Abstract
With femtosecond infrared spectroscopy and ab initio calculations we could assign the transient spectrum at 1 ps to the ring opened product of the dihydroazulene photo induced reaction. Thus, ring-opening proceeds within 1 ps.
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Schrader, T.E., Schmidhammer, U., Schreier, W.J., Koller, F.O., Pugliesi, I. (2009). Assignment of the Excited-State Infrared-Spectra in the Course of the Ring Opening Reaction of a Photochromic Dihydroazulene. In: Corkum, P., Silvestri, S., Nelson, K., Riedle, E., Schoenlein, R. (eds) Ultrafast Phenomena XVI. Springer Series in Chemical Physics, vol 92. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95946-5_115
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DOI: https://doi.org/10.1007/978-3-540-95946-5_115
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