Abstract
A wide variety of monodentate, sterically encumbering ligands have been used to stabilize low coordination numbers in both main group and transition element compounds [1]. In recent years, the very crowded m-terphenyls have emerged as a particularly effective class of bulky ligand for the stabilization of numerous main group element compounds with unusual bonding and electron configurations [2, 3]. These include, for example, the first compounds with formal triple bonds between group 13 [4, 5] and group 14 metals [6, 7], as well as a stable crystalline heavier main group radical species [8]. In contrast, transition metal terphenyl derivatives have received less attention and most of the work has been performed within the last 5 years. This account focuses on these recently discovered transition metal species.
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Notes
- 1.
Co-centroid distance of 31 Co-arene (benzene or toluene) complexes from Cambridge database (version 5.29, February 2008).
- 2.
The Fe–P distance of iron center to PMe3 molecule of 118 compounds from Cambridge database (version 5.29, February 2008).
- 3.
The Co-C distance of Co-allyl compounds from Cambridge database (version 5.29, February 2008).
- 4.
The Mn-centroid (benzene or toluene) of 79 manganese complexes in the Cambridge Crystal Structure Database (Version 5.28, August 2006) range from 1.546 to 1.765 Å.
- 5.
The N–N distances are typically 1.26 to 1.35 Å and the N–N–N angles are typically 99.1 to 111. 9∘ in the 54 triazene complexes reported in the Cambridge Crystallographic Database (version 5.29, February 2008) in which one metal is coordinated to two nitrogen atoms of the triazene ligand.
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The authors are grateful to the National Science Foundation for financial support. In addition, we thank the many talented and dedicated coworkers who are named in the references for their crucial role in advancing the chemistry described in this review.
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Ni, C., Power, P.P. (2010). Transition Metal Complexes Stabilized by Bulky Terphenyl Ligands: Application to Metal–Metal Bonded Compounds. In: Parkin, G. (eds) Metal-Metal Bonding. Structure and Bonding, vol 136. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-05243-9_3
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