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Ultra-Trace Analysis of Palladium: State-of-the-Art and Future Challenges

  • C. PulsEmail author
  • A. Limbeck
  • S. Hann
Chapter
Part of the Environmental Science and Engineering book series (ESE)

Abstract

Due to the introduction of the three-way catalytic converter (TWC) in Europe in the mid-eighties, determination of platinum group elements (PGE) in environmental compartments has received elevated interest over the past two decades. While improving air quality by converting hydrocarbons, carbon monoxide, and nitrogen oxides into the less harmful substances carbon dioxide, nitrogen, and water, the use of these devices constitutes a new source for the widespread emission of PGE into the environment.

Keywords

Instrumental Neutron Activation Analysis Road Dust Platinum Group Element Catalytic Converter Flame Atomic Absorption Spectrometry 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgments

The authors gratefully acknowledge the financial support from the Austrian Science Fund-FWF (Project Nr.: P20838-N17).

References

  1. Amosse J (1998) Determination of platinum-group elements and gold in geological matrixes by inductively coupled plasma-mass spectrometry (ICP-MS) after separation with selenium and tellurium carriers. Geostand Newslett 22:93–102CrossRefGoogle Scholar
  2. Balcerzak M (2002) Sample digestion methods for the determination of traces of precious metals by spectrometric techniques. Anal Sci 18:737–750CrossRefGoogle Scholar
  3. Barbante C, Veysseyre A, Ferrari C, Van de Velde K, Morel C, Capodaglio G, Cescon P, Scarponi G, Boutron C (2001) Greenland snow evidence of large scale atmospheric contamination for platinum, palladium, and rhodium. Env Sci Technol 35:835–839CrossRefGoogle Scholar
  4. Barefoot RR (1999) Distribution and speciation of platinum group elements in environmental matrices. Trends Anal Chem 18:702–711CrossRefGoogle Scholar
  5. Begerow J, Turfeld M, Dunemann L (1997) Determination of physiological palladium, platinum, iridium and gold levels in human blood using double focusing magnetic sector field inductively coupled plasma mass spectrometry. J Anal At Spectrom 12:1095–1098CrossRefGoogle Scholar
  6. Bencs L, Ravindra K, Van Grieken R (2003) Methods for the determination of platinum group elements originating from the abrasion of automotive catalytic converters. Spectrochim Acta B 58:1723–1755CrossRefGoogle Scholar
  7. Boch K, Schuster M, Risse G, Schwarzer M (2002) Microwave-assisted digestion procedure for the determination of palladium in road dust. Anal Chim Acta 459:257–265CrossRefGoogle Scholar
  8. Brzezicka M, Szmyd E (1999) Investigation of the influence of interfering elements on the determination of palladium in copper ores by graphite furnace atomic absorption spectrometry. Spectrochim Acta B 54:883–889CrossRefGoogle Scholar
  9. Caroli S, Alimonti A, Petrucci F, Bocca B, Krachler M, Forastiere F, Sacerdote MT, Mallone S (2001) Assessment of exposure to platinum group metals in urban children. Spectrochim Acta B 56:1241–1248CrossRefGoogle Scholar
  10. Colombo C, Monhemius AJ, Plant JA (2008) Platinum, palladium and rhodium release from vehicle exhaust catalysts and road dust exposed to simulated lung fluids. Ecotoxicol Env Saf 71:722–730CrossRefGoogle Scholar
  11. da Silva MAM, Frescura VLA, Curtius AJ (2001) Determination of noble metals in biological samples by electrothermal vaporization inductively coupled plasma mass spectrometry, following cloud point extraction. Spectrochim Acta B 56:1941–1949CrossRefGoogle Scholar
  12. da Silva LID, de Souza Sarkis JE, Zotin FMZ, Carneiro MC, Neto AA, da Silva ASAG, Cardoso MJB, Monteiro MIC (2008) Traffic and catalytic converter-related atmospheric contamination in the metropolitan region of the city of Rio de Janeiro, Brazil. Chemosphere 71:677–684CrossRefGoogle Scholar
  13. de Vos E, Edwards SJ, McDonald I, Wray DS, Carey PJ (2002) A baseline survey of the distribution and origin of platinum group elements in contemporary fluvial sediments of the Kentish Stour, England. Appl Geochem 17:1115–1121CrossRefGoogle Scholar
  14. Ek KH, Morrison GM, Rauch S (2004) Environmental routes for platinum group elements to biological materials—a review. Sci Total Env 334–335:21–38CrossRefGoogle Scholar
  15. Ely JC, Neal CR, O’Neill J, Jain JC (1999) Quantifying the platinum group elements (PGE) and gold in geological samples using cation exchange pretreatment and ultrasonic nebulization inductively coupled plasma-mass spectrometry (USN-ICP-MS). Chem Geol 157:219–234CrossRefGoogle Scholar
  16. Falta T, Limbeck A, Stingeder G, Hann S (2007) Ultra-trace determination of palladium in human urine samples via flow injection coupled with ICP-MS. At Spectr 28:81–89Google Scholar
  17. Fraser MP, Cass GR, Simoneit BRT (1999) Particulate organic compounds emitted from motor vehicle exhaust in the atmosphere. Atmos Env 33:2715–2724CrossRefGoogle Scholar
  18. Fritz JS (1999) Analytical solid-phase extraction. Wiley-VCH, New YorkGoogle Scholar
  19. Georgieva M, Pihlar B (1997) Determination of palladium by adsorptive stripping voltammetry. Fresenius J Anal Chem 357:847–880CrossRefGoogle Scholar
  20. Godlewska-Zylkiewicz B, Lesniewska BA, Gasiewska U, Hulanicki A (2000) Ion-exchange preconcentration and separation of trace amounts of platinum and palladium. Anal Lett 33:2805–2820CrossRefGoogle Scholar
  21. Gomez B, Gomez M, Sanchez JL, Fernandez R, Palacios MA (2001) Platinum and rhodium distribution in airborne particulate matter and road dust. Science Total Env 269:131–144CrossRefGoogle Scholar
  22. Gomez MB, Gomez MM, Palacios MA (2003) ICP-MS determination of Pt, Pd and Rh in airborne and road dust after tellurium coprecipitation. J Anal At Spectrom 18:80–83CrossRefGoogle Scholar
  23. Hann S, Köllensperger G, Kanitsar K, Stingeder G (2001) ICP-SFMS determination of palladium using IDMS in combination with on-line and off-line matrix separation. J Anal At Spectrom 16:1057–1063CrossRefGoogle Scholar
  24. Heumann KG (2004) Isotope-dilution ICP-MS for trace element determination and speciation: from a reference method to a routine method? Anal Bioanal Chem 378:318–329CrossRefGoogle Scholar
  25. Hossain KZ, Honjo T (2000) Separation of trace amounts of palladium(II) with crown ether from hydrochloric acid and potassium thiocyanate media. Fresenius J Anal Chem 367:141–145CrossRefGoogle Scholar
  26. Jarvis I, Totland MM, Jarvis KE (1997) Determination of the platinum-group elements in geological materials by ICP-MS using microwave digestion, alkali fusion and cation-exchange chromatography. Chem Geol 143:27–42CrossRefGoogle Scholar
  27. Jarvis KE, Parry SJ, Piper JM (2001) Temporal and spatial studies of autocatalyst-derived platinum, rhodium, and palladium and selected vehicle-derived trace elements in the environment. Env Sci Technol 35:1031–1036CrossRefGoogle Scholar
  28. Johnson Matthey Precious Metal Marketing, Johnson Matthey Plc, London, UK, 2009. http://www.platinum.matthey.com/publications/12108520516719.html
  29. Kanitsar K, Köllensperger G, Hann S, Limbeck A, Puxbaum H, Stingeder G (2003) Determination of Pt, Pd and Rh by inductively coupled plasma sector field mass spectrometry (ICP-SFMS) in size-classified urban aerosol samples. J Anal At Spectrom 18:239–246CrossRefGoogle Scholar
  30. Kántor T (2001) Electrothermal vaporization and laser ablation sample introduction for flame and plasma spectrometric analysis of solid and solution samples. Spectrochim Acta B 56:1523–1563CrossRefGoogle Scholar
  31. Köllensberger G, Hann S, Stingeder G (2000) Determination of Rh, Pd and Pt in environmental silica containing matrices: capabilities and limitations of ICP-MS. J Anal At Spectrom 15:1553–1557CrossRefGoogle Scholar
  32. Kovacheva P, Djingova R (2002) Ion-exchange method for separation and concentration of platinum and palladium for analysis of environmental samples by inductively coupled plasma atomic emission spectrometry. Anal Chim Acta 464:7–13CrossRefGoogle Scholar
  33. Krachler M, Alimonti A, Pertrucci F, Irgolic KJ, Forastiere F, Caroli S (1998) Analytical problems in the determination of platinum-group metals in urine by quadrupole and magnetic sector field inductively coupled plasma mass spectrometry. Anal Chim Acta 363:1–10CrossRefGoogle Scholar
  34. Lesniewska BA, Godlewska-Zylkiewicz B, Ruszczynska A, Bulska E, Hulanicki A (2006) Elimination of interferences in determination of platinum and palladium in environmental samples by inductively coupled plasma mass spectrometry. Anal Chim Acta 564:236–242CrossRefGoogle Scholar
  35. Limbeck A (2005) Short-term variation of palladium in airborne particulate matter. In: Zereini F, Alt F (eds) Palladium emissions in the environment: analytical methods, environmental assessment and health effects. Springer, Berlin, pp 381–396Google Scholar
  36. Limbeck A (2006) Microwave-assisted UV-digestion procedure for the accurate determination of Pd in natural waters. Anal Chim Acta 575:114–119CrossRefGoogle Scholar
  37. Limbeck A, Rendl J, Puxbaum H (2003) ETAAS determination of palladium in environmental samples with on-line preconcentration and matrix separation. J Anal At Spectrom 18:161–165CrossRefGoogle Scholar
  38. Limbeck A, Rendl J, Heimburger G, Kranabetter A, Puxbaum H (2004) Seasonal variation of palladium, elemental carbon and aerosol mass concentrations in airborne particulate matter. Atmos Env 38:1979–1987CrossRefGoogle Scholar
  39. Limbeck A, Puls C, Handler M (2007) Platinum and palladium emissions from on-road vehicles in the Kaisermühlen tunnel (Vienna, Austria). Env Sci Technol 41:4938–4945CrossRefGoogle Scholar
  40. Liu P, Su Z, Wu X, Pu Q (2002) Application of isodiphenylthiourea immobilized silica gel to flow injection on-line microcolumn preconcentration and separation coupled with flame atomic absorption spectrometry for interference-free determination of trace silver, gold, palladium and platinum in geological and metallurgical samples. J Anal At Spectrom 17:125–130CrossRefGoogle Scholar
  41. Lough GC, Schauer JJ, Park J, Shafer MM, DeMinter JT, Weinstein JP (2005) Emissions of metals associated with motor vehicle roadways. Env Sci Technol 39:826–836CrossRefGoogle Scholar
  42. Matsubara I, Takeda Y, Ishida K (2000) Improved recovery of trace amounts of gold (III), palladium (II) and platinum (IV) from large amounts of associated base metals using anion-exchange resins. Fresenius J Anal Chem 366:213–217CrossRefGoogle Scholar
  43. Meisel T, Fellner N, Moser J (2003) A simple procedure for the determination of platinum group elements and rhenium (Ru, Rh, Pd, Re, Os, Ir and Pt) using ID-ICP-MS with an inexpensive on-line matrix separation in geological and environmental materials. J Anal At Spectrom 18:720–726CrossRefGoogle Scholar
  44. Messerschmidt J, von Bohlen A, Alt F, Klockenkamper R (2000) Separation and enrichment of palladium and gold in biological and environmental samples, adapted to the determination by total reflection X-ray fluorescence. Analyst 125:397–399CrossRefGoogle Scholar
  45. Moldovan M, Gomez MM, Palacios MA (1999) Determination of platinum, rhodium and palladium in car exhaust fumes. J Anal At Spectrom 14:1163–1169CrossRefGoogle Scholar
  46. Moldovan M, Rauch S, Gomez M, Palacios MA, Morrison GM (2001) Bioaccumulation of palladium, platinum and rhodium from urban particulates and sediments by the freshwater isopod Asellus aquaticus. Water Res 35:4175–4183CrossRefGoogle Scholar
  47. Moldovan M, Palacios MA, Gomez MM, Morrison GM, Rauch S, McLeod C, Ma R, Caroli S, Alimonti A, Petrucci F, Bocca B, Schramel P, Zischka M, Pettersson C, Wass U, Luna M, Saenz JC, Santamarıa J (2002) Environmental risk of particulate and soluble platinum group elements released from gasoline and diesel engine catalytic converters. Sci Total Env 296:199–208CrossRefGoogle Scholar
  48. Moldovan M, Gomez M, Palacios MA (2003) On-line preconcentration of palladium on alumina microcolumns and determination in urban waters by inductively coupled plasma mass spectrometry. Anal Chim Acta 478:209–217CrossRefGoogle Scholar
  49. Müller M, Heumann KG (2000) Isotope dilution inductively coupled plasma quadrupole mass spectrometry in connection with a chromatographic separation for ultra trace determinations of platinum group elements (Pt, Pd, Ru, Ir) in environmental samples. Fresenius J Anal Chem 368:109–115CrossRefGoogle Scholar
  50. Muzikar M, Fontas C, Hidalgo M, Havel J, Salvado V (2006) A preconcentration system using polyamine Metalfix-Chelamine resin for the on-line determination of palladium(II) and platinum(IV) by inductively coupled plasma optical emission spectrometry. Talanta 70:1081–1086CrossRefGoogle Scholar
  51. Palacios MA, Gomez MM, Moldovan M, Morrison G, Rauch S, McLeod C, Ma R, Laserna J, Lucena P, Caroli S, Alimonti A, Petrucci F, Bocca B, Schramel P, Lustig S, Zischka M, Wass U, Stenbom B, Luna M, Saenz JC, Santamaria J, Torrents JM (2000) Platinum-group elements: quantification in collected exhaust fumes and studies of catalytist surfaces. Sci Total Env 257:1–15CrossRefGoogle Scholar
  52. Patel KS, Sharma PC, Hoffmann P (2000) Graphite furnace-atomic absorption spectrophotometric determination of palladium in soil. Fresenius J Anal Chem 367:738–741CrossRefGoogle Scholar
  53. Petrucci F, Bocca B, Alimonti A, Caroli S (2000) Determination of Pd, Pt and Rh in airborne particulate and road dust by high-resolution ICP-MS: a preliminary investigation of the emission from automotive catalysts in the urban area of Rome. J Anal At Spectrom 15:525–528CrossRefGoogle Scholar
  54. Radziuk B, Rödel G, Stenz H, Becker-Ross H, Florek S (1995) Spectrometer system for simultaneous multielement electrothermal atomic absorption spectrometry using line sources and Zeeman-effect background correction. J Anal At Spectrom 10:127–136CrossRefGoogle Scholar
  55. Rao CRM, Reddi GS (2000) Platinum group metals (PGM); occurrence, use and recent trends in their determination. Trends Anal Chem 19:565–586CrossRefGoogle Scholar
  56. Rauch S, Lu M, Morrison GM (2001) Heterogeneity of platinum group metals in airborne particles. Env Sci Technol 35:595–599CrossRefGoogle Scholar
  57. Rauch S, Hemond HF, Peuker-Ehrenbrink B, Ek KH, Morrison GM (2005) Platinum group element concentrations and osmium isotopic composition in urban airborne particles from Boston, Massachusetts. Env Sci Technol 39:9464–9470CrossRefGoogle Scholar
  58. Ravindra K, Bencs L, Van Grieken R (2004) Platinum group elements in the environment and their health risk. Sci Total Env 318:1–43CrossRefGoogle Scholar
  59. Rudolph E, Limbeck A, Hann S (2006) Novel matrix separation-on-line pre-concentration procedure for accurate quantification of palladium in environmental samples by isotope dilution inductively coupled plasma sector field mass spectrometry. J Anal At Spectrom 21:1287–1293CrossRefGoogle Scholar
  60. Schäfer J, Hannker D, Eckhardt JD, Stüben D (1998) Uptake of traffic-related heavy metals and platinum group elements (PGM) by plants. Sci Total Env 215:59–67CrossRefGoogle Scholar
  61. Schäfer J, Eckhardt JD, Berner ZA, Stüben D (1999) Time-dependent increase of traffic-emitted platinum-group elements (PGE) in different environmental compartments. Env Sci Technol 33:3166–3170CrossRefGoogle Scholar
  62. Schuster M, Schwarzer M (1996) Selective determination of palladium by online column preconcentration and graphite furnace atomic absorption spectrometry. Anal Chim Acta 328:1–11CrossRefGoogle Scholar
  63. Shazali I, Van’t Dack L, Gijbels R (1987) Determination of precious metals in ores and rocks by thermal neutron activation/γ-spectrometry after preconcentration by nickel sulfide fire assay and coprecipitation with tellurium. Anal Chim Acta 196:49–58CrossRefGoogle Scholar
  64. Sternbeck J, Sjodin A, Andreasson K (2002) Metal emissions from road traffic and the influence of resuspension—results from two tunnel studies. Atmos Env 36:4735–4744CrossRefGoogle Scholar
  65. Sun Y, Guan X, Du A (1998) Determination of platinum group elements by inductively coupled plasma-mass spectrometry combined with nickel sulfide fire assay and tellurium coprecipitation. Spectrochim Acta B 53:1463–1467CrossRefGoogle Scholar
  66. Sures B, Zimmermann S, Messerschmidt J, von Bohlen A, Alt F (2001) First report on the uptake of automobile catalyst emitted palladium by European eels (Anguilla anguilla) following experimental exposure to road dust. Env Pollut 113:341–345CrossRefGoogle Scholar
  67. Sures B, Zimmermann S, Messerschmidt J, von Bohlen A (2002) Relevance and analysis of traffic related platinum group metals (Pt, Pd, Rh) in the aquatic biosphere, with emphasis on palladium. Ecotoxicology 11:385–392CrossRefGoogle Scholar
  68. Tilch J, Schuster M, Schwarzer M (2000) Determination of palladium in airborne particulate matter in a German city. Fresenius J Anal Chem 367:450–453CrossRefGoogle Scholar
  69. Turner A, Crussel M, Millward GE, Cobelo-Garcia A, Fisher AS (2006) Adsorption kinetics of platinum group elements in river water. Env Sci Technol 40:1524–1531CrossRefGoogle Scholar
  70. Vlasankova R, Otruba V, Bendl J, Fisera M, Kanicky V (1999) Preconcentration of platinum group metals on modified silica gel and their determination by inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry in airborne particulates. Talanta 48:839–846CrossRefGoogle Scholar
  71. Wang J, Varughese K (1987) Determination of traces of palladium by adsorptive stripping voltammetry of the dimethylglyoxime complex. Anal Chim Acta 199:185–189CrossRefGoogle Scholar
  72. Zereini F, Alt F (2000) Anthropogenic platinum-group element emissions. Their impact on man and environment. Springer, BerlinCrossRefGoogle Scholar
  73. Zereini F, Wiseman C, Alt F, Messerschmidt J, Müller J, Urban H (2001) Platinum and rhodium concentrations in airborne particulate matter in Germany from 1988 to 1998. Env Sci Technol 35:1996–2000CrossRefGoogle Scholar
  74. Zereini F, Alt F, Messerschmidt J, von Bohlen A, Liebl K, Püttmann W (2004) Concentration and distribution of platinum group elements (Pt, Pd, Rh) in airborne particulate matter in Frankfurt am Main, Germany. Env Sci Technol 38:1686–1692CrossRefGoogle Scholar
  75. Zereini F, Alt F, Messerschmidt J, Wiseman C, Feldmann I, von Bohlen A, Müller J, Liebl K, Püttmann W (2005) Concentration and particle size distribution of road-specific heavy metals in urban airborne particulate matter. Env Sci Technol 39:2983–2989CrossRefGoogle Scholar
  76. Zhao Z, Freiser H (1986) Differential pulse polarographic determination of trace levels of platinum. Anal Chem 58:1498–1501CrossRefGoogle Scholar
  77. Zischka M, Wegscheider W (2000) Reliability of and measurement uncertainty for the determination of Au, Pd, Pt and Rh for ICP-MS in environmentally relevant samples. In: Zereini F, Alt F (eds) Anthropogenic platinum-group element emissions: their impact on man and environment. Springer, Berlin, pp 201–214CrossRefGoogle Scholar

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© Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  1. 1.Department of ChemistryUniversity of Natural Resources and Applied Life SciencesViennaAustria
  2. 2.Institute of Chemical Technologies and AnalyticsVienna University of TechnologyViennaAustria

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