Skip to main content

Capturing Transient Solute Structures in Solution by Pulsed X-ray Diffraction

  • Conference paper
  • First Online:
  • 78 Accesses

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 92))

Abstract

The structural kinetics of photo-induced elimination reaction of 1,2-diiodotetrafluoroethane in solution is examined by transient X-ray diffraction. The structure of .CF2CF2I is determined to be a classical mixture of anti and gauche forms and their decay mechanism is also tracked in real time.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

References

  1. H. Lee, Y. C. Chang, andG. R. Fleming, Science 316 1462 2007.

    Article  ADS  Google Scholar 

  2. P. Kukura, D. W. McCamant, S. Yoon, D. B. Wandschneider, and R. A. Mathies, Science 310, 1006, 2005.

    Article  ADS  Google Scholar 

  3. H. Ihee, M. Lorenc, T. K. Kim, Q.Y. Kong, M. Cammarata, J.H. Lee, S. Bratos, and M. Wulff, Science 309, 1223, 2005.

    Article  ADS  Google Scholar 

  4. T. K. Kim, M. Lorenc, J. H. Lee, M. Lo Russo, J. Kim, M. Cammarata, Q. Kong, S. Noel, A. Plech, M. Wulff, and H. Ihee, Proc. Natl. Sci. USA 103, 9410, 2006.

    Article  ADS  Google Scholar 

  5. M. Cammarata, M. Lorenc, T. K. Kim, J. H. Lee, Q. Y. Kong, E. Pontecorvo, M. Lo Russo, G. Schiro, A. Cupane, M. Wulff, and H. Ihee, J. Chem. Phys. 124, 124504, 2006.

    Article  ADS  Google Scholar 

  6. C. Bressler, and M. Chergui, Chem. Rev. 104, 1781, 2004.

    Article  Google Scholar 

  7. A. Cavalleri, and M.Rini, H. H. W. Chong, S. Fourmaux, T. E. Glover, P. A. Heimann, J. C. Kieffer, and R.W. Schoenlein, Phys. Rev. Lett. 95, 067454, 2005.

    Article  Google Scholar 

  8. H. Ihee, V. A. Lobastov, U. M. Gomez, B. M. Goodson, R. Srinvasan, C. Y. Ruan, and A. H. Zewail, Science 291, 458, 2001.

    Article  ADS  Google Scholar 

  9. M. Rasmusson, A. N. Tarnovsky, T. Pascher, V. Sundström, and E. Åkesson, J. Phys. Chem. A. 106, 7090, 2002.

    Article  Google Scholar 

  10. S. Aditya, and J. E. Willard, J. Am. Chem. Soc. 79, 2680, 1957.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jae Hyuk Lee .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2009 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Lee, J.H. et al. (2009). Capturing Transient Solute Structures in Solution by Pulsed X-ray Diffraction. In: Corkum, P., Silvestri, S., Nelson, K., Riedle, E., Schoenlein, R. (eds) Ultrafast Phenomena XVI. Springer Series in Chemical Physics, vol 92. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95946-5_43

Download citation

  • DOI: https://doi.org/10.1007/978-3-540-95946-5_43

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-95945-8

  • Online ISBN: 978-3-540-95946-5

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

Publish with us

Policies and ethics