Abstract
Metal nanoparticles, nanoscopic metal particles, or fine particles of metal in a nanometer size have received much attention recently because they have specific chemical and physical properties much different from those of bulk metal [1, 2]. They are expected to be useful in various ways such as catalysts [3–7], magnetic materials [8–11], semiconductors [12, 13], electro-optic materials [14, 15], drug delivery materials [16], and so on, and thus is attractive to many researchers. These metal nanoparticles are often surrounded by organic corona, which stabilizes the dispersion of nanoparticles and provide additional novel functions to the core nanoparticles. Polymers are useful materials as the organic corona because of their strong stabilizing function due to multidentate interaction. Thus, these metal nanoparticles are prepared and used as composites with organic materials like polymers, when they are applied to various fields.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
G. Schmid (ed.), Clusters and Colloids from Theory to Application (VCH, Weinheim, 1994)
B. Corain, G. Schmid, N. Toshima (eds.), Metal Nanoclusters in Catalysis and Materials Science: The Issue of Size Control (Elsevier, Amsterdam, 2008)
H. Hirai, N. Toshima, in Taiored Metal Catalyst, ed. by Y. Iwasawa (Reidel, Dordrecht, 1985), pp. 121–135
H. Bönnemann, W. Brijoux, R. Brinkmann, E. Dinjus, T. JouBen, B. Korall, Angew. Chem. Int. Ed. Engl. 30, 1312 (1991)
C. Amiens, D. de Caro, B. Chaudret, J.S. Bradley, R. Mazel, C. Roucau, J. Am. Chem. Soc. 115, 11638 (1993)
N. Toshima, Y. Shiraishi, T. Teranishi, M. Miyake, T. Tominaga, H. Watanabe, W. Brijoux, H. Bönnemann, G. Schmid, Appl. Organometal. Chem. 15, 1 (2001)
H. Tsunoyama, H. Sakurai, Y. Negishi, T. Tsukuda, J. Am. Chem. Soc. 127, 9374 (2005)
S. Sun, C.B. Murray, D. Weller, L. Folk, A. Moser, Science 287, 1989 (2000)
M. Chen, J. Kim, J.P. Liu, H. Fan, S. Sun, J. Am. Chem. Soc. 128, 7132 (2006)
M. Nakaya, M. Kanehara, T. Teranishi, Langmuir 22, 3485 (2006)
T. Matsushita, J. Masuda, T. Iwamoto, N. Toshima, Chem. Lett. 36, 1264 (2007)
T. Teranishi, M. Nishida, M. Kanehara, Chem. Lett. 34, 1004 (2005)
(a) N. Watanabe, J. Kawamata, N. Toshima, Chem. Lett. 33, 1368 (2004); (b) N. Watanabe, N. Toshima, Bull. Chem. Soc. Jpn. 80, 2008 (2007)
S. Kobayashi, T. Miyama, N. Nishida, Y. Sakai, H. Shiraki, Y. Shiraishi, N. Toshima, J. Display Technol. 2, 121 (2006)
Y. Shiraishi, N. Toshima, K. Maeda, H. Yoshikawa, J. Xu, S. Kobayashi, Appl. Phys. Lett. 81, 2845 (2002)
H. Iida, T. Nakanishi, T. Osaka, Electrochim. Acta 51, 855 (2005)
V. Ponec, Appl. Catal. A: General 222, 31 (2001)
N. Toshima, K. Kushihashi, T. Yonezawa, H. Hirai, Chem. Lett. 1769 (1989)
K. Hirakawa, N. Toshima, Chem. Lett. 32, 78 (2003)
(a) N. Toshima, T. Yonezawa, K. Kushihashi, J. Chem. Soc. Faraday Trans. 191, 2537 (1993); (b) T. Yonezawa, N. Toshima, J. Chem. Soc. Faraday Trans. 91, 4111 (1985)
Y. Wang, N. Toshima, J. Phys. Chem. B 101, 5301 (1997)
N. Toshima, M. Kanemaru, Y. Shiraishi, Y. Koga, J. Phys. Chem. B 109, 16326 (2005)
N. Toshima, in Macromolecular Complexes: Dynamic Interactions and Electronic Processes, ed. by E. Tsuchida (Japan Scientific Societies Press, Tokyo, 1991), pp. 279–295
A. Henglein, J. Phys. Chem. B 104, 6683 (2000)
N. Toshima, Y. Shiraishi, T. Matsushita, H. Mukai, K. Hirakawa, Int. J. Nanosci. 1, 397 (2003)
T. Matsushita, Y. Shiraishi, S. Horiuchi, N. Toshima, Bull. Chem. Soc. Jpn. 80, 1217 (2007)
Y. Shiraishi, N. Toshima, Colloids Surfaces A: Physicochem. Eng. Asp. 169, 59 (2000)
J.S. Bradley, G.H. Via, L. Bonnevio, E.W. Hill, Chem. Mater. 8, 1895 (1996)
Y. Shiraishi, D. Ikenaga, N. Toshima, Aust. J. Chem. 56, 1025 (2003)
N. Toshima, Y. Shiraishi, A. Shiotsuki, D. Ikenaga, Y. Wang, Eur. Phys. J. D 16, 209 (2001)
N. Toshima, R. Ito, T. Matsushita, Y. Shiraishi, Catal. Today 122, 239 (2007)
H. Hirai, H. Chawanya, N. Toshima, Reactive Polym. 3, 127 (1985)
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2009 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Toshima, N. (2009). Polymer-Assisted Composites of Trimetallic Nanoparticles with a Three-Layered Core-Shell Structure for Catalyses. In: Muramatsu, A., Miyashita, T. (eds) Nanohybridization of Organic-Inorganic Materials. Advances in Materials Research, vol 13. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-92233-9_3
Download citation
DOI: https://doi.org/10.1007/978-3-540-92233-9_3
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-540-92232-2
Online ISBN: 978-3-540-92233-9
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)