Skip to main content

Intumescent Flame-Retardant Treatments for Flexible Barriers

  • Chapter
Multifunctional Barriers for Flexible Structure

Part of the book series: Materials Science ((SSMATERIALS,volume 97))

Intumescent flame-retardant systems are known from several years in coating for the protection of building structure against fire. More recently, this concept was applied to polymer and to flexible structure such as textiles. The aim of this paper is to review the use of the intumescent flame-retardant process for flexible materials. In a first part, the mechanism of intumescence is described. It is pointed out that limited factors to apply this process to textiles are the durability of the systems, the stiffness due to surface deposit of the treatment and the spinnability of intumescent formulations for the bulk treatment. In a second and in a third part, recent developments to overcome those problems are presented, respectively, for natural and synthetic fibers.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. A.R. Horrocks, Fire Retardant Materials(Woodhead Publishing Limited, Cambridge, 2001), p. 128

    Book  Google Scholar 

  2. U.K. Fire Statistics London, Home Office, HOSB 20/00 (2000)

    Google Scholar 

  3. M.J. Karter Jr., NFPA 2000 United States Fire Loss, September 2001

    Google Scholar 

  4. H.L. Vandersall, J. Fire Flammability 2, 97 (1971)

    CAS  Google Scholar 

  5. G. Camino, L. Costa, L. Trossarelli, Polym. Degrad. Stab. 12, 213 (1985)

    Article  CAS  Google Scholar 

  6. R. Delobel, M. Le Bras, N. Ouassou, F. Alistiqsa, J. Fire Sci. 8(2), 85 (1990)

    Article  CAS  Google Scholar 

  7. S. Bourbigot, M. Le Bras, S. Duquesne, M. Rockery, Macromol. Mater. Eng. 289,499-511 (2004)

    Article  CAS  Google Scholar 

  8. J.W. Lyons, The Chemistry and Uses of Fire Retardants (Wiley, London, 1970), pp. 122-142

    Google Scholar 

  9. H.L. Vandersall, J. Fire Flammability 2, 97-140 (1971)

    CAS  Google Scholar 

  10. M. Kay, A.F. Price, I. Lavery, J. Fire Retardant Chem. 6(2), 69-91 (1979)

    CAS  Google Scholar 

  11. W.A. Rains, Fire Retardant Coatings. Handbook of Fire retardant Coatings and Fire Testing Services (Technomic Publishing Company, Lancaster, 1994), pp. 1-4

    Google Scholar 

  12. B.K. Kandola, R.A. Horrocks, Polym. Degrad. Stab. 54, 289-303 (1996)

    Article  CAS  Google Scholar 

  13. M. Wladyka-Przybylak, R. Kozlowski, D. Wesolek, The Thermal Characteristic of Different Intumescent Coatings, Proceedings of the 5th Arab International Conference on Materials Science, Alexandria, Egypt,22-25March 1998, pp. 45-58.

    Google Scholar 

  14. G. Camino, S. Lomakin, Fire Retardant Materials (Woodhead Publishing Lim-ited, Cambridge, 2001)

    Google Scholar 

  15. A.R. Horrocks, Polym. Degrad. Stab. 54, 143-154 (1996)

    Article  CAS  Google Scholar 

  16. H.V. Landin, Flexible Fire Barrier Felt. US Patent 5830319 (1998)

    Google Scholar 

  17. T.W. Tolbert, J.P. Panela, J.S. Dugan, J.E. Hendrix, Fireproof Fabrics, US Patent 333174 (1993)

    Google Scholar 

  18. A.R. Horrocks, S.C. Anand, B.J. Hill, Fire and Heat Resistant Materials. US Patent 5645926 (1997)

    Google Scholar 

  19. A.R. Horrocks, B.K. Kandola, in: Fire Retardancy of Polymers - The Use of Intumescence, ed. byM. Le Bras, G. Camino, S. Bourbigot, R. Delobel (Royal Society of Chemistry, London, 1998) pp. 343-362

    Google Scholar 

  20. A.R. Horrocks, P.J. Davies, Fire Mater. 24, 151-157 (2000)

    Article  CAS  Google Scholar 

  21. R. Kozlowski, B. Mieleniak, M. Muzyczek, D. Wesolek, M. Wladyka-Przybylak, Project: New Surface Modified Flame Retarded Polymeric Systems to Improve Safety in Transportation and Other Areas. Acronym: FLAMERET. Contract No: G5RD-CT 1999-00120 (2000-2003)

    Google Scholar 

  22. R. Kozlowski, B. Mieleniak, M. Muzyczek, A. Kubacki, Fire Mater. 26, 243-246 (2002)

    Article  CAS  Google Scholar 

  23. R. Kozlowski, D. Wesolek, M. Wladyka-Przybylak, Nat. Fibres 45, 149-156 (2001)

    Google Scholar 

  24. R. Kozlowski, D. Wesolek, M. Wladyka-Przybylak, FR Treatment of Fabrics With Intumescent Systems, 2nd International Conference on Polymer Modifi-cation, Degradation and Stabilisation - MoDeSt 2002, Budapest, Hungary, 30 June-4 July, 2002

    Google Scholar 

  25. PN-76/C-89020, Plastics. Determination of Ignitability by the Method of Lim-iting Oxygen Index (LOI)

    Google Scholar 

  26. ISO 5660, Fire Test Reaction to Fire (Cone Calorimeter Method)

    Google Scholar 

  27. PN-ISO 3795:1996, Road Vehicles, Tractors and Machinery for Agriculture and Forestry - Determination of Burning Behavior of Interior Materials

    Google Scholar 

  28. A.R. Horrocks, M.Y. Wang, M.E. Hall, F. Sunmonu, J.S. Pearson, Polym. Int. 49(10),1079-1091 (2000)

    Article  CAS  Google Scholar 

  29. S. Giraud, S. Bourbigot, M. Rochery, I. Vroman, L. Tighzert, R. Delobel, Polym. Degrad. Stab. 77, 285-297 (2002)

    Article  CAS  Google Scholar 

  30. S. Giraud, S. Bourbigot, M. Rochery, I. Vroman, L. Tighzert, R. Delobel, F. Poutch, Polym. Degrad. Stab. 88, 106-113 (2005)

    Article  CAS  Google Scholar 

  31. M. Bugajny, M. Le Bras, S. Bourbigot, F. Poutch, J.M. Lefebvre, J. Fire Sci. 17,494(1999)

    Article  CAS  Google Scholar 

  32. C. Thie, Encyclopedia of Polymer Science and Engineering, Microencapsulation, 2nd edn. (Wiley, New York, 1987)

    Google Scholar 

  33. A. Kondo,in Microcapsules Processing and Technology, ed. by J.W. Van Valkenburg (Dekker, New York, 1982)

    Google Scholar 

  34. P.B. Deasy, Microencapsulation and Related Drug Processes (Dekker, New York, 1984)

    Google Scholar 

  35. S. Giraud, S. Bourbigot, M. Rochery, I. Vroman, L. Tighzert, R. Delobel, J. Ind.Text.31,11(2001). S. Giraud, Microencapsulation d’un diisocyanate et d’un phosphate d’ammonium- Application: e laboration d’un sys-teme polyurethane monocomposant à propriétées retardatrices de flame pour l’enduction textile, Ph.D. Thesis, Université des Sciences et Technologies de Lille(2002), pp.113-140(www.univ-lille1.fr/bustl-grisemine/pdf/extheses/50376- 2002- 311- 312.pdf)

  36. R. Arshady, J. Microencapsul. 6, 13-28 (1989)

    Article  PubMed  CAS  Google Scholar 

  37. R. Arshady, Polym. Eng. Sci. 30, 915-924 (1990)

    Article  CAS  Google Scholar 

  38. D. Saihi, I. Vroman, S. Giraud, S. Bourbigot, React. Funct. Polym. 64(3), 127-138 (2005)

    Article  CAS  Google Scholar 

  39. S. Giraud, A. Castrovinci, I. Vroman, G. Camino, S. Bourbigot, Thermal Sta-bility and Fire Performance of Polypropylene Loaded with Microencapsulated Ammonium Phosphate, 10th European Meeting on Fire Retardancy and Pro-tection of Materials, BAM, Berlin, Germany, 7-9 September 2005

    Google Scholar 

  40.   www.specialchem4polymers.com/sf/budenheim/index.aspx?id=ammonium

  41. S.V. Levchik, E.D. Weil, Polym. Int. 54(1), 11-35 (2005)

    Article  CAS  Google Scholar 

  42. J.D. Conmey, M. Day, D.M. Wiles, J. Appl. Polym. Sci. 29, 911-923 (1984)

    Google Scholar 

  43. Z. Ma, W. Zhao, Y. Liu, J. Shi, J. Appl. Polym. Sci. 63, 1511-1515 (1997)

    CAS  Google Scholar 

  44. G. Camino, S. Duquesne, R. Delobel, E. Berend, C. Lindsay, T. Roels, Mech-anism of Expandable Graphite Fire Retardant Action in Polyurethanes, 220th ACS National Meeting, Washington, DC, 20-24 August 2000

    Google Scholar 

  45. S.C. Yao, H.E. Chen, S.C. Yeh, The Expandable Flame-Retardant Textile Mate-rials, vol. 1, Proceedings of the 5th Asian Textile Conference, 1999, p. 1160

    Google Scholar 

  46. C. Caze, E. Devaux, G. Testard, T. Reix, in Fire Retardancy of Polymers: The Use of Intumescence, ed. by M. Le Bras, G. Camino, S. Bourbigot, R. Delobel (Royal Society of Chemistry, London, 1998), pp. 363-375

    Google Scholar 

  47. M. Lewin, Polym. Degrad. Stab. 88, 13-19 (2005)

    Article  CAS  Google Scholar 

  48. R. Horrocks, M.Y. Wang, M.E. Hall, J.S. Pearson, J. Ind. Text. 29(3), 206-239 (2000)

    Article  CAS  Google Scholar 

  49. R. Horrocks, M.Y. Wang, M.E. Hall, F. Sunmonu, J.S. Pearson, Polym. Int. 49, 1079-1091 (2000)

    Article  CAS  Google Scholar 

  50. C. Drevelle, J. Lefebvre, S. Duquesne, M. Le Bras, F. Poutch, M. Vouters, C. Magniez, Polym. Degrad. Stab. 88(1), 130-137 (2005)

    Article  CAS  Google Scholar 

  51. S. Zhang, A.R. Horrocks, Prog. Polym. Sci. 28, 1517-1538 (2003)

    Article  CAS  Google Scholar 

  52. C. Magniez, R. Delobel, F. Poutch, Textile Substrate with Improved Fire Resis-tance, EP1300506 (2003)

    Google Scholar 

  53. C. Magniez, A. Dubois, M. Vouters, R. Delobel, F. Poutch, J. Ind. Text. 32(4), 255-266 (2003)

    Article  Google Scholar 

  54. A.R. Horrocks, B.K. Kandola, P.J. Davies, S. Zhang, S.A. Padbury, Polym. Degrad. Stab. 88, 3-12 (2005)

    Article  CAS  Google Scholar 

  55. C. Drevelle, Conception and Development of Fire Retardant Systems for Syn-thetic Fibers. Ph.D. Thesis (2005)

    Google Scholar 

  56. S. Duquesne, C. Drevelle, S. Bourbigot, R. Delobel, F. Poutch, Influence of the Fireproofing Method on the Fire Retardant Performance of Intumescent Polypropylene Non-Woven, 17th Annual BCC Conference on Flame Retardancy - Recent Advances in Flame Retardancy of Polymeric Materials, Stamford, CT, 21-24 May 2006

    Google Scholar 

  57. G. Montaudo, E. Scamporrino, C. Puglisi, D. Vitalini, J. Appl. Polym. Sci. 30, 1449-1460 (1985)

    CAS  Google Scholar 

  58. S. Bourbigot, M. Le Bras, C. Siat, in Recent Advances in FR of Polymeric Materials, vol. 8, ed. by M. Lewin (Business Communications, Norwall, 1998), pp. 146-160

    Google Scholar 

  59. Q. Wang, Y. Chen, Y. Liu, H. Yin, N. Aelmans, R. Kierkels, Polym. Int. 53, 439-448 (2004)

    Article  CAS  Google Scholar 

  60. S. Bourbigot, M. LeBras, F. Dabrowski, J. Gilman, T. Kashiwagi, Fire Mater. 24,201-208 (2000)

    Article  CAS  Google Scholar 

  61. S. Duquesne, S. Bourbigot, M. Lebras, C. Jama, R. Delobel, in Fire Retardancy of Polymers - New Applications of Mineral Fillers, ed. by M. Lebras, C. Wilkie, S. Bourbigot, C. Jama (RSC Publications, London, 2005), pp. 239-247

    Google Scholar 

  62. R. Kozlowski, D. Wesolek, M. Wladyka-Przybylak, Flammability of Intumescent Fire Retardant System Based on Nano-Modifiers. Proceedings of the 15th BCC Conference on Flame Retardancy, Recent Advances in Flame Retardancy of Polymeric Materials, Holiday Inn Select, Stamford, CT, 22-25 May 2005

    Google Scholar 

  63. S.V. Levchik, A.I. Balabanovich, G.F. Levchik, L. Costa, Fire Mater. 21(2), 75-83 (1997)

    Article  CAS  Google Scholar 

  64. G.F. Levchik, S.V. Levchik, A.F. Selevich, A.I. Lesnikovich, A.V. Lutske, L. Costa, in Fire Retardancy of Polymers. The Use of Intumescence ed. by M. Le Bras, G. Camino, S. Bourbigot, R. Delobel (Royal Society of Chemistry, London, 1998), pp. 280-289

    Google Scholar 

  65. A.R. Horrocks, S. Zhang, Text. Res. J. 74, 433-441 (2004)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2007 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Kozlowski, R. et al. (2007). Intumescent Flame-Retardant Treatments for Flexible Barriers. In: Duquesne, S., Magniez, C., Camino, G. (eds) Multifunctional Barriers for Flexible Structure. Materials Science, vol 97. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-71920-5_3

Download citation

Publish with us

Policies and ethics