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Massenspektrometrie

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Book cover Spektroskopische Daten zur Strukturaufklärung organischer Verbindungen

Zusammenfassung

Fragmentierung: Größere Alkylfragmente (Cn>4) werden im Wesentlichen durch direkte Fragmentierung gebildet. Die Fragmente dehydrieren und zeigen umfangreiche Umlagerungen von H-Atomen und des Gerüsts. Dabei können sich Atomgruppen aus dem Inneren der Alkylkette unter Rekombination der Enden abspalten. Kleinere Alkylfragmente (C2 bis C4) werden meist durch Zerfall höherer Fragmente gebildet.

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Authors and Affiliations

  1. Inst. Biogeochemie und Schadstoffdynamik, ETH Zürich, Universitätsstr. 16, 8092, Zürich, Schweiz

    Prof. Ernö Pretsch

  2. Dept. Chemistry, University of Minnesota, Pleasant Street SE., 207, 55455, Minneapolis, Minnesota, USA

    Prof. Philippe Bühlmann

  3. Laboratorium für Organische Chemie, ETH Zürich, Wolfgang-Pauli-Str. 10, 8093, Zürich, Schweiz

    Dr. Martin Badertscher

Authors
  1. Prof. Ernö Pretsch
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  2. Prof. Philippe Bühlmann
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  3. Dr. Martin Badertscher
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Correspondence to Ernö Pretsch .

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Pretsch, E., Bühlmann, P., Badertscher, M. (2010). Massenspektrometrie. In: Spektroskopische Daten zur Strukturaufklärung organischer Verbindungen. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-76866-1_8

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