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Porous Coordination Polymers Towards Gas Technology

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Molecular Networks

Part of the book series: Structure and Bonding ((STRUCTURE,volume 132))

Abstract

Gas sorption is a key technology for solving the global issues of energy and the environment that beset the world. From the end of the twentieth century, porous coordination polymers have been synthesized and studied as candidates for advanced adsorbents with a wide variety of applications. The regular nanospace of porous coordination polymers shows unique gas molecule capture and creates a new chemistry in the field of porous materials. In this article, we focus on the gas sorption properties of porous coordination polymers. Their uniqueness is illustrated using current representative results and discussed together with perspectives on the gas technology.

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Abbreviations

adip:

5,5′-(9,10-Anthracenediyl)di-isophthalate

azpy:

4,4′-Azopyridine

1,4-bdc (bdc):

1,4-Benzenedicarboxylate

bdt:

1,4-Benzeneditetrazol-5-yl

bipyen:

trans-1,2-Bis(4-pyridyl)ethylene

BMIm:

1-Butyl 3-methylimidazolium

bpdc:

4,4′-Biphenyldicarboxylate

bptc:

3,3′,5,5′-Biphenyltetracarboxylate

btapa:

1,3,5-Benzenetricarboxylic acid tris[N-(4-pyridyl)amide]

1,3,5-btb (btb):

1,3,5-Benzenetribenzoate

1,3,5-btc (btc):

1,3,5-Benzenetricarboxylate

cbbdc:

1,2-Dihydrocyclobutabenzene-3,6-dicarboxylate

dabco:

1,4-Diazabicyclo[2.2.2]octane

DFT:

Density functional theory

FCC:

Fluidized catalytic cracking

eg:

Ethylene glycol

GC:

Gas chromatography

GCMC:

Grand canonical Monte Carlo

MOF:

Metal–organic framework

ndc:

2,6-Naphthalenedicarboxylate

OMS:

Open metal site

PCP:

Porous coordination polymer

pd:

Propanediol

pzdc:

Pyrazine-2,3-dicarboxylate

pyz:

Pyrazine

Pur:

Purinate

QM:

Quantum mechanics

qptc:

Quaterphenyl-3,3″′,5,5″′-tetracarboxylate

tatb:

4,4′,4″-s-Triazine-2,4,6-triyltribenzoate

TMA:

Trimesic acid

tmbdc:

Tetramethylterephthalate

tptc:

Terphenyl-3,3″,5,5″-tetracarboxylate

ttdc:

2,2′:5′,2″-Terthiophene-5,5″-dicarboxylate

Stdc:

Styrene-2,5-dicarboxylate

STP:

Standard temperature and pressure

UMS:

Unsaturated metal center

XRPD:

X-ray powder diffraction

ZIF:

Zeolitic imidazolate framework

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Authors and Affiliations

  1. Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan

    Satoru Shimomura, Sareeya Bureekaew & Susumu Kitagawa

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  1. Satoru Shimomura
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  2. Sareeya Bureekaew
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  3. Susumu Kitagawa
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  1. Inst. Le Bel, Université Strasbourg, rue Blaise Pascal 4, Strasbourg, 67000, France

    Mir Wais Hosseini

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Shimomura, S., Bureekaew, S., Kitagawa, S. (2009). Porous Coordination Polymers Towards Gas Technology. In: Hosseini, M. (eds) Molecular Networks. Structure and Bonding, vol 132. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-01367-6_6

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