Abstract
Potential of a novel relaxation-assisted 2DIR spectroscopy method is demonstrated on several molecular systems, including model compounds, peptides, and transition metal complexes. The cross-peaks for modes separated by distances greater than 11Å can be easily detected using RA 2DIR. A correlation of the energy transport time (arrival time) with the intermode distance is shown in several molecular systems for a number of mode pairs.
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D.V. Kurochkin, S.G. Naraharisetty, and I.V. Rubtsov. J. Phys. Chem. A 109, 10799, 2005.
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D. V. Kurochkin, S. G. Naraharisetty, and I. V. Rubtsov, Proc. Natl. Acad. Sci. U.S.A. 104, 14209, 2007.
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Rubtsov, I.V., Naraharisetty, S.R.G., Keating, C., McClure, B.A., Rack, J.J., Kasyanenko, V.M. (2009). Relaxation-Assisted Dual-Frequency Two-Dimensional Infrared Spectroscopy: Measuring Distances and Bond Connectivity. In: Corkum, P., Silvestri, S., Nelson, K., Riedle, E., Schoenlein, R. (eds) Ultrafast Phenomena XVI. Springer Series in Chemical Physics, vol 92. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95946-5_129
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DOI: https://doi.org/10.1007/978-3-540-95946-5_129
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