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The three hydroxyls of the monomer units of cellulose can be substituted fully or in part. Generally, only regular derivatization along the chain leads to crystalline structures, and only these will be considered. Blockwise but regular derivatization of parts of the molecule can fulfill the proposed requirement of one-dimensional order along the chain molecule to a certain extent and an ordered three-dimensional structure appears in certain regions of the materials.

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(2008). Cellulose Derivatives. In: Crystalline Cellulose and Derivatives. Springer Series in Wood Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-73934-0_6

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