Abstract
Palladium-catalyzed multicomponent coupling and annulation reactions have become important tools in organic synthesis. Recently, palladium(IV) complexes have been proposed as intermediates in catalytic cycles of these transformations, although experimental evidence for their involvement is frequently lacking. Examples of such catalytic annulation reactions are discussed, followed by a review of studies performed with stoichiometric isolable or semistable palladium(IV) complexes seeking experimental evidence for feasibility of the participation of palladium(IV) intermediates in cascade carbon–carbon and carbon–heteroatom bond-forming sequences.
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Malinakova, H.C. (2011). Palladium(IV) Complexes as Intermediates in Catalytic and Stoichiometric Cascade Sequences Providing Complex Carbocycles and Heterocycles. In: Canty, A. (eds) Higher Oxidation State Organopalladium and Platinum Chemistry. Topics in Organometallic Chemistry, vol 35. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-17429-2_4
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DOI: https://doi.org/10.1007/978-3-642-17429-2_4
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