Skip to main content
SpringerLink
Log in

Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy

  • Conference paper
  • First Online:
Book cover Ultrafast Phenomena XVI

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 92))

  • 90 Accesses

Abstract

We report the first time-resolved soft x-ray measurements of solvated transitionmetal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. J. E. Monat and J. M. McCusker, J. Am. Chem. Soc. 122, 4092, 2000.

    Article  Google Scholar 

  2. M. Khalil, M. A. Marcus, A. L. Smeigh, J. K. McCusker, H. H. W. Chong, and R. W. Schoenlein, J. Phys. Chem. A 110, 38, 2006.

    Article  Google Scholar 

  3. W. Gawelda, V.-T. Pham, M. Benfatto, et al., Phys. Rev. Lett. 98, 057401, 2007.

    Article  ADS  Google Scholar 

  4. D. Kraemer, M. L. Cowan,  A. Paarmann, N. Huse, E. T. J. Nibbering, T. Elsaesser, and R. J. D. Miller, Proc. Nat. Acad. Sci. 105, 437, 2008.

    Article  ADS  Google Scholar 

  5. V. Briois, Ch. Cartier dit Moulin, J Ph. Sainctavit, Ch. Brouder, and A.-M. Flank, J. Am. Chem. Soc. 117, 1019 1995.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chemical Sciences Division, Lawrence Berkeley National Laboratory, 1Cyclotron Road, 94720, Berkeley, CA, USA

    Nils Huse & Robert W. Schoenlein

  2. Department of Chemistry, Pusan National University, Geumjeong-gu, 609-735, Busan, Korea

    Tae Kyu Kim

  3. Department of Chemistry, University of Washington, 98195, Seattle, WA, USA

    Munira Khalil

  4. Department of Chemistry, Michigan State University, East Lansing, 48824, MI, USA

    Lindsey Jamula & James K. McCusker

Authors
  1. Nils Huse
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Tae Kyu Kim
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Munira Khalil
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Lindsey Jamula
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. James K. McCusker
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Robert W. Schoenlein
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Nils Huse .

Editor information

Editors and Affiliations

  1. National Research Council Canada, Sussex Drive 100, Ottawa, K1A 0R6, Canada

    Paul Corkum

  2. Dipto. Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano, 20133, Italy

    Sandro Silvestri

  3. Technology (MIT), Massachusetts Institute of, Massachusetts Ave. 77, Cambridge, 02139, USA

    Keith A. Nelson

  4. Sektion Physik, Univ. München, Oettingenstr. 67, München, 80538, Germany

    Eberhard Riedle

  5. Lawrence Berkeley National Laboratory, University of California, Cyclotron Road 1, Berkeley, 94720, USA

    Robert W. Schoenlein

Rights and permissions

Reprints and permissions

Copyright information

© 2009 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Huse, N., Kim, T., Khalil, M., Jamula, L., McCusker, J.K., Schoenlein, R.W. (2009). Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy. In: Corkum, P., Silvestri, S., Nelson, K., Riedle, E., Schoenlein, R. (eds) Ultrafast Phenomena XVI. Springer Series in Chemical Physics, vol 92. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95946-5_41

Download citation

  • DOI: https://doi.org/10.1007/978-3-540-95946-5_41

  • Published:

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-95945-8

  • Online ISBN: 978-3-540-95946-5

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

Publish with us

Policies and ethics

Search

Navigation