Abstract
Femtosecond polarization spectroscopy measures electronic wavepacket motion after vibrational wavepackets are excited near an energetically inaccessible conical intersection in a free-base naphthalocyanine. Partial equilibration via the conical funnel takes place within ~100 fs.
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Smith, E.R., Peters, W.K., Jonas, D.M. (2009). Femtosecond Electronic Dynamics via a Conical Funnel. In: Corkum, P., Silvestri, S., Nelson, K., Riedle, E., Schoenlein, R. (eds) Ultrafast Phenomena XVI. Springer Series in Chemical Physics, vol 92. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95946-5_125
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DOI: https://doi.org/10.1007/978-3-540-95946-5_125
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