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Thermodynamic Modeling of Complex Systems

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Molecular Thermodynamics of Complex Systems

Part of the book series: Structure and Bonding ((STRUCTURE,volume 131))

Abstract

The thermodynamic behavior of complex pure fluids and mixtures is strongly affected by specific interactions like association (hydrogen bonding) and electrostatic interactions of permanent or induced dipoles. The modeling of those systems requires a physical model that is able to explicitly account for these specific interactions. This contribution describes the state of the art in modeling of complex fluids using analytical equations of state. Many applications demonstrate that those models can successfully be applied to describe and even to predict the phase behav ior of a whole variety of substances ranging from small gas molecules up to organic solvents and polymeric systems.

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Author information

Authors and Affiliations

  1. Dortmund University of Technology, Laboratory of Thermodynamics, Emil-Figge-Str. 70, Dortmund, 44227, Germany

    Matthias Kleiner, Feelly Tumakaka & Gabriele Sadowski

Authors
  1. Matthias Kleiner
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  2. Feelly Tumakaka
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  3. Gabriele Sadowski
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Editor information

Editors and Affiliations

  1. Dept. Chemical Engineering, Nanjing University of Science & Technology, Nanjing, 210009, China

    Xiaohua Lu

  2. Dept. Chemistry, East China University of Science and Technology, Shanghai, 200237, China

    Ying Hu

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Kleiner, M., Tumakaka, F., Sadowski, G. (2009). Thermodynamic Modeling of Complex Systems. In: Lu, X., Hu, Y. (eds) Molecular Thermodynamics of Complex Systems. Structure and Bonding, vol 131. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-69116-7_2

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