciences, vol 1. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-17435-3_3

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