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Chemistry of Hetero Analogs of Pentalene Dianion

  • Chapter
Aromaticity in Heterocyclic Compounds

Part of the book series: Topics in Heterocyclic Chemistry ((TOPICS,volume 19))

Abstract

This chapter is devoted to recent progress in the chemistry of the 5:5 fused heterocyclic systems. There are four possible modes of 5:5 fusions of the simple five-membered heterocycles leading to four structures containing one heteroatom in each ring. The heteroatoms may be the same or different and may be O, NH, S, Se, Te, P, As, or Sb. The fully conjugated hetero analogs of pentalene dianion have a central C–C bond and are isoelectronic with the 10-π-electron pentalene dianion. The scope of the chapter is outlined with a survey of various structural types and nomenclature of the parent compounds and their derivatives. New synthetic procedures and synthetic applications of title compounds are presented. This review has concentrated on the new developments achieved from 1997 to September 2007.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Chemical Sciences, University of St. Cyril and Methodius, Trnava, 817 01, Slovakia

    A. Krutošíková

  2. Institut of Organic Chemistry, Catalysis and Petrochemistry, Slovak University of Technology, Radlinského 9, Bratislava, SK, 812 37, Slovakia

    T. Gracza

Authors
  1. A. Krutošíková
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  2. T. Gracza
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Editors and Affiliations

  1. Department of Chemistry, University of Warsaw, ul. Pasteura 1, Warszawa, 02-093, Poland

    Tadeusz M. Krygowski  & Michał K. Cyrański  & 

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Krutošíková, A., Gracza, T. (2009). Chemistry of Hetero Analogs of Pentalene Dianion. In: Krygowski, T.M., Cyrański, M.K. (eds) Aromaticity in Heterocyclic Compounds. Topics in Heterocyclic Chemistry, vol 19. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-68343-8_6

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