Abstract
Self assembled monolayers (SAMs) of 11-mercaptoundecanoic acid (11-MUA) were investigated by means of x-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and thermal desorption spectroscopy (TDS). SAMs were prepared in solution, using Au(111)/mica and recrystallized gold foils as substrates. Different binding energies of the S2p peak measured by XPS as well as different thermal desorption behavior indicate the influence of the substrate on the SAM formation. The stability of the SAM under ambient conditions was investigated in order to determine long term effects, showing rearrangements as well as depletion of the 11-MUA layer.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. Ulman, Chemical Reviews, 96, 1535, 1996.
R. G. Nuzzo, L. H. Dubois and D. L. Allara, J. Am. Chem. Soc., 112, 558, 1984.
C. Vericat, M. E. Vela and R. C. Salvarezza, PCCP, 7, 3258, 2005.
S. Mendoza, I. Arfaoui, S. Zanarini, F. Paolucci and P. Rudolf, Langmuir, 23, 582, 2006.
B. L. Frey and R. M. Corn, Analytical Chemistry, 68, 3187, 1996.
P. Jiang, Z. Liu and S. Cai, Langmuir, 18, 4495, 2002.
R. V. Duevel and R. M. Corn, Analytical Chemistry, 64, 337, 1992.
K. Nakano, T. Yoshitake, Y. Yamashita and E. F. Bowden, Langmuir, 23, 6270, 2007.
H. Wang, S. Chen, L. Li and S. Jiang, Langmuir, 21, 2633, 2005.
E. Ito, K. Konno, J. Noh, K. Kanai, Y. Ouchi, K. Seki and M. Hara, Applied Surface Science, 244, 584, 2005.
C. Gorman, Y. He and R. L. Carroll, Langmuir, 17, 5324, 2001.
P. Frank, G. Hlawacek, O. Lengyel, A. Satka, C. Teichert, R. Resel, A. Winkler, Surface Science, 601, 2152, 2007.
P. Frank, J. Stettner, F. Nußbacher, and A. Winkler, in this proceedings.
D. Käfer, G. Witte, P. Cyganik, A. Terfort and C. Wöll, J. Am. Chem. Soc., 128, 1723, 2006.
A. B. Horn, D. A. Russell, L. J. Shorthouse and T. R. E. Simpson, J. Chem. Soc., 92, 4759, 1996.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2009 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Stettner, J. et al. (2009). Characterization of 11-MUA SAM formation on gold surfaces. In: Al-Shamery, K., Horowitz, G., Sitter, H., Rubahn, HG. (eds) Interface Controlled Organic Thin Films. Springer Proceedings in Physics, vol 129. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95930-4_17
Download citation
DOI: https://doi.org/10.1007/978-3-540-95930-4_17
Published:
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-95929-8
Online ISBN: 978-3-540-95930-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)