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Transition Metal Catalyzed Electrophilic Halogenation of C–H Bonds in Alpha-Position to Carbonyl Groups

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C-X Bond Formation

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 31))

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Abbreviations

Ar:

aromatic substituent

Ee:

enantiomeric excess

Et:

ethyl

M:

metal centre

Me:

methyl

NBS:

N-bromo succinimide

NCS:

N-chloro succinimide

NF:

N-fluoro

Np:

naphthyl

OTf:

triflate

R:

organyl substituent

rt:

room temperature

SET:

single electron transfer

TADDOL:

2,2-dimethyl-α,α,α′,α′-tetraaryl-1,3-dioxolane-4,5-dimethanol

tBu:

tert-butyl

Tol:

4-tolyl

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Author information

Authors and Affiliations

  1. Catalonian Institute for Chemical Investigation (ICIQ), Av. Països Catalans 16, Tarragona, E-43007, Spain

    Kilian Muñiz

Authors
  1. Kilian Muñiz
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Correspondence to Kilian Muñiz .

Editor information

Editors and Affiliations

  1. Sackler Fac. Exact Sciences, School of Chemístry, Tel Aviv University, Tel Aviv, 69978, Israel

    Arkadi Vigalok

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Muñiz, K. (2010). Transition Metal Catalyzed Electrophilic Halogenation of C–H Bonds in Alpha-Position to Carbonyl Groups. In: Vigalok, A. (eds) C-X Bond Formation. Topics in Organometallic Chemistry, vol 31. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-12073-2_1

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