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Modification of Amorphous Carbon Film Surfaces by Thermal Grafting of Alkene Molecules

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Interface Controlled Organic Thin Films

Abstract

Thermally-assisted grafting of linear alkene molecules either in the liquid phase (ethyl undecylenate) or in the gas phase (perfluorodecene), has been performed on atomically flat amorphous carbon (a-C) films with variable average surface hybridization, sp3/(sp2 + sp3), as obtained from X-ray photoelectron spectroscopy. In contrast with the sp2-rich sputtered a-C, optimized sp3-rich a-C films obtained by Pulsed Laser ablation of a glassy carbon target do not require surface preparation before liquid phase grafting.

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Correspondence to Francine Solal .

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Sabbah, H. et al. (2009). Modification of Amorphous Carbon Film Surfaces by Thermal Grafting of Alkene Molecules. In: Al-Shamery, K., Horowitz, G., Sitter, H., Rubahn, HG. (eds) Interface Controlled Organic Thin Films. Springer Proceedings in Physics, vol 129. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95930-4_15

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