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Elastomer Clay Nanocomposites for Packaging

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Recent Advances in Elastomeric Nanocomposites

Part of the book series: Advanced Structured Materials ((STRUCTMAT,volume 9))

Abstract

Packaging application of the materials require strong barrier as well as mechanical properties. Majority of the reports in the literature have studied the mechanical properties while neglecting the barrier properties and it is generally assumed that the improvement in mechanical properties leads to automatic enhancement of barrier performance. However, it may not be true in all the cases as the permeation properties are more sensitive to interface between the polymer and filler phases. The incompatibility between the filler surface modification and polymer or the presence of excess surface modification on the filler surface can negatively impact the permeation properties, while the mechanical performance may still enhance. The current chapter focuses on the two very important elastomeric materials used in large amounts in packaging industry. Various factors affecting the barrier performance have been quantified. Use of not only montmorillonite, but also vermiculite has been presented. The importance of clean filler surface on the composite properties has also been underlined. The determination of average aspect ratio as a tool to control or tune the microstructure and properties of the nanocomposites has been shown with the help of finite element computer models.

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References

  1. Mittal, V.: Barrier properties of composite materials. In: Mittal, V. (ed.) Barrier Properties of Polymer Clay Nanocomposites. Nova Science Publishers, New York (2009)

    Google Scholar 

  2. Osman, M.A., Mittal, V., Morbidelli, M., Suter, U.W.: Polyurethane adhesive nanocomposites as gas permeation barrier. Macromolecules 36, 9851–9858 (2003)

    Article  CAS  Google Scholar 

  3. Xu, R., Manias, E., Snyder, A.J., Runt, J.: New biomedical poly(urethane urea)-layered silicate nanocomposites. Macromolecules 34, 337–339 (2001)

    Article  CAS  Google Scholar 

  4. Chang, J.H., An, Y.U.: Nanocomposites of polyurethane with various organoclays: thermomechanical properties, morphology, and gas permeability. J. Polym. Sci. Polym. Chem. 40, 670–677 (2002)

    CAS  Google Scholar 

  5. Tortora, M., Gorrasi, G., Vittoria, V., Galli, G., Ritrovati, S., Chiellini, E.: Structural characterization and transport properties of organically modified montmorillonite/polyurethane nanocomposites. Polymer 43, 6147–6157 (2002)

    Article  CAS  Google Scholar 

  6. Wang, Z., Pinnavia, T.J.: Nanolayer reinforcement of elastomeric polyurethane. Chem. Mater. 10, 3769–3771 (1998)

    Article  CAS  Google Scholar 

  7. Zilg, C., Thomann, R., Mulhaupt, R., Finter, J.: Polyurethane nanocomposites containing laminated anisotropic nanoparticles derived from organophilic layered silicates. Adv. Mater. 11, 49–52 (1999)

    Article  CAS  Google Scholar 

  8. Chen, T.K., Tien, Y.I., Wie, K.H.: Synthesis and characterization of novel segmented polyurethane/clay nanocomposites. Polymer 41, 1345–1353 (2000)

    Article  CAS  Google Scholar 

  9. Ma, J., Zhang, S., Qi, Z.: Synthesis and characterization of elastomeric polyurethane/clay nanocomposites. J. Appl. Polym. Sci. 82, 1444–1448 (2001)

    Article  CAS  Google Scholar 

  10. Yao, K.J., Song, M., Hourston, D.J., Luo, D.Z.: Polymer/layered clay nanocomposites: 2 polyurethane nanocomposites. Polymer 43, 1017–1020 (2002)

    Article  CAS  Google Scholar 

  11. Tien, Y.I., Wei, K.H.: Hydrogen bonding and mechanical properties in segmented montmorillonite/polyurethane nanocomposites of different hard segment ratios. Polymer 42, 3213–3221 (2001)

    Article  CAS  Google Scholar 

  12. Tien, Y.I., Wei, K.H.: High-tensile-property layered silicates/polyurethane nanocomposites by using reactive silicates as pseudo chain extenders. Macromolecules 34, 9045–9052 (2001)

    Article  CAS  Google Scholar 

  13. Tien, Y.I., Wei, K.H.: The effect of nano-sized silicate layers from montmorillonite on glass transition, dynamic mechanical, and thermal degradation properties of segmented polyurethane. J. Appl. Polym. Sci. 86, 1741–1748 (2002)

    Article  CAS  Google Scholar 

  14. Osman, M.A., Mittal, V., Morbidelli, M., Suter, U.W.: Epoxy-layered silicate nanocomposites and their gas permeation properties. Macromolecules 37, 7250–7257 (2004)

    Article  CAS  Google Scholar 

  15. Lan, T., Pinnavaia, T.J.: Clay-reinforced epoxy nanocomposites. Chem. Mater. 6, 2216–2219 (1994)

    Article  CAS  Google Scholar 

  16. Messersmith, P.B., Giannelis, E.P.: Synthesis and characterization of layered silicate-epoxy nanocomposites. Chem. Mater. 6, 1719–1725 (1994)

    Article  CAS  Google Scholar 

  17. Lan, T., Kaviratna, P.D., Pinnavaia, T.J.: Mechanism of clay tactoid exfoliation in epoxy-clay nanocomposites. Chem. Mater. 7, 2144–2150 (1995)

    Article  CAS  Google Scholar 

  18. Zilg, C., Mulhaupt, R., Finter, J.: Morphology and toughness/stiffness balance of nanocomposites based upon anhydride-cured epoxy resins and layered silicates. Macromol. Chem. Phys. 200, 661–670 (1999)

    Article  CAS  Google Scholar 

  19. Brown, J.M., Curliss, D., Vaia, R.A.: Thermoset-layered silicate nanocomposites. Quaternary ammonium montmorillonite with primary diamine cured epoxies. Chem. Mater. 12, 3376–3384 (2000)

    Article  CAS  Google Scholar 

  20. Zerda, A.S., Lesser, A.J.: Intercalated clay nanocomposites: morphology, mechanics, and fracture behavior. J. Polym. Sci. Polym. Phys. 39, 1137–1146 (2001)

    Article  CAS  Google Scholar 

  21. Kornmann, X., Lindberg, H., Berglund, L.A.: Synthesis of epoxy-clay nanocomposites: influence of the nature of the clay on structure. Polymer 42, 1303–1310 (2001)

    Article  CAS  Google Scholar 

  22. Kornmann, X., Thomann, R., Mulhaupt, R., Finter, J., Berglund, L.: Synthesis of amine-cured, epoxy-layered silicate nanocomposites: the influence of the silicate surface modification on the properties. J. Appl. Polym. Sci. 86, 2643–2652 (2002)

    Article  CAS  Google Scholar 

  23. Kong, D., Park, C.E.: Real time exfoliation behavior of clay layers in epoxy-clay nanocomposites. Chem. Mater. 15, 419–424 (2003)

    Article  CAS  Google Scholar 

  24. Ma, J., Yu, Z.Z., Zhang, Q.X., Xie, X.L., Mai, Y.W., Luck, I.: A novel method for preparation of disorderly exfoliated epoxy/clay nanocomposite. Chem. Mater. 16, 757–759 (2004)

    Article  CAS  Google Scholar 

  25. Mittal, V.: Epoxy-vermiculite nanocomposites as gas permeation barrier. J. Compos. Mater. 42, 2829–2839 (2008)

    Article  CAS  Google Scholar 

  26. Mittal, V.: Effect of the presence of excess ammonium ions on the clay surface on permeation properties of epoxy nanocomposites. J. Mater. Sci. 43, 4972–4978 (2008)

    Article  CAS  Google Scholar 

  27. Osman, M.A., Atallah, A., Suter, U.W.: Influence of excessive filler coating on the tensile properties of LDPE–calcium carbonate composites. Polymer 45, 1177–1183 (2004)

    Article  CAS  Google Scholar 

  28. Morgan, A.B., Harris, J.D.: Effects of organoclay Soxhlet extraction on mechanical properties, flammability properties and organoclay dispersion of polypropylene nanocomposites. Polymer 44, 2313–2320 (2003)

    Article  CAS  Google Scholar 

  29. Kadar, F., Szazdi, L., Fekete, E., Pukanszky, B.: Surface characteristics of layered silicates: influence on the properties of clay/polymer nanocomposites. Langmuir 22, 7848–7854 (2006)

    Article  CAS  Google Scholar 

  30. Osman, M.A., Mittal, V., Lusti, H.R.: The aspect ratio and gas permeation in polymer-layered silicate nanocomposites. Macromol. Rapid Commun. 25, 1145–1149 (2004)

    Article  CAS  Google Scholar 

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Mittal, V. (2011). Elastomer Clay Nanocomposites for Packaging. In: Mittal, V., Kim, J., Pal, K. (eds) Recent Advances in Elastomeric Nanocomposites. Advanced Structured Materials, vol 9. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-15787-5_9

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