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References
Al-Akhras NM (2006) Durability of metakaolin to sulfate attack. Cement and Concrete Research 36 (9): 1727–1734.
Alonso S, Palomo A (2001a) Alkaline activation of metakaolin and calcium hydroxide mixtures: influence of temperature, activator concentration and solids ratio. Materials Letters 47: 55–62.
Alonso S, Palomo A (2001b) Calorimetric study of alkaline activation of calcium hydroxide + metakaolin solid mixtures. Cement and Concrete Research 31: 25–30.
Ambroise J, Maximilien S, Pera J (1994) Properties of metakaolin blended cements. Advanced Cement Based Materials 1: 161–168.
Ambroise J, Murat M, Pera J (1986) Investigations on synthetic binders obtained by middle-temperature thermal dissociation of clay minerals. Silicates Industries 7 (8): 99–107.
Asbridge AH, Chadbourn GA, Page CL (2001) Effects of metakaolin and the interfacial transition zone on the diffusion of chloride ions through cement mortars. Cement and Concrete Research 31: 1567–1572.
Asbridge AH, Page CL, Page MM (2002) Effects of metakaolin, water/binder ratio and interfacial transition zones on the micro hardness of cement mortars. Cement and Concrete Research 32: 1365–1369.
Asbridge AH, Walters GV, Jones TR (1994) Ternary blended concretes- OPC/GGBFS/metakaolin. Denmark: Concrete Across Borders, pp. 547–557.
Badogiannis E, Kakali G, Dimopoulou G, Chaniotakis E, Tsivilis S (2005) Metakaolin as a main cement constituent: Exploitation of poor Greek kaolins. Cement & Concrete Composites 27: 197–203.
Badogiannis E, Papadakis VG, Chaniotakis E, Tsivilis S (2004) Exploitation of poor Greek kaolins: strength development of metakaolin concrete and evaluation by means of k-value. Cement and Concrete Research 34: 1035–1041.
Bai J, Wild S (2002) Investigation of the temperature change and heat evolution of mortar incorporating PFA and metakaolin. Cement & Concrete Composites 24: 201–209.
Bai J, Wild S, Sabir BB (2002) Sorptivity and strength of air-cured and water-cured PC–PFA–MK concrete and the influence of binder composition on carbonation depth. Cement and Concrete Research 32: 1813–1821.
Bai J, Wild S, Sabir BB (2003b) Chloride ingress and strength loss in concrete with different PC–PFA–MK binder compositions exposed to synthetic seawater. Cement and Concrete Research 33: 353–362.
Bai J, Wild S, Ware JA, Sabir BB (2003a) Using neural networks to predict workability of concrete incorporating metakaolin and fly ash. Advances in Engineering Software 34: 663–669.
Batis G, Pantazopoulou P, Tsivilis S, Badogiannis E (2005) The effect of metakaolin on the corrosion behavior of cement mortars. Cement & Concrete Composites 27: 125–130.
Boddy A, Hooton RD, Gruber KA (2001) Long-term testing of the chloride-penetration resistance of concrete containing high-reactivity metakaolin. Cement and Concrete Research 31 (5): 759–765.
Bredy P, Chabannet M, Pera J (1989) Microstructural and porosity of metakaolin blended cements. Material Research Society Symposium 137: 431–436.
Brooks JJ, Johari MMA (2001) Effect of metakaolin on creep and shrinkage of concrete. Cement & Concrete Composites 23: 495–502.
Cabrera JG, Nwaubani SO (1998) The microstructure and chloride ion diffusion characteristics of cements containing metakaolin and fly ash. In: V.M. Malhotra (Eds.), Sixth CANMET/ACI/JCI International Conference on Fly Ash, Silica Fume, Slag and Natural Pozzolans in Concrete, Bangkok, Thailand, 1: 385–400.
Cabrera J, Rojas MF (2001) Mechanism of hydration of the metakaolin-lime-water system. Cement and Concrete Research 31: 177–182.
Changling H, Osbaeck B, Makovicky E (1995) Pozzolanic reaction of six principal clay minerals: Activation reactivity assessments and technological effects. Cement and Concrete Research 25 (8): 1691–1702.
Coleman NJ, Page CL (1997) Aspects of the pore solution chemistry of hydrated cement pastes containing metakaolin. Cement and Concrete Research 27 (1): 147–154.
Courard L, Darimont A, Schouterden M, Ferauche F, Willem X, Degeimbre R. (2003) Durability of mortars modified with metakaolin. Cement and Concrete Research 33: 473–1479.
Curcio F, DeAngelis BA (1998) Dilatant behavior of superplasticized cement pastes containing metakaolin. Cement and Concrete Research 28 (5): 629–634.
Curcio F, Deangelis BA, Pagliolico S (1998) Metakaolin as pozzolanic micro filler for high-performance mortars. Cement and Concrete Research 28 (6): 803–809.
Dias WPS (2000) Reduction of concrete sorptivity with age through carbonation. Cement and Concrete Research 30 (8): 1255–1261.
Fortes-Revilla C, MartÃnez-RamÃrez S, Blanco-Varela MT (2006) Modeling of slaked lime–metakaolin mortar engineering characteristics in terms of process variables. Cement & Concrete Composites 28: 458–467.
Fraire-Luna PE, Escalante-Garcia JI, Gorokhovsky A (2006) Composite systems fluorgypsum–blast furnace slag–metakaolin, strength and microstructures. Cement and Concrete Research 36: 1048–1055.
FrÃas. M, Cabrera J (2000) Pore size distribution and degree of hydration of MK-Cement pastes. Cement and Concrete Research 30: 561–569.
FrÃas M, Cabrera J (2001) Influence of MK on the reaction kinetics in MK/lime and MK-blended cement systems at 20ĉ. Cement and Concrete Research 31: 519–527.
FrÃas M, Sánchez de Rojas MI, Cabrera J (2000) The effect that the pozzolanic reaction of metakaolin has on the heat evolution in metakaolin-cement mortars. Cement and Concrete Research 30: 209–216.
Glinicki MA, Zielinski M (2004) Depth-sensing indentation method for evaluation of efficiency of secondary cementitious materials. Cement and Concrete Research 34: 721–724.
Gruber KA, Ramlochan T, Boddy A, Hooton, RD, Thomas MDA (2001) Increasing concrete durability with high-reactivity metakaolin. Cement and Concrete Research 23 (6): 479–484.
Hooton RD, Gruber KA, Boddy A (1997) The chloride penetration resistance of concrete containing high reactivity metakaolin. Proceedings of the PCI/FHWA International Symposium on High Performance Concrete, New Orleans, LA, pp. 172–183.
Igurashi S, Bentur A, Mindess S (1996) Micro-hardness testing of cementitious materials. Advanced Cement Based Materials 4: 48–57.
Jin X, Li Z (2003) Effects of mineral admixture on properties of young concrete. Journal of Materials in Civil Engineering 15 (5): 435–442.
Khatib JM, Clay RM (2004) Absorption characteristics of metakaolin concrete. Cement and Concrete Research. 34 (1): 19–29.
Khatib JM, Mangat PS (1995) Absorption characteristics of concrete as a function of location relative to casting position. Cement and Concrete Research 25 (5): 999–1010.
Khatib JM, Wild S (1996) Pore size distribution of metakaolin paste. Cement and Concrete Research 26 (10): 1545–1553.
Khatib JM, Wild S (1998) Sulfate resistance of metakaolin mortar. Cement and Concrete Research 28 (1): 83–92.
Kinuthia JM, Wild S, Sabir BB, Bai J (2000) Self-compensating autogenous shrinkage in Portland cement-metakaolin-fly ash pastes. Advance Cement Research 12 (1): 35–43.
Klimesch DS, Ray A (1998a) Hydrogarnet formation during autoclaving at 180°C in unstirred metakaolin-lime-quartz slurries. Cement and Concrete Research 28 (8): 1109–1117.
Klimesch DS, Ray A (1998b) Autoclaved cement-quartz pastes with metakaolin additions. Advanced Cement Based Materials 7: 109–117.
Kostuch JA, Walters GV, Jones TR (1993) High performance concrete incorporating metakaolin – a review. Concrete 2000, University of Dundee, pp. 1799–1811.
Larbi JA, Bijen JM (1992) Influence of pozzolans on the Portland cement paste – aggregate interface in relation to diffusion of ions and water absorption in concrete. Cement and Concrete Research 22: 551–562.
Lee ST, Moon HY, Hooton RD, Kim JP (2005) Effect of solution concentrations and replacement levels of metakaolin on the resistance of mortars exposed to magnesium sulfate solutions. Cement and Concrete Research 35: 1314–1323.
Li Z, Ding Z (2003) Property improvement of Portland cement by incorporating with metakaolin and slag. Cement and Concrete Research 33: 579–584.
Lyubimova TY, Pinus ER (1962) Crystallization structure in the contact zone between aggregate and cement. Concr. Kolloidn. Z. (USSR) 24 (5): 578–587.
Murat M (1983) Hydration reaction and hardening of calcined clays and related minerals. Cement and Concrete Research 13: 259–266.
Oriol M, Pera J (1995) Pozzolanic activity of metakaolin under microwave treatment. Cement and Concrete Research 25 (2): 265–270.
Palomo A, Blanco-Varela MT, Granizo ML, Puertas F, Vazquez T, Grutzeck MW (1999) Chemical stability of cementitious materials based on metakaolin. Cement and Concrete Research 29: 997–1004.
Pera J, Ambroise J, Messi, A (1998) A pozzolanic activity of calcined laterite. Silicates Industries, Ceram Sci Technol 63 (7–8): 107–111.
Poon CS, Azhar S, Anson M, Wong YL (2003) Performance of metakaolin concrete at elevated temperatures. Cement & Concrete Composites 25: 83–89.
Poon CS, Kou SC, Lam L (2006) Compressive strength, chloride diffusivity and pore structure of high performance metakaolin and silica fume concrete. Construction and Building Materials 20: 858–865.
Poon CS, Lam L, Kou SC, Wong YL, Wong R (2001) Rate of pozzolanic reaction of metakaolin in high-performance cement pastes. Cement and Concrete Research 31: 1301–1306.
Poon CS, Shui ZH, Lam L (2004) Compressive behavior of fiber reinforced high-performance concrete subjected to elevated temperatures. Cement and Concrete Research 34: 2215–2222.
Potgieter-Vermaak SS, Potgieter JH (2006) Metakaolin as an extender in South African cement. Journal of Materials in Civil Engineering 18 (4): 619–623.
Qian X, Li Z (2001) The relationships between stress and strain for high-performance concrete with metakaolin. Cement and Concrete Research 31: 1607–1611.
Ramlochan T, Thomas M, Gruber KA (2000) The effect of metakaolin on alkali-silica reaction in concrete. Cement and Concrete Research 30: 339–344.
Ramlochan T, Zacarias P, Thomas MDA, Hooton RD (2004) The effect of pozzolans and slag on the expansion of mortars cured at elevated temperature Part II: Microstructural and microchemical investigations. Cement and Concrete Research 34: 1341–1356.
Razak HA, Chai HK, Wong HS (2004) Near surface characteristics of concrete containing supplementary cementing materials. Cement & Concrete Composites 26: 883–889.
Razak HA, Wong HS (2005) Strength estimation model for high-strength concrete incorporating metakaolin and silica fume. Cement and Concrete Research 35: 688–695.
Rojas MF (2006) Study of hydrated phases present in a MK–lime system cured at 60°C and 60 months of reaction. Cement and Concrete Research 36: 827–831.
Rojas MF, Cabrera J (2002) The effect of temperature on the hydration rate and stability of the hydration phases of metakaolin–lime–water systems. Cement and Concrete Research 32: 133–138.
Rojas MF, Sánchez de Rojas MI (2003) The effect of high curing temperature on the reaction kinetics in MK/lime and MK-blended cement matrices at 60°C. Cement and Concrete Research 33: 643–649.
Roy DM, Arjunan P, Silsbee MR (2001) Effect of silica fume, metakaolin, and low-calcium fly ash on chemical resistance of concrete. Cement and Concrete Research 31: 1809–1813.
Saikia NJ, Sengupta P, Gogoi PK, Borthakur PC (2002a) Cementitious properties of metakaolin–normal Portland cement mixture in the presence of petroleum effluent treatment plant sludge. Cement and Concrete Research 32: 1717–1724.
Saikia NJ, Sengupta P, Gogoi PK, Borthakur PC (2002b) Hydration behavior of lime–co-calcined kaolin–petroleum effluent treatment plant sludge. Cement and Concrete Research 32: 297–302.
Saito M, Kawamura M (1986) Resistance of the cement – aggregate interfacial zone to the propagation of cracks. Cement and Concrete Research 16 (5): 653–661.
Salvador S (1995) Pozzolanic properties of flash-calcined kaolinite: A comparative study with soak-calcined products. Cement and Concrete Research 25 (1): 102–112.
Sayanam RA, Kalsotra AK, Mehta SK, Singh RS, Mandal G (1989) Studies on thermal transformations and pozzolanic activities of clay from Jamu region (India). Journal of Thermal Analysis 35: 99–106.
Shvarzman A, Kovler K, Grader GS, Shter GE (2003) The effect of dehydroxylation/ amorphization degree on pozzolanic activity of kaolinite. Cement and Concrete Research 33: 405–416.
Smallwood I, Wild S, Morgan E (2003) The resistance of metakaolin (MK)–Portland cement (PC) concrete to the thaumasite-type of sulfate attack (TSA)—-Programme of research and preliminary results. Cement & Concrete Composites 25: 931–938.
Sun W, Zhang Y-S, Lin W, Liu Z-Y (2004) In situ monitoring of the hydration process of K-PS geopolymer cement with ESEM. Cement and Concrete Research 34: 935–940.
Thomas MDA, Gruber KA, Hooton RD (1997) The use of high reactivity metakaolin in high performance concrete, 1st Engineering Foundation Conference on High Strength Concrete, Hawaii, pp. 517–530.
Tsivilis S, Kakali G, Skaropoulou A, Sharp JH, Swamy RN (2003) Use of mineral admixtures to prevent thaumasite formation in limestone cement mortar. Cement & Concrete Composites 25: 969–976.
Wild S, Khatib JM (1997) Portlandite Consumption in metakaolin cement pastes and mortars. Cement end Concrete Research 27 (1): 137–146.
Wild S, Khatib JM, Jones A (1996) Relative strength, pozzolanic activity and cement hydration in superplasticised metakaolin concrete. Cement and Concrete Research 26 (10): 1537–1544.
Wild S, Khatib J, Roose JL (1998) Chemical and autogenous shrinkage of Portland cement-metakaolin pastes. Advance Cement Research 10 (3): 109–119.
Wong HS, Razak HA (2005) Efficiency of calcined kaolin and silica fume as cement replacement material for strength performance. Cement and Concrete Research 35: 696–702.
Zhang MH, Malhotra VM (1995) Characteristics of a thermally activated alumino-silicate pozzolanic material and its use in concrete. Cement and Concrete Research 25 (8): 1713–1725.
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Siddique, R. (2008). Metakaolin. In: Waste Materials and By-Products in Concrete. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-74294-4_2
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