Abstract
Functions of zeolites as catalysts and adsorbents are related with the observed acidic properties. The turnover frequency and activation energy of alkane cracking depend on the ammonia desorption heat. Desorption heat of toluene on Na-zeolite is related with the ammonia adsorption heat of corresponding H-zeolite. Highly active catalysts for Friedel–Crafts alkylation (Ga/MCM-41) and amination of phenol (Ga/ZSM-5) are found based on the ammonia TPD analysis.
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Niwa, M., Katada, N., Okumura, K. (2010). Catalytic Activity and Adsorption Property. In: Characterization and Design of Zeolite Catalysts. Springer Series in Materials Science, vol 141. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-12620-8_5
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DOI: https://doi.org/10.1007/978-3-642-12620-8_5
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