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Nanomechanical Properties of Interfacial Transition Zone in Concrete

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Abstract

This research provides better understanding of the nanostructure and the nanoscale local mechanical properties of the interfacial transition zone (ITZ) in concrete. Nanoindentation with in-situ scanning probe microscopy imaging was used to compare the properties of the bulk paste with the properties of the ITZ between paste and two different types of aggregates. ITZ was found to be extremely heterogeneous with some areas as strong as the bulk matrix. Higher concentration of large voids and cracks along the interface was observed due to poor bonding. Nanoindentation results on relatively intact areas of the interface disagreed with the notion of increasing elastic modulus with distance from the interface. Depending on the aggregate type, average modulus of the ITZ was 70% to 85% of the average modulus of the paste matrix. The main problem the ITZ poses on the overall mechanical properties of concrete was concluded to be due to extreme heterogeneity within the interface and poor bonding between aggregate and paste. It was noted that the connectivity of the weaker areas such as large voids and cracks along the interface governs failure.

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References

  1. Scrivener, K.L., Crumbie, A.K., Laugesen, P.: The interfacial transition zone (ITZ) between cement paste and aggregate in concrete. Interfac. Sci. 12, 411–421 (2004)

    Article  CAS  Google Scholar 

  2. Simeonov, P., Ahmad, S.: Effect of transition zone on the elastic behavior of cement-based composites. Cement Concrete Res. 25, 165–176 (1995)

    Article  Google Scholar 

  3. Bentz, D.P., Garboczi, E.J., Schlangen, E.: Computer simulation of interfacial zone microstructure and its effect on the properties of cement-based composites. Mat. Sci. Concrete 4, 44 (1995)

    Google Scholar 

  4. Lutz, M.P., Monteiro, P.J.M., Zimmerman, R.W.: Inhomogeneous interfacial transitionzone model for the bulk modulus of mortar. Cement Concrete Res. 27, 1113–1122 (1997)

    Article  CAS  Google Scholar 

  5. Sun, Z., Garboczi, E.J., Shah, S.P.: Modeling the elastic properties of concrete composites: Experiment, differential effective medium theory, and numerical simulation. Cement Concrete Comp. 29, 22–38 (2007)

    Article  Google Scholar 

  6. Ramesh, G., Sotelino, E.D., Chen, W.F.: Effect of transition zone on elastic stresses in concrete materials. J. Mater. Civil Eng. 10, 275–282 (1998)

    Article  CAS  Google Scholar 

  7. Zhu, W., Bartos, P.J.M.: Application of depth-sensing microindentation testing to study of interfacial transition zone in reinforced concrete. Cement Concrete Res. 30, 1299–1304 (2000)

    Article  CAS  Google Scholar 

  8. Zhu, W., Sonebi, M., Bartos, P.J.M.: Bond and interfacial properties of reinforcement in self-compacting concrete. Mater. Struct. 37, 442–448 (2004)

    CAS  Google Scholar 

  9. Asbridge, A.H., Page, C.L., Page, M.M.: Effects of metakaolin, water/binder ratio and interfacial transition zones on the microhardness of cement mortars. Cement Concrete Res. 32, 1365–1369 (2002)

    Article  CAS  Google Scholar 

  10. Constantinides, G., Ulm, F.J.: The effect of two types of C-S-H on the elasticity of cementbased materials: Results from nanoindentation and micromechanical modeling. Cement Concrete Res. 34, 67–80 (2004)

    Article  CAS  Google Scholar 

  11. Hughes, J.J., Trtik, P.: Micro-mechanical properties of cement paste measured by depthsensing nanoindentation: A preliminary correlation of physical properties with phase type. Mater. Charact. 53, 223–231 (2004)

    Article  CAS  Google Scholar 

  12. Mondal, P., Shah, S.P., Marks, L.D.: Nano-scale characterization of cementitious materials. ACI Mater. J. 105, 174–179 (2008)

    CAS  Google Scholar 

  13. Nemecek, J., Kopecky, L., Bittnar, Z.: Size effect in nanoindentation of cement paste. In: Proceedings of the International Conference held at the University of Dundee. Thomas Telford, Scotland (2005)

    Google Scholar 

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© 2009 Springer-Verlag Berlin Heidelberg

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Mondal, P., Shah, S.P., Marks, L.D. (2009). Nanomechanical Properties of Interfacial Transition Zone in Concrete. In: Bittnar, Z., Bartos, P.J.M., Němeček, J., Šmilauer, V., Zeman, J. (eds) Nanotechnology in Construction 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-00980-8_42

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